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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 66, Iss. 3 — Mar. 1, 2012
  • pp: 282–288

Application of Raman Multivariate Curve Resolution to Solvation-Shell Spectroscopy

KATHRYN REBECCA FEGA, DAVID SCOTT WILCOX, and DOR BEN-AMOTZ

Applied Spectroscopy, Vol. 66, Issue 3, pp. 282-288 (2012)


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Abstract

<b>Raman spectroscopy and multivariate curve resolution (Raman-MCR) are combined to yield a powerful spectroscopic method for identifying solute-induced perturbations of solvent molecules. The principles and applications of the resulting solvation-shell spectroscopy are described and illustrated using both numerical model spectra and experimental Raman spectra, including water in acetone and aqueous OH<sup>−</sup>, as well as of both neutral and ionic acetic acid solutions. The results illustrate the quantitative capabilities of Raman-MCR as a solvation-shell spectroscopy, including fundamental limitations arising from “intensity” and “rotational” ambiguities.</b>

Citation
KATHRYN REBECCA FEGA, DAVID SCOTT WILCOX, and DOR BEN-AMOTZ, "Application of Raman Multivariate Curve Resolution to Solvation-Shell Spectroscopy," Appl. Spectrosc. 66, 282-288 (2012)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-66-3-282


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