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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 30,
  • Issue 6,
  • pp. 630-631
  • (1976)

Infrared Studies of Water in Crystalline Hydrates: Ba(ClO3)2·H2O

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Abstract

Infrared studies of the uncoupled OH and OD vibrations of isotopically dilute HDO have given important information about the nature of water molecules in crystalline hydrates. The main advantage of studying the spectrum of dilute HDO in H<sub>2</sub>O or D<sub>2</sub>O is that vibrations are free of intramolecular and intermolecular coupling and are thus narrower and have simpler shapes.

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