OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 42, Iss. 1 — Jan. 1, 1988
  • pp: 101–108

Examination of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part VI

W. M. Coleman and Bert M. Gordon

Applied Spectroscopy, Vol. 42, Issue 1, pp. 101-108 (1988)


View Full Text Article

Acrobat PDF (490 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

Matrix isolation Fourier transform spectral evidence is presented that documents the isolation of rotational isomers in an argon matrix. The spectral evidence is based on the presence of split carbonyl absorption bands in the spectra of selected derivatives of methyl acetate which do not vary in intensity with changes in the matrix-to-eluate ratios. The results compare very favorably with FT-IR data on the identical compounds obtained in the vapor phase. The low temperature of the matrix isolation experiment (10 K) allows for the observance of rotational isomers not seen at the high temperatures of the vapor-phase experiment (500 K). The presence of multiple carbonyl absorption bands dictates that careful attention must be paid to spectral/structure correlations employing MI/FT-IR data.

Citation
W. M. Coleman and Bert M. Gordon, "Examination of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part VI," Appl. Spectrosc. 42, 101-108 (1988)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-42-1-101


Sort:  Journal  |  Reset

References

References are not available for this paper.

Cited By

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited