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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 41,
  • Issue 3,
  • pp. 463-467
  • (1987)

Vibrational Analysis of Terephthalate and Terephthalate-d4 Ions

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Abstract

Infrared and Raman spectra of the terephthalate and terephthalate-d<sub>4</sub>, ions have been obtained. Normal coordinate analysis was carried out for both ions by transferring force fields from previous work on aromatic esters and <i>p</i>-nitro-benzoate and then refining all the force constants for the carboxylate groups and the diagonal force constants for the benzene rings by a first-order perturbation technique. An interpretation of the observed spectra has been proposed and selected eigenvectors have been presented.

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