OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 43, Iss. 5 — May. 1, 1989
  • pp: 781–786

Matrix Effects in Matrix Isolation Infrared Spectroscopy

S. Jagannathan, J. R. Cooper, and C. L. Wilkins

Applied Spectroscopy, Vol. 43, Issue 5, pp. 781-786 (1989)


View Full Text Article

Acrobat PDF (774 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

A major factor limiting extensive use of matrix isolation gas chromatography-Fourier transform infrared spectrometry is the incompatibility of matrix-isolated spectra with available vapor-or condensed-phase spectral data bases. Here, matrix and surface effects on matrix isolation infrared spectra of organic molecules are investigated. Use of xenon at −215°C (58 K) to obtain matrix isolation spectra that are similar to condensed-phase spectra is demonstrated. Finally, the effect of temperature on reflection-absorption infrared spectra of matrix-isolated molecules is discussed, and guidelines for obtaining and interpreting matrix isolation infrared spectra of gas chromatographic eluants using the existing condensed phase data bases are provided.

Citation
S. Jagannathan, J. R. Cooper, and C. L. Wilkins, "Matrix Effects in Matrix Isolation Infrared Spectroscopy," Appl. Spectrosc. 43, 781-786 (1989)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-43-5-781

You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited