OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 40, Iss. 7 — Sep. 1, 1986
  • pp: 1004–1009

FT-IR Photoacoustic Spectra of Gaseous Group VIB Metal Chalcocarbonyl Complexes

Zhen H. Xu, Ian S. Butler, and Francois G. T. St.-Germain

Applied Spectroscopy, Vol. 40, Issue 7, pp. 1004-1009 (1986)


View Full Text Article

Acrobat PDF (536 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

Attempts to record the room-temperature, FT-IR photoacoustic (PA) spectra of the crystalline group VIB metal chalcocarbonyls, M(CO)6 (M = Cr, Mo, W) and Cr(CO)5(CS), suprisingly failed owing to the high volatilities of the solid complexes in the PA cell, and excellent-quality gas-phase spectra were obtained instead. Vibrational assignments are proposed for these gases for the CO stretching and MCO bending fundamentals, and the associated binary overtone and combination spectra in the 4500-500 cm−1 region. The binary overtone and combination spectra are easily observed in the FT-IR/PA spectra and are useful in distinguishing between the four metal chalcocarbonyl complexes.

Citation
Zhen H. Xu, Ian S. Butler, and Francois G. T. St.-Germain, "FT-IR Photoacoustic Spectra of Gaseous Group VIB Metal Chalcocarbonyl Complexes," Appl. Spectrosc. 40, 1004-1009 (1986)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-40-7-1004


Sort:  Journal  |  Reset

References

References are not available for this paper.

Cited By

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited