Soil samples were washed with dilute solutions of the toxic anti-knock fuel additive methylcyclopentadienyl manganese tricarbonyl (MMT) in hexanes and commercial unleaded gasoline. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was then used to detect the <i>v</i>(CO) modes of MMT, and subsequently <sup>13</sup>CO-enriched MMT, in the soil samples. The presence of MMT in the soils was further confirmed by mass spectrometry. Concentrations corresponding to ~10 ppm Mn in soil could be detected by DRIFTS of the dry samples, and, most interestingly, there was no evidence of significant MMT decomposition over a period of eight months. Apparently, MMT is stabilized by physisorption onto the soils. In the absence of such stabilization, however, MMT undergoes photolytic and thermal decomposition in a matter of minutes. These results suggest the possibility of longer-term environmental problems associated with gasoline spills containing MMT than was previously suspected.
Andrew J. Vreugdenhil and Ian S. Butler, "Detection of the Engine Anti-knock Additive Methylcyclopentadienyl Manganese Tricarbonyl (MMT) from Unleaded Gasoline in Soil by Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Mass Spectrometry," Appl. Spectrosc. 49, 482-485 (1995)
References are not available for this paper.
OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.