OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 43, Iss. 6 — Aug. 1, 1989
  • pp: 1008–1016

Examinations of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part XVI

W. M. Coleman and Bert M. Gordon

Applied Spectroscopy, Vol. 43, Issue 6, pp. 1008-1016 (1989)


View Full Text Article

Acrobat PDF (883 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

Information concerning the matrix isolation Fourier transform infrared spectra of a series of alkanes, esters, lactones, lactams, phenols, alcohols, amides, alkenes, and ketones is presented. A comparison between the characteristics of the spectra in two matrices (argon and xenon) as well as in the absence of any matrix (bare gold disk) is drawn. The impact of these matrices on the characteristics of the IR spectra is compared with the impact observed when spectra are gathered in the vapor phase as well as the condensed phase/solid state. For the majority of compounds studied, the major absorption bands of each class of compound fall between higher values for the vapor phase and lower values for the condensed phase when either argon or xenon is used as the matrix gas. The few exceptions are discussed. The absorption bands found in the xenon matrix are usually at a lower energy than are comparable bands in the argon matrix. In most all cases, the valués of absorptions for compounds on the bare disk were lower than the comparable values found in the argon matrix. These results represent the first extensive study at 10 K of the effect of different matrix gas hosts and document the proposal that preconceptions of noble gases as inert hosts for the examination of FT-IR spectra at low temperature are not valid.

Citation
W. M. Coleman and Bert M. Gordon, "Examinations of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part XVI," Appl. Spectrosc. 43, 1008-1016 (1989)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-43-6-1008


Sort:  Journal  |  Reset

References

References are not available for this paper.

Cited By

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited