Abstract
The vapor phase ir spectrum of 1,4-difluorobenzene has been recorded on a Perkin–Elmer 521 spectrophotometer equipped with a 10 m variable path multiple reflection cell. The band contours have been critically studied and the <i>PR</i> separations of typical <i>A</i>-, <i>B</i>-, and <i>C</i>-type bands are reported along with the relative intensity of <i>Q</i> branch with respect to that of the whole band for a few typical <i>A</i>- and <i>C</i>-type contours. The observed values are compared with those computed from rotational constants using the existing semiempirical theory.
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