Abstract
Less than 1 ppb of Ni(CO)<sub>4</sub> has been detected, under STP conditions, in the presence of a 10<sup>6</sup>-fold excess of CO at 2 cm<sup>−1</sup> resolution. Absorbance subtraction software was employed to minimize the interfering effects of the CO spectra. These results indicate that, using 20 m absorption length gas cells, Ni(CO)<sub>4</sub> concentrations on the order of 0.01 ppb are detectable using this technique.
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