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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 30,
  • Issue 5,
  • pp. 552-553
  • (1976)

Elimination of Thin Film Infrared Channel Spectra in Fourier Transform Infrared Spectroscopy

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Abstract

Thin samples in spectroscopy often show disturbing "channel spectra" due to interference fringes produced by reflections at the sample surface. These fringes will be characterized by a set of peak wavenumbers, <i>v<sub>m</sub></i> as <i>V</i><sub>m</sub> = <i>m</i>/2<i>nd</i> (1) where <i>m</i> = 0, 1, 2, ... ; <i>n</i> is the sample refractive index, and <i>d</i>, its thickness. The intensity of these peaks, Δ<i>T</i>, is given by Δ<i>T</i> = 4 (<i>n</i> − 1/<i>n</i> + 1)<sup>2</sup> (2) for thin film solid samples and Δ<i>T</i> = 4 (<i>n</i> − <i>n</i><sub>0</sub>/<i>n</i> + <i>n</i><sub>0</sub>)<sup>2</sup> (3) for samples contained between windows of index <i>n</i><sub>0</sub>.

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