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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 42,
  • Issue 1,
  • pp. 166-168
  • (1988)

Condensed-Phase Reactions of Vanadium in the Pyrolytic Graphite-Coated Furnace: Analysis by X-Ray Powder Diffraction

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Abstract

The sequences of solid-phase reactions preceding formation of atomic vapors in the pyrolytic graphite-coated furnace have been inferred from appearance temperatures, activation energies, and multiple-phase high-temperature thermodynamic calculations. Of these, only the latter provides information on the penultimate and earlier steps preceding atom formation.

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