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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 42,
  • Issue 4,
  • pp. 572-576
  • (1988)

Self-Absorption in Copper Hollow Cathode Discharges: Effects on Spectral Line Shape and Absorption Sensitivity

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Abstract

The intensity of the hyperfine doublet of the Cu(I) 324.8-nm transition was observed as a function of current, fill gas, and fill gas pressure for a new design of hollow cathode lamp incorporating a positive column and an enlarged volume cathode cavity. The intensity ratio of the two components, which reflects the degree of self-absorption, and the flame absorption sensitivity were compared with those of a conventional hollow cathode lamp. Higher intensity, better component ratio, and increased absorption sensitivity were found in the new lamp.

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