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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 47,
  • Issue 12,
  • pp. 2058-2060
  • (1993)

Overtone Spectra of CHD3 with an FT-IR Spectrometer Aided by Infrared Double Resonance

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Abstract

We have used a time-resolved double-resonance (pump-probe) method to assign the CHD<sub>3</sub> spectra taken by an FT-IR spectrometer at high resolution. The spectra of 2<i>v</i><sub>3</sub>, <i>v</i><sub>3</sub> + <i>v</i><sub>6</sub>, and 2<i>v</i><sub>6</sub> around 2000 cm<sup>−1</sup> were investigated. Collisional processes in the molecule were investigated by the time evolution of the signal and double-resonance spectra.

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