OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 29, Iss. 3 — May. 1, 1975
  • pp: 260–261

A Normal Coordinate Treatment of IF6SbF6

L. J. Basile, F. A. Hohorst, and J. R. Ferraro

Applied Spectroscopy, Vol. 29, Issue 3, pp. 260-261 (1975)


View Full Text Article

Acrobat PDF (203 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

The adduct between IF7 and AsF5 has been shown to be ionic and consist of IF6+ and AsF6 ions. The environment of these ions appears to be octahedral. Based on this symmetry, force constants have been determined. Some controversy regarding the frequency position of the ν4 (F1u) vibration, and the assignment for the ν1 (A1g), ν2 (Eg) vibrations in IF6+ has existed. However, the proper ν4 assignment was eventually made, and Raman studies of IF6+AsF6 in HF solutions clearly indicated that the lower frequency band at 711 cm−1 was polarized. Thus, the depolarized 732 cm−1 vibration was assigned as the ν2 (Eg) mode. Recently, IF6+SbF6 has been prepared and the vibration spectrum analyzed. The results support previous assignments of Christe and Sawodny and verify the ν4 assignment.

Citation
L. J. Basile, F. A. Hohorst, and J. R. Ferraro, "A Normal Coordinate Treatment of IF6SbF6," Appl. Spectrosc. 29, 260-261 (1975)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-29-3-260

You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited