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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 40, Iss. 1 — Jan. 1, 1986
  • pp: 16–20

Far-IR Studies of Carbon Acid Complexes of 18-Crown-6

William P. McKenna and Edward M. Eyring

Applied Spectroscopy, Vol. 40, Issue 1, pp. 16-20 (1986)


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Abstract

Bands in the far-IR spectra of 18-crown-6 complexes of nitromethane, acetronitrile, and malonodinitrile are attributed to hydrogen bonding. The vσ vibrational mode is assigned for these neutral complexes. Solution studies of the complexes in CHCl3 show that a substantial amount of both the nitromethane complex and the malonodinitrile complex remains intact. The acetonitrile complex, however, appears to dissociate in CHCl3.

Citation
William P. McKenna and Edward M. Eyring, "Far-IR Studies of Carbon Acid Complexes of 18-Crown-6," Appl. Spectrosc. 40, 16-20 (1986)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-40-1-16


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