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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 41,
  • Issue 8,
  • pp. 1418-1421
  • (1987)

Investigation of the Effect of Gamma-Radiation on High-Density Polyethylene by Solid-State Magic-Angle 13C NMR Spectroscopy

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Abstract

The structural and morphological changes occurring in high-density polyethylene when exposed to gamma-radiation have been investigated by high-resolution solid state <sup>13</sup>C NMR, NMR measurements are used to study the effect of gamma-radiation on crystalline and amorphous components. In addition, resonance peaks due to direct cross-links have been detected. The changes in main chain unsaturation are also studied.

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