Variation of electronic transition moment versus internuclear distance for NO (A^(2)? ? X^(2)?) transition
Chinese Optics Letters, Vol. 1, Issue 8, pp. 438-440 (2003)
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Abstract
Two-photon laser-induced fluorescence spectrum (TP-LIF) of NO is obtained with a Nd:YAG pumped optical parametric generator and amplifier as radiation source. Spectral intensity distribution shows that the electronic transition moment for NO (A^(2)? ? X^(2)?) transition varies significantly with inter-nuclear distance. The variation relationship of the electronic transition moment versus inter-nuclear distance is deduced with polyminal fit procedure. The spontaneous radiative coefficients for NO (A^(2)? ? X^(2)?) transition from ?' = 0, 1 are obtained by combing this transition moment variation with the measurements of spontaneous radiative lifetime.
© 2005 Chinese Optics Letters
OCIS Codes
(020.4180) Atomic and molecular physics : Multiphoton processes
(300.2530) Spectroscopy : Fluorescence, laser-induced
Citation
Lianshui Zhang, Guiyin Zhang, Xiaodong Yang, Xiaohui Zhao, and Yi Li, "Variation of electronic transition moment versus internuclear distance for NO (A^(2)? ? X^(2)?) transition," Chin. Opt. Lett. 1, 438-440 (2003)
http://www.opticsinfobase.org/col/abstract.cfm?URI=col-1-8-438
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