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Journal of Display Technology

Journal of Display Technology


  • Vol. 9, Iss. 9 — Sep. 1, 2013
  • pp: 688–693

Be-Doped ZnO Thin-Film Transistors and Circuits Fabricated by Spray Pyrolysis in Air

Stuart R. Thomas, George Adamopoulos, and Thomas D. Anthopoulos

Journal of Display Technology, Vol. 9, Issue 9, pp. 688-693 (2013)

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We report the fabrication of zinc oxide (ZnO) thin-film transistors (TFTs) and simple integrated circuits by spray pyrolysis, and examine the role of beryllium (Be) as the chemical dopant. Doping is achieved through addition of Be-acetylacetonate into the parent Zn-acetate precursor solution followed by film deposition through spray pyrolysis. The microstructural properties of as-grown Be-ZnO films with different dopant concentrations are investigated using a combination of atomic force microscopy and x-ray diffraction techniques, which show the formation of polycrystalline films. Introduction of Be is found to impact the degree of crystallinity of ZnO films where a dramatic decrease in the average grain size is observed with increasing Be concentration. To assess the effects of Be-doping on the electrical properties of ZnO films we have fabricated Be-ZnO based TFTs using different doping concentrations. The average electron mobility calculated from these transistors is on the order of $\sim {{2}}\ {{cm}}^{2}\cdot{{V}}^{-1}\cdot{{s}}^{-1}$ with the threshold voltage $(V_{\rm TH})$ exhibiting a strong dependence on Be concentration. The ability to control ${V}_{\rm TH}$ through the introduction of Be has been exploited for the fabrication of unipolar inverters with symmetric trip-voltages and good noise margins.

© 2012 IEEE

Stuart R. Thomas, George Adamopoulos, and Thomas D. Anthopoulos, "Be-Doped ZnO Thin-Film Transistors and Circuits Fabricated by Spray Pyrolysis in Air," J. Display Technol. 9, 688-693 (2013)

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