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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 40,
  • Issue 1,
  • pp. 29-35
  • (1986)

Molecular Vibration Frequency Assignment of Dimethylsilanediol

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Abstract

The fundamental molecular vibration frequencies of dimethylsilanediol were studied and assigned based upon data collected by infrared and Raman spectroscopy, and upon the literature of analogous compounds. Dimethylsilanediol and dimethylsilane-d<sub>2</sub>-diol were prepared by the hydrolysis of dimethoxydimethylsilane with water and deuterium oxide, respectively. The purity of dimethylsilanediol was verified by a gas chromatographic technique. This research found the SiOH deformations of dimethylsilanediol to absorb at 1175 cm<sup>−1</sup> and 1060 cm<sup>−1</sup>

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