Abstract
We focus on the full relativistic quantum mechanical calculations from boron
to fluorine atoms with electronic configuration of 1s22s22pn (n = 1, 2, 3, 4, and
5), where 1s22s2 is the closed shell and 2pn is the open shell. Their active
electrons in the open shell occupy all the six spinors as far as possible.
Therefore, we suggest a new rule called "maximum probability" for the full symmetry
group relativistic theory. Furthermore, the spectral fine structure of the atomic
ground states based on the full relativistic theory and their intervals of L-S
splitting are all reasonable. It is impossible to calculate the L-S splitting
through non-relativistic quantum mechanics. The relativistic effect of atomic mass
is increased significantly by about 12 folds from boron atom to fluorine atom.
© 2011 Chinese Optics Letters
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