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Applied Spectroscopy

Applied Spectroscopy

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  • Vol. 68, Iss. 5 — May. 1, 2014
  • pp: 603–607

Variable-Temperature Fourier Transform Near-Infrared Imaging Spectroscopy of the Deuterium/Hydrogen Exchange in Liquid D2O

Miriam Unger, Yukihiro Ozaki, and Heinz W. Siesler

Applied Spectroscopy, Vol. 68, Issue 5, pp. 603-607 (2014)


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Abstract

In the present publication, the deuterium/hydrogen (D/H) exchange of liquid D2O exposed to water vapor of the surrounding atmosphere has been studied by variable-temperature Fourier transform near-infrared (FT-NIR) imaging spectroscopy. Apart from the visualization of the exchange process in the time-resolved FT-NIR images, kinetic parameters and the activation energy for this D/H exchange reaction have been derived from the Arrhenius plot of the variable-temperature spectroscopic data.

Citation
Miriam Unger, Yukihiro Ozaki, and Heinz W. Siesler, "Variable-Temperature Fourier Transform Near-Infrared Imaging Spectroscopy of the Deuterium/Hydrogen Exchange in Liquid D2O," Appl. Spectrosc. 68, 603-607 (2014)
http://www.opticsinfobase.org/as/abstract.cfm?URI=as-68-5-603


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