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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 43, Iss. 7 — Sep. 1, 1989
  • pp: 1208–1211

The KBM Equation for Solvent-Induced Frequency Shifts Revisited

R. A. Nyquist

Applied Spectroscopy, Vol. 43, Issue 7, pp. 1208-1211 (1989)


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Abstract

The KBM equation for determining solvent frequency shifts is generally useless for predicting vC=O frequencies for compounds in various solvent systems. The vC=O frequencies for acetone and tetramethylurea in various solvents do not correlate with dielectric effects (ε) of the solvent. A series of factors most likely determine the extent of solute/solvent-induced vibrational mode frequency shifts.

Citation
R. A. Nyquist, "The KBM Equation for Solvent-Induced Frequency Shifts Revisited," Appl. Spectrosc. 43, 1208-1211 (1989)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-43-7-1208

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