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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 25,
  • Issue 3,
  • pp. 352-355
  • (1971)

Metal Isotope Effect on Raman Spectrum of [Zn(NH3)4]I2 Crystals

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Abstract

The Raman spectra of [<sup>64</sup>Zn(NH<sub>3</sub>)<sub>4</sub>]I<sub>2</sub> and its <sup>68</sup>Zn analog have been measured in the crystalline state. The Zn–N stretching vibrations have been assigned based on the observed metal isotope shifts. These shifts have been compared with theoretical values obtained from a complete normal coordinate analysis on the [Zn(NH<sub>3</sub>)<sub>4</sub>]<sup>2+</sup> ion.

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