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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 25,
  • Issue 4,
  • pp. 442-448
  • (1971)

Infrared Band Contours and PR Separations of Fluorinated Aromatics: 1,4-Difluorobenzene

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Abstract

The vapor phase ir spectrum of 1,4-difluorobenzene has been recorded on a Perkin–Elmer 521 spectrophotometer equipped with a 10 m variable path multiple reflection cell. The band contours have been critically studied and the <i>PR</i> separations of typical <i>A</i>-, <i>B</i>-, and <i>C</i>-type bands are reported along with the relative intensity of <i>Q</i> branch with respect to that of the whole band for a few typical <i>A</i>- and <i>C</i>-type contours. The observed values are compared with those computed from rotational constants using the existing semiempirical theory.

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