OSA's Digital Library

Applied Spectroscopy

Applied Spectroscopy

| PUBLISHED BY SAS — AVAILABLE FROM SAS AND OSA

  • Vol. 54, Iss. 2 — Feb. 1, 2000
  • pp: 268–276

Molecular Self-Assembling of Butan-1-ol, Butan-2-ol, and 2-Methylpropan-2-ol in Carbon Tetrachloride Solutions as Observed by Near-Infrared Spectroscopic Measurements

Makio Iwahashi, Masayuki Suzuki, Norihisa Katayama, Hideyo Matsuzawa, Miroslaw A. Czarnecki, Yukihiro Ozaki, and Akihiro Wakisaka

Applied Spectroscopy, Vol. 54, Issue 2, pp. 268-276 (2000)


View Full Text Article

Acrobat PDF (419 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations
  • Export Citation/Save Click for help

Abstract

The self-associations of butan-1-ol, butan-2-ol, and 2-methylpropan2-ol (tert-butanol) in the pure liquid state and in carbon tetrachloride solutions have been studied mainly through near-infrared spectroscopic observation at various temperatures. A new analysis assuming a successive association process for the alcohol molecules was applied to the sharp band around 1410 nm (the first-overtone band of the OH stretching vibration mode attributed to free OH monomer and partly to OH polymer); it became clear that the mean association number for each alcohol increases with increasing concentration and decreases with increasing temperature. Comparisons of the association numbers at various constant temperatures for the three kinds of alcohols show that the association abilities are on the order butan-1-ol > butan-2-ol > 2-methylpropan-2-ol.

Citation
Makio Iwahashi, Masayuki Suzuki, Norihisa Katayama, Hideyo Matsuzawa, Miroslaw A. Czarnecki, Yukihiro Ozaki, and Akihiro Wakisaka, "Molecular Self-Assembling of Butan-1-ol, Butan-2-ol, and 2-Methylpropan-2-ol in Carbon Tetrachloride Solutions as Observed by Near-Infrared Spectroscopic Measurements," Appl. Spectrosc. 54, 268-276 (2000)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-54-2-268

You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Log in to access OSA Member Subscription

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited