Abstract

The ir spectra of (CH₃)₃SiCo(CO)₄ in the gaseous (4000–250 cm⁻¹) and solid (4000–33 cm⁻¹) phases have been recorded. The Raman spectrum has also been recorded for the solid state. To aid in the assignment, the ir and Raman spectra were recorded of solid (CH₃)₃SiH. The vibrational assignment for most of the 60 normal modes has been given on the basis of the fundamental vibrations of the –Si(CH₃)₃ and –Co(CO)₄ moities. The static field was sufficiently strong to split the degenerate modes but the correlation field was so weak that no definite splitting of the symmetric modes was detected.

Continuously tunable CH₃F Raman far-infrared laser

Pierre Mathieu and Jerald R. Izatt
Opt. Lett. 6(8) 369-371 (1981)

Far-infrared emission from an optically pumped overtone Raman CH₃I laser

P. T. Lang, W. Schatz, T. Kass, A. D. Semenov, and K. F. Renk
Opt. Lett. 17(7) 502-504 (1992)

Infrared–infrared double-resonance spectra of CH₃OD

J. C. Petersen and G. Duxbury
J. Opt. Soc. Am. B 7(10) 1997-2001 (1990)

Infrared–infrared double-resonance spectra of ¹³CH₃OH and ¹²CH₃OH

J. C. Petersen
J. Opt. Soc. Am. B 6(3) 350-355 (1989)

Infrared radio-frequency double-resonance spectra of CH₃OH in the CH₃ deformation state and torsionally excited states

J. C. Petersen
J. Opt. Soc. Am. B 7(2) 159-163 (1990)