Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 68,
  • Issue 8,
  • pp. 852-864
  • (2014)

Robust Calibration Transfer in Noninvasive Ethanol Measurements, Part I: Mathematical Basis for Spectral Distortions in Fourier Transform Near-Infrared Spectroscopy (FT-NIR)

Not Accessible

Your library or personal account may give you access

Abstract

Multivariate calibration transfer in spectroscopy is an active area of interest. Many current approaches rely on the measurement of a subset of calibration samples on each instrument produced, an approach that can be impractical in many applications. Furthermore, such methods attempt to model implicitly, rather than explicitly, interinstrument differences. In Part I of this work, a Fourier transform near-infrared spectroscopy (FT-NIR) system designed to perform noninvasive ethanol measurements is discussed. Optical distortions caused by self-apodization, shear, and off-axis detector field of view (FOV) are examined and equations describing their effects are given. The effects of shear and off-axis detector FOV are shown to yield nonlinear distortions of the amplitude and wavenumber axes of measured spectra that cannot be accommodated by typical wavenumber calibration procedures or background correction. The distortions forecast by these equations are verified using laboratory measurements, and an analysis of the spectral complexity caused by the distortions is presented. The theoretical and experimental aspects presented in Part I are incorporated into a new calibration transfer method whose benefits are illustrated in Part II using noninvasive alcohol measurements. Although this work discusses a specific FT-NIR instrument and application, the methods developed form a general framework for modeling the distortions of other types of optical spectrometers to improve instrument standardization and multivariate calibration transfer.

PDF Article
More Like This
Correction of Instrument Line-Shape Distortions in Fourier Transform Spectroscopy

Piera Raspollini, Peter Ade, Bruno Carli, and Marco Ridolfi
Appl. Opt. 37(17) 3697-3704 (1998)

Near-common-path interferometer for imaging Fourier-transform spectroscopy in wide-field microscopy

Dushan N. Wadduwage, Vijay Raj Singh, Heejin Choi, Zahid Yaqoob, Hans Heemskerk, Paul Matsudaira, and Peter T. C. So
Optica 4(5) 546-556 (2017)

Wavelength calibration of Fourier-transform emission spectra with applications to Fe i

R. C. M. Learner and A. P. Thorne
J. Opt. Soc. Am. B 5(10) 2045-2059 (1988)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved