Spectrum of Doubly Ionized Thulium (Tm iii)*

Jack Sugar

doi:10.1364/JOSA.60.000454

Journal of the Optical Society of America
Vol. 60,
Issue 4,
pp. 454-466
(1970)
•https://doi.org/10.1364/JOSA.60.000454

Spectrum of Doubly Ionized Thulium (Tm iii)

Jack Sugar

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Jack Sugar, "Spectrum of Doubly Ionized Thulium (Tm iii)*," J. Opt. Soc. Am. 60, 454-466 (1970)

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Abstract

A list of 848 low-excitation spectral lines of Tm iii has been obtained by utilizing the sliding-spark light source at a peak current of 6 A. An analysis of these lines yielded 108 energy levels belonging to the configurations 4f¹³, 4f¹²5d, 4f¹²6s, and 4f¹²6p. The classified lines and level values are presented as well as a theoretical interpretation of these configurations.

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Fitted parameter values and associated standard errors for 4f¹²(5d + 6s) configurations of Tm iii in units of cm⁻¹.

Parameters	4f¹²5d	4f¹²6s
A	40 423±64	38 871±90
E¹(f¹²)	6897±62	6995±98
E²	32.92±0.5	33.75±0.6
E³	672.9±4	676.4±7
F²(fd)	20 475±100
F⁴	12 911±350
G¹	7578±70
G³	9922±320
G⁵	8035±550
G³(fs)		1918±210
ζ_f	2639.4±6	2632±10
ζ_d	1131±11
E_l	7.2±1
E_s	379±40
Configuration interaction
R²(fd, fs) = 0 (fixed)
R³(fd, sf) = −3872±700
rms error of calculated levels = 64 cm⁻¹

Calculated energy levels and compositions of the mixed 4f¹²5d and 4f¹²6s configurations of Tm iii. Negative eigenvector components are denoted by asterisks.

J	Levels calculated (cm⁻¹)	Levels observed (cm⁻¹)	Obs. minus calc.	Configuration 4f¹²5d 4f¹²6s		Composition in J₁J₂ coupling
$0 \frac{1}{2}$	42 083			x		$({{}^{3}F}_{2}) \frac{3}{2}$	52%,	$({{}^{3}F}_{3}) \frac{5}{2}$	30%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	7%
	45 865			x		$({{}^{3}F}_{2}) \frac{5}{2}$	62%,	$({{}^{3}F}_{2}) \frac{3}{2}$	14%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	13%
	46 286			x		$* ({{}^{3}F}_{3}) \frac{5}{2}$	63%,	$({{}^{3}F}_{2}) \frac{3}{2}$	16%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	12%
	55 219			x		$({{}^{3}P}_{2}) \frac{3}{2}$	32%,	$({{}^{1}D}_{2}) \frac{3}{2}$	30%,	$({{}^{3}P}_{1}) \frac{3}{2}$	17%
	59 666			x		$({{}^{1}D}_{2}) \frac{5}{2}$	30%,	$({{}^{3}P}_{2}) \frac{5}{2}$	27%,	$({{}^{1}D}_{2}) \frac{3}{2}$	15%
	61 334				x	$({{}^{3}P}_{0}) \frac{1}{2}$	87%,	$* ({{}^{3}P}_{1}) \frac{1}{2}$	7%,
	62 182				x	$({{}^{3}P}_{1}) \frac{1}{2}$	59%,	$({{}^{3}P}_{1}) \frac{3}{2}$	29%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	3%
	63 230			x		$({{}^{3}P}_{1}) \frac{3}{2}$	33%,	$* ({{}^{3}P}_{1}) \frac{1}{2}$	33%,	$({{}^{1}D}_{2}) \frac{5}{2}$	15%
	68 291			x		$({{}^{3}P}_{2}) \frac{3}{2}$	60%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	31%
	72 295			x		$({{}^{3}P}_{2}) \frac{5}{2}$	62%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	30%
	103 627				x	$({{}^{1}S}_{0}) \frac{1}{2}$	95%
$1 \frac{1}{2}$	34 877			x		$({{}^{3}H}_{4}) \frac{5}{2}$	31%,	$* ({{}^{1}G}_{4}) \frac{5}{2}$	29%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	22%
	38 219			x		$({{}^{3}F}_{4}) \frac{5}{2}$	35%,	$({{}^{3}F}_{3}) \frac{3}{2}$	27%,	$({{}^{3}H}_{4}) \frac{5}{2}$	19%
	40 351	40 404	53		x	$({{}^{3}F}_{2}) \frac{1}{2}$	78%,	$* ({{}^{1}D}_{2}) \frac{1}{2}$	20%
	41 490			x		$* ({{}^{3}F}_{2}) \frac{3}{2}$	29%,	$({{}^{3}F}_{3}) \frac{3}{2}$	27%,	$({{}^{1}D}_{2}) \frac{3}{2}$	14%
	43 068	43 161	93	x		$* ({{}^{3}F}_{3}) \frac{3}{2}$	37%,	$({{}^{3}H}_{4}) \frac{5}{2}$	31%,	$* ({{}^{3}F}_{2}) \frac{3}{2}$	12%
	45 113			x		$({{}^{3}F}_{3}) \frac{5}{2}$	56%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	22%,	$* ({{}^{3}F}_{2}) \frac{3}{2}$	7%
	46 058			x		$({{}^{3}F}_{2}) \frac{5}{2}$	46%,	$({{}^{3}F}_{3}) \frac{5}{2}$	24%,	$* ({{}^{1}G}_{4}) \frac{5}{2}$	9%
	51 637			x		$({{}^{1}G}_{4}) \frac{5}{2}$	50%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	18%,	$({{}^{3}H}_{4}) \frac{5}{2}$	15%
	53 779				x	$({{}^{1}D}_{2}) \frac{1}{2}$	44%,	$* ({{}^{3}P}_{2}) \frac{1}{2}$	37%,	$({{}^{3}F}_{2}) \frac{1}{2}$	18%
	55 891			x		$({{}^{3}P}_{2}) \frac{3}{2}$	45%,	$({{}^{3}F}_{2}) \frac{3}{2}$	18%,	$({{}^{1}D}_{2}) \frac{3}{2}$	16%
	58 421			x		$* ({{}^{1}D}_{2}) \frac{5}{2}$	45%,	$* ({{}^{3}P}_{2}) \frac{5}{2}$	26%,	$* ({{}^{3}P}_{1}) \frac{5}{2}$	8%
	62 049				x	$({{}^{3}P}_{1}) \frac{1}{2}$	98%
	63 325			x		$({{}^{3}P}_{0}) \frac{3}{2}$	46%,	$({{}^{1}D}_{2}) \frac{3}{2}$	14%,	$* ({{}^{3}P}_{1}) \frac{5}{2}$	13%
	64 123				x	$({{}^{3}P}_{2}) \frac{1}{2}$	56%,	$({{}^{1}D}_{2}) \frac{1}{2}$	33%,	$* ({{}^{3}P}_{1}) \frac{5}{2}$	3%
	64 521			x		$({{}^{3}P}_{1}) \frac{3}{2}$	51%,	$({{}^{3}P}_{0}) \frac{3}{2}$	31%,	$* ({{}^{3}F}_{2}) \frac{3}{2}$	4%
	68 329			x		$({{}^{3}P}_{1}) \frac{3}{2}$	34%,	$* ({{}^{3}P}_{1}) \frac{5}{2}$	20%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	17%
	69 835			x		$({{}^{3}P}_{1}) \frac{5}{2}$	48%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	22%,	$({{}^{1}D}_{2}) \frac{3}{2}$	19%
	71 347			x		$({{}^{3}P}_{2}) \frac{5}{2}$	62%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	29%
	105 253			x		$({{}^{1}S}_{0}) \frac{3}{2}$	94%
$2 \frac{1}{2}$	31 485	31 570	85	x		$({{}^{3}F}_{4}) \frac{3}{2}$	44%,	$({{}^{1}G}_{4}) \frac{3}{2}$	28%,	$* ({{}^{3}H}_{4}) \frac{3}{2}$	6%
	33 550	33 605	55	x		$({{}^{3}H}_{5}) \frac{5}{2}$	42%,	$({{}^{3}H}_{4}) \frac{3}{2}$	13%,	$* ({{}^{3}F}_{3}) \frac{3}{2}$	10%
	36 338	36 392	54	x		$* ({{}^{3}F}_{4}) \frac{3}{2}$	23%,	$({{}^{1}G}_{4}) \frac{3}{2}$	20%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	18%
	39 383	39 279	−104	x		$* ({{}^{3}H}_{5}) \frac{5}{2}$	25%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	20%,	$* ({{}^{3}F}_{3}) \frac{3}{2}$	13%
	39 850				x	$({{}^{3}F}_{3}) \frac{1}{2}$	85%,	$({{}^{3}F}_{2}) \frac{1}{2}$	12%
	40 821	40 754	−67		x	$({{}^{3}F}_{2}) \frac{1}{2}$	58%,	$* ({{}^{1}D}_{2}) \frac{1}{2}$	16%,	$* ({{}^{3}F}_{3}) \frac{1}{2}$	13%
	41 021			x		$({{}^{3}F}_{2}) \frac{3}{2}$	40%,	$* ({{}^{3}H}_{4}) \frac{3}{2}$	11%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	9%
	41 829			x		$({{}^{3}H}_{4}) \frac{5}{2}$	30%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	16%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	13%
	42 874	42 915	41	x		$* ({{}^{3}F}_{3}) \frac{3}{2}$	37%,	$({{}^{3}H}_{4}) \frac{5}{2}$	22%,	$({{}^{3}F}_{2}) \frac{5}{2}$	9%
	43 697	43 768	71	x		$({{}^{3}F}_{3}) \frac{5}{2}$	65%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	9%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	8%
	47 662	47 624	−38	x		$({{}^{3}F}_{2}) \frac{5}{2}$	43%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	20%,	$({{}^{3}F}_{3}) \frac{3}{2}$	14%
	49 047			x		$* ({{}^{1}G}_{4}) \frac{5}{2}$	37%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	20%,	$({{}^{1}G}_{4}) \frac{3}{2}$	20%
	52 697	52 680	−17	x		$* ({{}^{1}D}_{2}) \frac{3}{2}$	21%,	$({{}^{1}G}_{4}) \frac{3}{2}$	19%,	$({{}^{3}P}_{2}) \frac{3}{2}$	14%
	53 645				x	$({{}^{1}D}_{2}) \frac{1}{2}$	41%,	$({{}^{3}P}_{2}) \frac{1}{2}$	40%,	$({{}^{3}F}_{2}) \frac{1}{2}$	19%
	56 235	56 218	−17	x		$({{}^{3}F}_{2}) \frac{3}{2}$	20%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	20%,	$({{}^{1}D}_{2}) \frac{3}{2}$	12%
	59 038			x		$({{}^{1}D}_{2}) \frac{5}{2}$	39%,	$({{}^{3}P}_{2}) \frac{5}{2}$	26%,	$({{}^{3}F}_{2}) \frac{5}{2}$	14%
	63 380			x		$* ({{}^{3}P}_{0}) \frac{5}{2}$	29%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	18%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	18%
	63 849				x	$({{}^{3}P}_{2}) \frac{1}{2}$	55%,	$* ({{}^{1}D}_{2}) \frac{1}{2}$	37%
	65 075			x		$({{}^{3}P}_{1}) \frac{3}{2}$	83%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	8%
	67 068			x		$({{}^{3}P}_{2}) \frac{5}{2}$	32%,	$({{}^{3}P}_{2}) \frac{3}{2}$	27%,	$* ({{}^{3}P}_{0}) \frac{5}{2}$	18%
	68 664			x		$({{}^{3}P}_{0}) \frac{5}{2}$	34%,	$({{}^{3}P}_{1}) \frac{5}{2}$	29%,	$({{}^{3}P}_{2}) \frac{5}{2}$	17%
	69 383			x		$* ({{}^{3}P}_{1}) \frac{5}{2}$	62%,	$({{}^{3}P}_{2}) \frac{5}{2}$	16%,	$({{}^{3}P}_{0}) \frac{5}{2}$	8%
	107 696			x		$({{}^{1}S}_{0}) \frac{5}{2}$	94%
$3 \frac{1}{2}$	27 593	27 547	−46	x		$* ({{}^{3}H}_{6}) \frac{5}{2}$	52%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	16%,	$({{}^{3}H}_{5}) \frac{3}{2}$	14%
	31 380	31 369	−11		x	$({{}^{3}F}_{4}) \frac{1}{2}$	60%,	$* ({{}^{1}G}_{4}) \frac{1}{2}$	30%
	32 296	32 263	−33	x		$* ({{}^{3}F}_{4}) \frac{3}{2}$	46%,	$({{}^{1}G}_{4}) \frac{3}{2}$	19%,	$({{}^{3}H}_{6}) \frac{5}{2}$	18%
	33 738	33 631	−107	x		$({{}^{3}H}_{5}) \frac{3}{2}$	53%,	$({{}^{3}H}_{6}) \frac{5}{2}$	14%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	13%
	36 290	36 406	116	x		$* ({{}^{3}H}_{5}) \frac{5}{2}$	40%,	$({{}^{3}F}_{4}) \frac{5}{2}$	14%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	7%
	37 321	37 368	47	x		$({{}^{3}H}_{5}) \frac{5}{2}$	30%,	$({{}^{3}F}_{4}) \frac{5}{2}$	23%,	$({{}^{3}H}_{4}) \frac{3}{2}$	14%
	38 059	38 056	−3		x	$({{}^{3}H}_{4}) \frac{1}{2}$	59%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	28%,	$* ({{}^{1}G}_{4}) \frac{1}{2}$	11%
	39 866	39 883	17		x	$({{}^{3}F}_{3}) \frac{1}{2}$	98%
	40 044	39 935	−109	x		$({{}^{3}F}_{3}) \frac{3}{2}$	50%,	$({{}^{3}F}_{2}) \frac{3}{2}$	9%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	9%
	41 312	41 233	−79	x		$* ({{}^{3}F}_{2}) \frac{3}{2}$	22%,	$({{}^{3}F}_{4}) \frac{5}{2}$	17%,	$({{}^{3}F}_{3}) \frac{3}{2}$	15%
	43 116	43 140	24	x		$({{}^{3}F}_{3}) \frac{5}{2}$	36%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	18%,	$({{}^{3}H}_{4}) \frac{3}{2}$	13%
	44 498	44 496	−2	x		$({{}^{3}F}_{3}) \frac{5}{2}$	30%,	$({{}^{3}F}_{2}) \frac{3}{2}$	22%,	$({{}^{3}F}_{2}) \frac{5}{2}$	15%
	45 696	45 733	37	x		$* ({{}^{3}H}_{4}) \frac{3}{2}$	26%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	25%,	$({{}^{3}F}_{4}) \frac{5}{2}$	14%
	45 861	45 795	−66	x		$* ({{}^{1}G}_{4}) \frac{5}{2}$	21%,	$({{}^{3}H}_{4}) \frac{5}{2}$	20%,	$* ({{}^{3}F}_{3}) \frac{5}{2}$	18%
	46 759	46 787	28		x	$({{}^{1}G}_{4}) \frac{1}{2}$	58%,	$({{}^{3}H}_{4}) \frac{1}{2}$	31%,	$({{}^{3}F}_{4}) \frac{1}{2}$	11%
	50 517	50 563	46	x		$* ({{}^{1}G}_{4}) \frac{5}{2}$	35%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	27%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	11%
	51 089	51 071	−18	x		$({{}^{1}G}_{4}) \frac{3}{2}$	33%,	$({{}^{3}H}_{4}) \frac{3}{2}$	22%,	$({{}^{1}D}_{2}) \frac{3}{2}$	12%
	55 578	55 587	9	x		$({{}^{3}P}_{2}) \frac{5}{2}$	20%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	20%,	$({{}^{1}D}_{2}) \frac{5}{2}$	14%
	57 713			x		$({{}^{1}D}_{2}) \frac{3}{2}$	21%,	$* ({{}^{3}P}_{2}) \frac{5}{2}$	19%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	16%
	62 759			x		$({{}^{1}I}_{6}) \frac{5}{2}$	86%,	$({{}^{3}H}_{4}) \frac{3}{2}$	4%
	64 761			x		$* ({{}^{1}D}_{2}) \frac{5}{2}$	31%,	$* ({{}^{3}P}_{1}) \frac{5}{2}$	25%,	$({{}^{3}P}_{2}) \frac{5}{2}$	18%
	66 939			x		$({{}^{3}P}_{1}) \frac{5}{2}$	39%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	35%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	19%
	68 537			x		$({{}^{3}P}_{2}) \frac{5}{2}$	35%,	$({{}^{3}P}_{1}) \frac{5}{2}$	27%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	15%
$4 \frac{1}{2}$	23 018	22 898	−120	x		$({{}^{3}H}_{6}) \frac{3}{2}$	84%,	$({{}^{3}H}_{6}) \frac{5}{2}$	7%
	30 482	30 536	54	x		$* ({{}^{3}H}_{6}) \frac{5}{2}$	61%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	10%,	$* ({{}^{3}H}_{5}) \frac{3}{2}$	9%
	31 047	31 038	−9		x	$({{}^{3}F}_{4}) \frac{1}{2}$	64%,	$({{}^{1}G}_{4}) \frac{1}{2}$	28%
	32 849	32 798	−51	x		$* ({{}^{3}F}_{4}) \frac{3}{2}$	53%,	$({{}^{1}G}_{4}) \frac{3}{2}$	20%,	$* ({{}^{3}H}_{6}) \frac{3}{2}$	8%
	33 834	33 832	−2		x	$({{}^{3}H}_{5}) \frac{1}{2}$	99%
	35 810	35 751	−59	x		$({{}^{3}F}_{4}) \frac{5}{2}$	57%,	$({{}^{1}G}_{4}) \frac{5}{2}$	24%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	6%
	36 970	37 029	59	x		$* ({{}^{3}H}_{5}) \frac{3}{2}$	65%,	$({{}^{3}F}_{3}) \frac{3}{2}$	12%,	$({{}^{3}H}_{6}) \frac{5}{2}$	11%
	38 032	38 003	−29		x	$({{}^{3}H}_{4}) \frac{1}{2}$	42%,	$* ({{}^{3}H}_{5}) \frac{5}{2}$	24%,	$({{}^{3}F}_{4}) \frac{1}{2}$	18%
	38 534	38 610	76	x		$* ({{}^{3}H}_{5}) \frac{5}{2}$	48%,	$* ({{}^{3}H}_{4}) \frac{1}{2}$	16%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	7%
	40 475	40 401	−74	x		$({{}^{3}H}_{4}) \frac{3}{2}$	49%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	21%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	18%
	42 653	42 670	17	x		$* ({{}^{3}F}_{3}) \frac{3}{2}$	38%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	18%,	$* ({{}^{3}H}_{5}) \frac{3}{2}$	14%
	43 026	43 022	−4	x		$({{}^{3}F}_{3}) \frac{5}{2}$	32%,	$({{}^{3}F}_{3}) \frac{3}{2}$	20%,	$* ({{}^{3}F}_{2}) \frac{5}{2}$	15%
	44 466	44 496	30	x		$* ({{}^{3}F}_{3}) \frac{5}{2}$	54%,	$({{}^{3}F}_{3}) \frac{3}{2}$	16%,	$({{}^{3}H}_{5}) \frac{5}{2}$	8%
	46 842	46 817	−25		x	$({{}^{1}G}_{4}) \frac{1}{2}$	53%,	$({{}^{3}H}_{4}) \frac{1}{2}$	31%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	9%
	47 053	47 071	18	x		$({{}^{3}F}_{2}) \frac{5}{2}$	50%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	14%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	10%
	49 276			x		$({{}^{1}G}_{4}) \frac{3}{2}$	48%,	$({{}^{3}H}_{4}) \frac{3}{2}$	39%,	$({{}^{3}F}_{4}) \frac{3}{2}$	7%
	51 687	51 634	−53	x		$({{}^{1}G}_{4}) \frac{5}{2}$	47%,	$({{}^{3}H}_{4}) \frac{5}{2}$	37%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	6%
	59 168			x		$({{}^{3}P}_{2}) \frac{5}{2}$	38%,	$({{}^{1}D}_{2}) \frac{5}{2}$	37%,	$({{}^{3}F}_{2}) \frac{5}{2}$	15%
	59 831			x		$({{}^{1}I}_{6}) \frac{3}{2}$	76%,	$* ({{}^{1}I}_{6}) \frac{5}{2}$	14%
	64 774			x		$({{}^{1}I}_{6}) \frac{5}{2}$	85%,	$({{}^{1}I}_{6}) \frac{3}{2}$	14%
	69 567			x		$({{}^{3}P}_{2}) \frac{5}{2}$	56%,	$* ({{}^{1}D}_{2}) \frac{5}{2}$	37%
$5 \frac{1}{2}$	25 838	25 921	83		x	$({{}^{3}H}_{6}) \frac{1}{2}$	93%
	26 275	26 252	−23	x		$({{}^{3}H}_{6}) \frac{3}{2}$	71%,	$({{}^{3}H}_{6}) \frac{5}{2}$	20%
	30 566	30 532	−34	x		$({{}^{3}H}_{6}) \frac{5}{2}$	61%,	$({{}^{3}F}_{4}) \frac{3}{2}$	17%,	$* ({{}^{3}H}_{6}) \frac{3}{2}$	10%
	33 156	33 236	80	x		$({{}^{3}F}_{4}) \frac{3}{2}$	30%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	23%,	$({{}^{3}H}_{4}) \frac{3}{2}$	12%
	33 838	33 803	−35		x	$({{}^{3}H}_{5}) \frac{1}{2}$	92%
	34 802	34 827	25	x		$({{}^{3}F}_{4}) \frac{5}{2}$	58%,	$({{}^{1}G}_{4}) \frac{5}{2}$	23%,	$* ({{}^{3}H}_{4}) \frac{5}{2}$	6%
	36 794	36 810	16	x		$({{}^{3}H}_{5}) \frac{3}{2}$	84%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	4%,	$({{}^{3}H}_{6}) \frac{5}{2}$	3%
	39 132	39 143	11	x		$({{}^{3}H}_{4}) \frac{3}{2}$	52%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	30%,	$* ({{}^{3}H}_{5}) \frac{3}{2}$	5%
	39 594	39 604	10	x		$({{}^{3}H}_{5}) \frac{5}{2}$	79%,	$({{}^{3}F}_{3}) \frac{5}{2}$	15%
	43 011	42 953	−58	x		$({{}^{3}H}_{4}) \frac{5}{2}$	44%,	$* ({{}^{1}G}_{4}) \frac{5}{2}$	20%,	$({{}^{3}F}_{4}) \frac{5}{2}$	17%
	45 985			x		$({{}^{3}F}_{3}) \frac{5}{2}$	71%,	$* ({{}^{3}H}_{5}) \frac{5}{2}$	12%,	$({{}^{3}H}_{4}) \frac{5}{2}$	5%
	47 563	47 604	41	x		$({{}^{1}G}_{4}) \frac{3}{2}$	56%,	$({{}^{3}H}_{4}) \frac{3}{2}$	26%,	$({{}^{3}F}_{4}) \frac{3}{2}$	13%
	51 775			x		$({{}^{1}G}_{4}) \frac{5}{2}$	50%,	$({{}^{3}H}_{4}) \frac{5}{2}$	41%
	59 947				x	$({{}^{1}I}_{6}) \frac{1}{2}$	98%
	63 290			x		$({{}^{1}I}_{6}) \frac{3}{2}$	88%,	$* ({{}^{1}I}_{6}) \frac{5}{2}$	11%
	66 996			x		$({{}^{1}I}_{6}) \frac{5}{2}$	87%,	$({{}^{1}I}_{6}) \frac{3}{2}$	10%
$6 \frac{1}{2}$	25 353	25 303	−50		x	$({{}^{3}H}_{6}) \frac{1}{2}$	99%
	28 627	28 721	94	x		$* ({{}^{3}H}_{6}) \frac{3}{2}$	93%
	31 262	31 323	61	x		$({{}^{3}H}_{6}) \frac{5}{2}$	72%,	$({{}^{3}F}_{4}) \frac{5}{2}$	15%,	$* ({{}^{3}H}_{5}) \frac{3}{2}$	6%
	34 123	34 124	1	x		$({{}^{3}H}_{5}) \frac{3}{2}$	87%,	$({{}^{3}H}_{6}) \frac{5}{2}$	6%
	36 392	36 369	−23	x		$({{}^{3}F}_{4}) \frac{5}{2}$	33%,	$({{}^{1}G}_{4}) \frac{5}{2}$	28%,	$* ({{}^{3}H}_{6}) \frac{5}{2}$	19%
	39 543	39 496	−47	x		$({{}^{3}H}_{5}) \frac{5}{2}$	90%
	41 892	41 864	−28	x		$({{}^{3}H}_{4}) \frac{5}{2}$	55%,	$({{}^{3}F}_{4}) \frac{5}{2}$	35%
	50 549			x		$({{}^{1}G}_{4}) \frac{5}{2}$	57%,	$({{}^{3}H}_{4}) \frac{5}{2}$	28%,	$* ({{}^{3}F}_{4}) \frac{5}{2}$	12%
	59 947				x	$({{}^{1}I}_{6}) \frac{1}{2}$	98%
	65 038			x		$({{}^{1}I}_{6}) \frac{3}{2}$	98%
	67 564			x		$({{}^{1}I}_{6}) \frac{5}{2}$	98%
$7 \frac{1}{2}$	25 875	25 879	4	x		$({{}^{3}H}_{6}) \frac{3}{2}$	96%
	30 700	30 665	−35	x		$({{}^{3}H}_{6}) \frac{5}{2}$	96%
	36 482	36 466	−16	x		$({{}^{3}H}_{5}) \frac{5}{2}$	99%
	57 767			x		$({{}^{1}I}_{6}) \frac{3}{2}$	91%
	67 515			x		$({{}^{1}I}_{6}) \frac{5}{2}$	91%
$8 \frac{1}{2}$	27 552	27 558	6	x		$({{}^{3}H}_{6}) \frac{5}{2}$	99%
	60 280			x		$({{}^{1}I}_{6}) \frac{5}{2}$	99%

Fitted parameter values and associated standard errors for the 4f¹²6p configuration of Tm iii.

Parameter	Value (cm⁻¹)
A	81 079±68
E¹(f¹²)	7018±32
E²	34.35±0.2
E³	684.3±2
F²(fp)	6030±75
G²	1782±52
G⁴	1930±130
ζ_f	2634±3
ζ_p	3850±8
rms error of calculated levels = 32 cm⁻¹

Calculated energy levels and compositions of the 4f¹²6p configuration of Tm iii. Negative eigenvector components are denoted by asterisks.

J	Levels calculated (cm⁻¹)	Levels observed (cm⁻¹)	Obs. minus calc.	Composition in J₁J₂ coupling
$0 \frac{1}{2}$	83 435			$({{}^{3}F}_{2}) \frac{3}{2}$	80%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	18%
	96 575			$({{}^{1}D}_{2}) \frac{3}{2}$	37%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	35%,	$({{}^{3}P}_{1}) \frac{1}{2}$	14%
	98 814			$({{}^{3}P}_{0}) \frac{1}{2}$	91%
	99 423			$({{}^{3}P}_{1}) \frac{1}{2}$	83%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	7%
	105 258			$* ({{}^{3}P}_{1}) \frac{3}{2}$	96%
	108 104			$({{}^{3}P}_{2}) \frac{3}{2}$	61%,	$({{}^{1}D}_{2}) \frac{3}{2}$	34%
	140 910			$({{}^{1}S}_{0}) \frac{1}{2}$	95%
$1 \frac{1}{2}$	77 409	77 380	−29	$({{}^{3}F}_{2}) \frac{1}{2}$	76%,	$* ({{}^{1}D}_{2}) \frac{1}{2}$	20%
	82 779			$({{}^{3}F}_{3}) \frac{3}{2}$	79%,	$* ({{}^{3}F}_{2}) \frac{3}{2}$	15%
	83 424	83 441	14	$* ({{}^{3}F}_{2}) \frac{3}{2}$	63%,	$* ({{}^{3}F}_{3}) \frac{3}{2}$	19%,	$({{}^{1}D}_{2}) \frac{3}{2}$	15%
	90 803			$({{}^{1}D}_{2}) \frac{1}{2}$	41%,	$* ({{}^{3}P}_{2}) \frac{1}{2}$	39%,	$({{}^{3}F}_{2}) \frac{1}{2}$	18%
	96 797			$({{}^{1}D}_{2}) \frac{3}{2}$	45%,	$* ({{}^{3}P}_{2}) \frac{3}{2}$	34%,	$({{}^{3}F}_{2}) \frac{3}{2}$	16%
	99 772			$({{}^{3}P}_{1}) \frac{1}{2}$	96%
	101 050			$({{}^{3}P}_{2}) \frac{1}{2}$	52%,	$({{}^{1}D}_{2}) \frac{1}{2}$	37%,	$({{}^{3}F}_{2}) \frac{1}{2}$	4%
	104 531			$* ({{}^{3}P}_{0}) \frac{3}{2}$	85%,	$({{}^{1}S}_{0}) \frac{3}{2}$	4%,	$({{}^{1}D}_{2}) \frac{3}{2}$	3%
	105 902			$({{}^{3}P}_{1}) \frac{3}{2}$	88%,	$({{}^{3}P}_{0}) \frac{3}{2}$	4%
	107 392			$({{}^{3}P}_{2}) \frac{3}{2}$	56%,	$({{}^{1}D}_{2}) \frac{3}{2}$	28%,	$* ({{}^{3}P}_{1}) \frac{3}{2}$	7%
	146 632			$({{}^{1}S}_{0}) \frac{3}{2}$	95%
$2 \frac{1}{2}$	73 859	73 853	−6	$({{}^{3}F}_{4}) \frac{3}{2}$	51%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	31%,	$({{}^{3}H}_{4}) \frac{3}{2}$	12%
	76 714	76 722	8	$({{}^{3}F}_{3}) \frac{1}{2}$	87%,	$({{}^{3}F}_{2}) \frac{1}{2}$	8%
	77 701	77 730	29	$({{}^{3}F}_{2}) \frac{1}{2}$	63%,	$* ({{}^{1}D}_{2}) \frac{1}{2}$	15%,	$* ({{}^{3}F}_{3}) \frac{1}{2}$	11%
	80 531	80 483	−48	$({{}^{3}H}_{4}) \frac{3}{2}$	57%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	26%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	7%
	82 577	82 573	−4	$* ({{}^{3}F}_{3}) \frac{3}{2}$	85%,	$* ({{}^{3}F}_{2}) \frac{3}{2}$	11%
	83 222	83 217	−5	$({{}^{3}F}_{2}) \frac{3}{2}$	64%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	17%,	$* ({{}^{3}F}_{3}) \frac{3}{2}$	15%
	89 072	89 077	5	$({{}^{1}G}_{4}) \frac{3}{2}$	55%,	$({{}^{3}H}_{4}) \frac{3}{2}$	25%,	$({{}^{3}F}_{4}) \frac{3}{2}$	13%
	91 002			$({{}^{1}D}_{2}) \frac{1}{2}$	40%,	$* ({{}^{3}P}_{2}) \frac{1}{2}$	37%,	$({{}^{3}F}_{2}) \frac{1}{2}$	17%
	96 237			$({{}^{1}D}_{2}) \frac{3}{2}$	41%,	$({{}^{3}P}_{2}) \frac{3}{2}$	38%,	$({{}^{3}F}_{2}) \frac{3}{2}$	19%
	101 171			$({{}^{3}P}_{2}) \frac{1}{2}$	59%,	$({{}^{1}D}_{2}) \frac{1}{2}$	35%
	104 935			$({{}^{3}P}_{1}) \frac{3}{2}$	90%
	106 571			$({{}^{3}P}_{2}) \frac{3}{2}$	55%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	31%,	$({{}^{3}P}_{1}) \frac{3}{2}$	10%
$3 \frac{1}{2}$	67 910	67 881	−29	$({{}^{3}F}_{4}) \frac{1}{2}$	62%,	$({{}^{1}G}_{4}) \frac{1}{2}$	30%
	74 058	74 059	1	$({{}^{3}F}_{4}) \frac{3}{2}$	54%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	26%
	74 908	74 882	−26	$({{}^{3}H}_{4}) \frac{1}{2}$	47%,	$({{}^{3}F}_{4}) \frac{1}{2}$	22%,	$* ({{}^{1}G}_{4}) \frac{1}{2}$	11%
	75 921	75 918	−3	$({{}^{3}H}_{5}) \frac{3}{2}$	55%,	$({{}^{3}F}_{3}) \frac{1}{2}$	19%,	$* ({{}^{3}H}_{4}) \frac{1}{2}$	10%
	77 390	77 397	7	$({{}^{3}F}_{3}) \frac{1}{2}$	73%,	$* ({{}^{3}H}_{5}) \frac{3}{2}$	26%
	81 032	81 011	−21	$({{}^{3}H}_{4}) \frac{3}{2}$	55%,	$* ({{}^{3}F}_{4}) \frac{3}{2}$	27%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	14%
	82 442	82 440	−2	$({{}^{3}F}_{3}) \frac{3}{2}$	95%
	83 678	83 672	−6	$({{}^{3}F}_{2}) \frac{3}{2}$	66%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	15%,	$({{}^{1}G}_{4}) \frac{1}{2}$	8%
	84 048	84 082	34	$({{}^{1}G}_{4}) \frac{1}{2}$	48%,	$({{}^{3}H}_{4}) \frac{1}{2}$	32%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	9%
	89 377	89 347	−30	$({{}^{1}G}_{4}) \frac{3}{2}$	56%,	$({{}^{3}H}_{4}) \frac{3}{2}$	34%
	96 794			$({{}^{1}D}_{2}) \frac{3}{2}$	42%,	$({{}^{3}P}_{2}) \frac{3}{2}$	39%,	$({{}^{3}F}_{2}) \frac{3}{2}$	18%
	107 120			$({{}^{3}P}_{2}) \frac{3}{2}$	59%,	$* ({{}^{1}D}_{2}) \frac{3}{2}$	37%
$4 \frac{1}{2}$	67 493	67 460	−33	$* ({{}^{3}H}_{6}) \frac{3}{2}$	45%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	35%,	$({{}^{1}G}_{4}) \frac{1}{2}$	15%
	68 855	68 854	−1	$({{}^{3}H}_{6}) \frac{3}{2}$	50%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	27%,	$({{}^{1}G}_{4}) \frac{1}{2}$	15%
	70 749	70 733	−16	$({{}^{3}H}_{5}) \frac{1}{2}$	95%
	73 646	73 657	11	$({{}^{3}F}_{4}) \frac{3}{2}$	60%,	$({{}^{1}G}_{4}) \frac{3}{2}$	26%,	$* ({{}^{3}H}_{4}) \frac{3}{2}$	7%
	75 069	75 089	20	$({{}^{3}H}_{4}) \frac{1}{2}$	55%,	$* ({{}^{3}F}_{4}) \frac{1}{2}$	27%,	$* ({{}^{1}G}_{4}) \frac{1}{2}$	10%
	76 826	76 807	−19	$({{}^{3}H}_{5}) \frac{3}{2}$	96%
	81 083	81 076	−7	$({{}^{3}H}_{4}) \frac{3}{2}$	56%,	$({{}^{3}F}_{4}) \frac{3}{2}$	24%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	15%
	82 797			$({{}^{3}F}_{3}) \frac{3}{2}$	95%
	83 557	83 597	40	$({{}^{1}G}_{4}) \frac{1}{2}$	55%,	$({{}^{3}H}_{4}) \frac{1}{2}$	32%,	$({{}^{3}F}_{4}) \frac{1}{2}$	10%
	89 738	89 706	−32	$({{}^{1}G}_{4}) \frac{3}{2}$	56%,	$({{}^{3}H}_{4}) \frac{3}{2}$	35%
	101 922			$({{}^{1}I}_{6}) \frac{3}{2}$	99%
$5 \frac{1}{2}$	62 123	62 064	−59	$({{}^{3}H}_{6}) \frac{1}{2}$	96%
	68 686	68 673	−13	$({{}^{3}H}_{6}) \frac{3}{2}$	92%
	70 692	70 725	33	$({{}^{3}H}_{5}) \frac{1}{2}$	96%
	73 872	73 910	38	$({{}^{3}F}_{4}) \frac{3}{2}$	60%,	$({{}^{1}G}_{4}) \frac{3}{2}$	30%
	77 071	77 058	−13	$({{}^{3}H}_{5}) \frac{3}{2}$	99%
	80 681	80 688	7	$* ({{}^{3}H}_{4}) \frac{3}{2}$	59%,	$({{}^{3}F}_{4}) \frac{3}{2}$	28%,	$* ({{}^{1}G}_{4}) \frac{3}{2}$	13%
	89 305			$({{}^{1}G}_{4}) \frac{3}{2}$	57%,	$* ({{}^{3}H}_{4}) \frac{3}{2}$	33%
	96 963			$({{}^{1}I}_{6}) \frac{1}{2}$	95%
	103 826			$({{}^{1}I}_{6}) \frac{3}{2}$	95%
$6 \frac{1}{2}$	62 563	62 573	10	$({{}^{3}H}_{6}) \frac{1}{2}$	99%
	68 856	68 839	−17	$({{}^{3}H}_{6}) \frac{3}{2}$	99%
	76 094	76 141	47	$({{}^{3}H}_{5}) \frac{3}{2}$	100%
	96 855			$({{}^{1}I}_{6}) \frac{1}{2}$	97%
	104 121			$({{}^{1}I}_{6}) \frac{3}{2}$	97%
$7 \frac{1}{2}$	67 627	67 716	89	$({{}^{3}H}_{6}) \frac{3}{2}$	99%
	102 095			$({{}^{1}I}_{6}) \frac{3}{2}$	99%

Classified lines of Tm iii

λ_air(Å)	Intensity	σ (cm⁻¹)	Classification

5867.482	3	17038.36	51634_9/2–68672°_11/2
4385.408	500	22796.49	8774°_5/2–31570_5/2
4361.570	50	22921.08	39142_11/2–62063°_11/2
4352.557	30	22968.54	39604_11/2–62572°_13/2
4348.948	10	22987.60	51071_7/2–74058°_7/2

4335.466	200	23059.09	45794_7/2–68853°_9/2
4332.201	20	23076.47	39496_13/2–62572°_13/2
4323.838	40	23121.10	45732_7/2–68853°_9/2
4322.316	8	23129.24	47603_11/2–70732°_9/2
4301.946	10	23238.76	52679_5/2–75918°_7/2

4275.104	80	23384.66	44496_7/2–67881°_7/2
4262.606	30	23453.23	38610_9/2–62063°_11/2
4256.137	40	23488.87	8774°_5/2–32262_7/2
4254.797	60	23496.27	50562_7/2–74058°_7/2
4180.125	20	23915.99	46816_9/2–70732°_9/2

4174.917	8	23945.82	46786_7/2–70732°_9/2
4146.028	5	24112.67	43768_5/2–67881°_7/2
4135.024	50	24176.84	44495_9/2–68672°_11/2
4119.920	80	24265.47	56217_5/2–80483°_5/2
4110.772	7	24319.47	50562_7/2–74882°_7/2

4104.273	60	24357.98	44495_9/2–68853°_9/2
4090.884	8	24437.70	43022_9/2–67460°_9/2
4079.313	20	24507.01	42952_11/2–67460°_9/2
4076.154	100	24526.00	50562_7/2–75088°_9/2
4040.640	9	24741.56	43139_7/2–67881°_7/2

4032.723	30	24790.14	42669_9/2–67460°_9/2
4032.132	700	24793.77	56217_5/2–81011°_7/2
4026.026	200	24831.37	8774°_5/2–33605_5/2
4021.925	200	24856.69	8774°_5/2–33630_7/2
4008.791	15	24938.13	45794_7/2–70732°_9/2

4004.323	30	24965.95	42915_5/2–67881°_7/2
3998.845	300	25000.15	45732_7/2–70732°_9/2
3993.328	50	25034.69	37028_9/2–62063°_11/2
3965.380	30	25211.13	42669_9/2–67881°_7/2
3958.732	30	25253.47	36810_11/2–62063°_11/2

3942.741	50	25355.89	50562_7/2–75918°_7/2
3932.236	10	25423.63	51634_9/2–77057°_11/2
3922.149	10	25489.01	55586_7/2–81075°_9/2
3897.486	40	25650.30	43022_9/2–68672°_11/2
3897.486	40	25650.30	51071_7/2–76721°_5/2

3890.782	60	25694.49	36369_13/2–62063°_11/2
3886.980	30	25719.62	42952_11/2–68672°_11/2
3884.488	10	25736.12	51071_7/2–76807°_9/2
3880.530	10	25762.37	51634_9/2–77396°_7/2
3867.187	50	25851.26	41864_13/2–67715°_15/2

3844.672	30	26002.65	42669_9/2–68672°_11/2
3821.697	20	26158.96	50562_7/2–76721°_5/2
3815.177	60	26203.67	36369_13/2–62572°_13/2
3811.568	60	26228.48	47624_5/2–73852°_5/2
3811.482	20	26229.07	44495_9/2–70724°_11/2

3810.419	40	26236.39	44496_7/2–70732°_9/2
3810.330	10	26237.00	44495_9/2–70732°_9/2
3799.407	100	26312.43	35751_9/2–62063°_11/2
3793.221	10	26355.34	56217_5/2–82573°_5/2
3781.838	40	26434.66	47624_5/2–74058°_7/2

3760.195	40	26586.81	47070_9/2–73657°_9/2
3751.606	6	26647.68	41233_7/2–67881°_7/2
3750.053	40	26658.71	51071_7/2–77729°_5/2
3729.130	5	26808.28	41864_13/2–68672°_11/2
3725.553	30	26834.02	50562_7/2–77396°_7/2

3724.850	6	26839.09	47070_9/2–73909°_11/2
3706.106	100	26974.82	41864_13/2–68839°_13/2
3702.772	50	26999.11	56217_5/2–83216°_5/2
3693.657	6	27065.74	46786_7/2–73852°_5/2
3685.336	50	27126.84	40754_5/2–67881°_7/2

3679.850	50	27167.29	50562_7/2–77729°_5/2
3672.248	40	27223.52	56217_5/2–83441°_3/2
3641.433	10	27453.89	56217_5/2–83671°_7/2
3637.296	6	27485.12	47603_11/2–75088°_9/2
3629.090	1000	27547.26	0°_7/2–27547_7/2

3623.040	50	27593.26	43139_7/2–70732°_9/2
3617.961	600	27632.00	8774°_5/2–36405_7/2
3607.719	60	27710.44	43022_9/2–70732°_9/2
3603.105	6	27745.93	34826_11/2–62572°_13/2
3599.739	4	27771.87	42952_11/2–70724°_11/2

3595.654	5	27803.42	52679_5/2–80483°_5/2
3588.892	6	27855.80	39604_11/2–67460°_9/2
3587.735	200	27864.79	56217_5/2–84082°_7/2
3580.039	60	27924.68	45732_7/2–73657°_9/2
3578.162	50	27939.33	34124_13/2–62063°_11/2

3569.073	15	28010.48	55586_7/2–83597°_9/2
3563.422	100	28054.90	42669_9/2–70724°_11/2
3562.411	300	28062.86	42669_9/2–70732°_9/2
3558.325	20	28095.09	46786_7/2–74882°_7/2
3555.164	60	28120.06	45732_7/2–73852°_5/2

3542.668	6	28219.25	39496_13/2–67715°_15/2
3537.466	100	28260.75	33802_11/2–62063°_11/2
3533.275	200	28294.27	47624_5/2–75918°_7/2
3532.350	20	28301.68	46786_7/2–75088°_9/2
3530.376	10	28317.50	39142_11/2–67460°_9/2

3529.289	200	28326.22	45732_7/2–74058°_7/2
3528.600	10	28331.75	52679_5/2–81011°_7/2
3513.586	6	28452.81	40400_9/2–68853°_9/2
3508.303	20	28495.66	55586_7/2–84082°_7/2
3496.250	200	28593.89	8774°_5/2–37367_7/2

3467.928	400	28827.41	33236_11/2–62063°_11/2
3465.461	2	28847.93	47070_9/2–75918°_7/2
3465.252	10	28849.67	38610_9/2–67460°_9/2
3463.947	10	28860.54	41864_13/2–70724°_11/2
3456.950	30	28918.95	39934_7/2–68853°_9/2

3439.187	4	29068.31	39604_11/2–68672°_11/2
3436.928	100	29087.41	45794_7/2–74882°_7/2
3415.963	100	29265.93	32797_9/2–62063°_11/2
3415.397	100	29270.78	38610_9/2–67881°_7/2
3407.727	200	29336.66	33236_11/2–62572°_13/2

3364.763	80	29711.24	39142_11/2–68853°_9/2
3325.475	30	30062.24	38610_9/2–68672°_11/2
3311.860	40	30185.82	45732_7/2–75918°_7/2
3290.087	8	30385.58	44496_7/2–74882°_7/2
3277.256	200	30504.54	8774°_5/2–39278_5/2
3259.663	10	30669.17	38003_9/2–68672°_11/2
3232.505	8	30926.83	45794 _7/2 –76721°_5/2
3222.172	20	31026.01	31037 _9/2 –62063°_11/2
3217.117	8	31074.76	45732 _7/2 –76807°_9/2
3201.280	30	31228.48	39496 _13/2–70724°_11/2

3199.149	50	31249.28	31323 _13/2–62572°_13/2
3189.231	30	31346.46	36369 _13/2–67715°_15/2
3183.509	20	31402.80	52679 _5/2 –84082°_7/2
3176.206	15	31475.00	36405 _7/2 –67881°_7/2
3170.875	20	31527.91	30535 _9/2 –62063°_11/2

3170.544	50	31531.20	30532 _11/2–62063°_11/2
3165.409	20	31582.35	39142 _11/2–70724°_11/2
3149.440	20	31742.48	43139 _7/2 –74882°_7/2
3141.291	20	31824.83	37028 _9/2 –68853°_9/2
3133.130	20	31907.72	30664 _15/2 –62572°_13/2

3130.420	10	31935.34	45794 _7/2 –77729°_5/2
3129.069	20	31949.13	43139 _7/2 –75088°_9/2
3124.350	20	31997.38	45732 _7/2 –77729°_5/2
3120.153	200	32040.42	30532 _11/2–62572°_13/2
3119.838	4	32043.66	36810 _11/2–68853°_9/2

3103.516	10	32212.17	42669 _9/2 –74882°_7/2
3080.983	5	32447.75	36405 _7/2 –68853°_9/2
3078.871	700	32470.01	36369 _13/2–68839°_13/2
3059.349	5	32677.19	38055 _7/2 –70732°_9/2
3049.849	10	32778.97	43139 _7/2 –75918°_7/2

3048.110	100	32797.68	0°_7/2 –32797 _7/2
3028.391	40	33011.22	51071 _7/2 –84082°_7/2
3020.407	5	33098.48	40754 _5/2 –73852°_5/2
3020.034	4	33102.57	35751 _9/2 –68853°_9/2
2998.285	1000	33342.68	28720 _13/2–62063°_11/2

2996.294	10	33364.83	37367 _7/2 –70732°_9/2
2982.429	5	33519.94	50562 _7/2 –84082°_7/2
2978.787	20	33560.92	43160 _3/2 –76721°_5/2
2976.914	20	33582.03	43139 _7/2 –76721°_5/2
2974.846	100	33605.38	0°_7/2 –33605_5/2

2973.773	6	33617.50	47070 _9/2 –80688°_11/2
2972.608	400	33630.68	0°_7/2 –33630_7/2
2971.018	20	33648.67	41233 _7/2 –74882°_7/2
2966.849	500	33695.95	37028 _9/2 –70724°_11/2
2966.150	100	33703.89	37028 _9/2 –70732°_9/2

2957.150	30	33806.47	42915 _5/2 –76721°_5/2
2953.178	500	33851.93	28720 _13/2–62572°_13/2
2952.961	3	33854.42	42952 _11/2–76807°_9/2
2947.716	1000	33914.66	36810 _11/2–70724°_11/2
2947.023	200	33922.63	36810 _11/2–70732°_9/2

2939.857	10	34005.32	47070 _9/2 –81075°_9/2
2939.251	10	34012.33	34826 _11/2–68839°_13/2
2937.994	60	34026.88	34826 _11/2–68853°_9/2
2929.305	20	34127.80	40754 _5/2 –74882°_7/2
2928.479	15	34137.43	42669 _9/2 –76807°_9/2

2925.157	20	34176.20	39882 _7/2 –74058°_7/2
2921.463	20	34219.41	43160 _3/2 –77379°_3/2
2921.082	400	34223.87	33236 _11/2–67460°_9/2
2916.673	20	34275.60	33605 _5/2 –67881°_7/2
2912.327	100	34326.75	36405 _7/2 –70732°_9/2

2908.297	80	34374.32	43022 _9/2 –77396°_7/2
2907.259	40	34386.59	8774° _5/2 –43160 _3/2
2905.003	80	34413.29	39496 _13/2–73909°_11/2
2900.653	10	34464.90	42915 _5/2 –77379°_3/2
2899.287	100	34481.13	40400 _9/2 –74882°_7/2

2891.494	20	34574.06	39278 _5/2 –73852°_3/2
2882.019	700	34687.72	40400 _9/2 –75088°_9/2
2879.756	20	34714.98	34124 _13/2 –68839°_13/2
2878.785	50	34726.69	42669 _9/2 –77396°_7/2
2871.496	10	34814.83	42915 _5/2 –77729°_5/2

2869.364	10	34840.70	33831 _9/2 –68672°_11/2
2856.353	10	34999.40	39882 _7/2 –74882°_7/2
2849.515	200	35083.38	32797 _9/2 –67881°_7/2
2842.956	5	35164.32	40754 _5/2 –75918°_7/2
2838.715	5	35216.85	45794 _7/2 –81011°_7/2

2838.215	50	35223.05	33630 _7/2 –68853°_9/2
2833.725	10	35278.86	45732 _7/2 –81011°_7/2
2828.563	10	35343.24	45732 _7/2 –81075°_9/2
2821.125	300	35436.42	33236 _11/2–68672°_11/2
2817.021	40	35488.04	41233 _7/2 –76721°_5/2

2814.676	10	35517.61	40400 _9/2 –75918°_7/2
2808.742	10	35592.64	47624 _5/2 –83216°_5/2
2806.768	2000	35617.67	33236 _11/2–68853°_9/2
2803.914	30	35653.93	38003 _9/2 –73657°_9/2
2798.543	10	35722.35	8774°_5/2 –44496 _7/2

2796.288	80	35751.16	0°_7/2 –35751_9/2
2786.641	40	35874.92	32797 _9/2 –68672°_11/2
2784.845	50	35898.05	34826 _11/2–70724°_11/2
2781.121	400	35946.12	39142 _11/2–75088°_9/2
2779.481	7	35967.32	40754 _5/2 –76721°_5/2

2778.209	10	35983.79	39934 _7/2 –75918°_7/2
2777.973	5	35986.85	44496 _7/2 –80483°_5/2
2777.431	100	35993.87	47603 _11/2–83597°_9/2
2774.194	20	36035.87	39882 _7/2 –75918°_7/2
2772.642	200	36056.04	32797 _9/2 –68853°_9/2

2769.924	700	36091.42	31368 _7/2 –67460°_9/2
2765.985	800	36142.81	25920 _11/2–62063°_11/2
2764.423	4	36163.23	41233 _7/2 –77396°_7/2
2756.154	400	36271.72	38610 _9/2 –74882°_7/2
2754.811	15	36289.40	37367 _7/2 –73657°_9/2

2753.205	400	36310.57	31570 _5/2 –67881°_7/2
2752.645	5	36317.96	40403_3/2 –76721°_5/2
2752.463	500	36320.36	26252 _11/2–62572°_13/2
2746.663	2	36397.05	52679 _5/2 –89076°_5/2
2745.989	400	36405.98	0°_7/2 –36405_7/2

2744.741	800	36422.54	31037 _9/2 –67460°_9/2
2740.059	20	36484.77	37367 _7/2 –73852°_5/2
2739.172	5	36496.58	41233 _7/2 –77729°_5/2
2737.978	400	36512.50	31368 _7/2 –67881°_7/2
2736.190	4	36536.36	39604 _11/2–76140°_13/2

2732.919	4	36580.08	44495 _9/2 –81075°_9/2
2732.113	300	36590.88	32262 _7/2 –68853°_9/2
2731.380	1000	36600.69	34124 _13/2–70724°_11/2
2729.506	10	36625.82	40754 _5/2 –77379°_3/2
2728.456	80	36639.92	39278 _5/2 –75918°_7/2

2728.266	20	36642.47	40754 _5/2 –77396°_7/2
2728.130	200	36644.29	39496 _13/2–76140°_13/2
2727.558	4000	36651.98	25920 _11/2–62572°_13/2
2724.439	3000	36693.94	25878 _15/2–62572°_13/2
2723.437	4	36707.44	45732 _7/2 –82440°_7/2

2719.473	3000	36760.94	25302 _13/2–62063°_11/2
2718.020	100	36780.59	46816 _9/2 –83597°_9/2
2717.559	300	36786.83	39934 _7/2 –76721°_5/2
2715.813	200	36810.48	46786 _7/2 –83597°_9/2
2714.632	70	36826.49	38055 _7/2 –74882°_7/2

2713.719	80	36838.88	39882 _7/2 –76721°_5/2
2713.375	1000	36843.55	31037 _9/2 –67881°_7/2
2710.788	200	36878.71	38003 _9/2 –74882°_7/2
2709.743	1000	36892.93	33831 _9/2 –70724°_11/2
2707.602	500	36922.10	33802 _11/2–70724°_11/2

2707.436	200	36924.37	30535 _9/2 –67460°_9/2
2707.192	300	36927.69	30532 _11/2–67460°_9/2
2707.027	2000	36929.94	33802 _11/2–70732°_9/2
2704.928	100	36958.60	8774°_5/2 –45732_7/2
2703.675	200	36975.73	40754 _5/2 –77729°_5/2

2703.630	100	36976.34	40403 _3/2 –77379°_3/2
2699.795	1000	37028.86	0°_7/2 –37028_9/2
2699.489	1000	37033.06	38055 _7/2 –75088°_9/2
2698.209	400	37050.63	30664 _15/2–67715°_15/2
2695.687	300	37085.29	38003 _9/2 –75088°_9/2

2687.144	300	37203.18	39604 _11/2–76807°_9/2
2682.635	300	37265.71	46816 _9/2 –84082°_7/2
2682.320	5000	37270.09	25302 _13/2–62572°_13/2
2680.488	100	37295.56	46786 _7/2 –84082°_7/2
2678.547	80	37322.58	43160 _3/2 –80483°_5/2

2678.279	100	37326.32	40403 _3/2 –77729°_5/2
2676.911	500	37345.39	30535 _9/2 –67881°_7/2
2676.641	1000	37349.16	31323 _13/2–68672°_11/2
2675.297	100	37367.92	0°_7/2 –37367_7/2
2671.418	100	37422.18	45794 _7/2 –83216°_5/2

2669.940	80	37442.89	39278 _5/2 –76721°_5/2
2669.668	40	37446.71	36405 _7/2 –73852°_5/2
2669.181	200	37453.54	39604 _11/2–77057°_11/2
2668.655	100	37460.92	36391 _5/2 –73852°_5/2
2668.588	200	37461.86	39934 _7/2 –77396°_7/2

2666.930	1000	37485.15	31368 _7/2 –68853°_9/2
2666.676	60	37488.72	33236 _11/2–70724°_11/2
2666.108	20	37496.71	33236 _11/2–70732°_9/2
2664.875	500	37514.06	37367 _7/2 –74882°_7/2
2664.875	500	37514.06	39882 _7/2 –77396°_7/2

2664.756	500	37515.73	31323 _13/2–68839°_13/2
2662.996	1000	37540.52	36369 _13/2–73909°_11/2
2661.510	500	37561.48	39496 _13/2–77057°_11/2
2661.039	20	37568.13	42915 _5/2 –80483°_5/2
2656.305	100	37635.08	31037 _9/2 –68672°_11/2

2655.048	200	37652.90	36405 _7/2 –74058°_7/2
2654.201	50	37664.91	39142 _11/2–76807°_9/2
2654.046	100	37667.11	36391 _5/2 –74058°_7/2
2650.824	100	37712.89	51634 _9/2 –89347°_7/2
2649.269	200	37735.02	42952 _11/2–80688°_11/2

2645.049	100	37795.23	39934 _7/2 –77729°_5/2
2643.580	500	37816.23	31037 _9/2 –68853°_9/2
2640.999	40	37853.18	37028 _9/2 –74882°_7/2
2640.317	100	37862.96	38055 _7/2 –75918°_7/2
2640.194	40	37864.72	45732 _7/2 –83597°_9/2

2639.340	30	37876.97	45794 _7/2 –83671°_7/2
2637.303	200	37906.23	35751 _9/2 –73657°_9/2
2636.683	200	37915.14	38003_9/2 –75918°_7/2
2634.664	300	37944.19	44495 _9/2 –82440°_7/2
2630.558	90	38003.42	0°_7/2 –38003 _9/2

2630.410	60	38005.56	51071 _7/2 –89076°_5/2
2627.088	100	38053.61	43022 _9/2 –81075°_9/2
2626.959	30	38055.48	0°_7/2 –38055_7/2
2625.827	100	38071.88	51634 _9/2 –89706°_9/2
2625.496	50	38076.68	44496 _7/2 –82573°_5/2

2624.136	40	38096.42	42915 _5/2 –81011°_7/2
2623.790	10	38101.44	39278 _5/2 –77379°_3/2
2622.645	15	38118.07	39278 _5/2 –77396°_7/2
2622.310	400	38122.94	42952 _11/2–81075°_9/2
2621.348	400	38136.93	30535 _9/2 –68672°_11/2

2621.117	1000	38140.29	30532 _11/2–68672°_11/2
2619.867	20	38158.49	35751 _9/2 –73909°_11/2
2618.785	500	38174.25	30664 _15/2–68839°_13/2
2617.221	500	38197.06	38610 _9/2 –76807°_9/2
2611.649	40	38278.55	36810 _11/2–75088°_9/2

2609.722	20	38306.82	30532 _11/2–68839°_13/2
2609.663	300	38307.68	35751 _9/2 –74058°_7/2
2608.961	500	38317.99	30535 _9/2 –68853°_9/2
2593.220	50	38550.57	37367 _7/2 –75918°_7/2
2589.204	300	38610.36	0°_7/2 –38610_9/2

2585.480	100	38665.97	38055 _7/2 –76721°_5/2
2585.099	40	38671.66	43768 _5/2 –82440°_7/2
2581.841	100	38720.46	44496 _7/2 –83216°_5/2
2574.976	500	38823.69	41864 _13/2–80688°_11/2
2574.522	1000	38830.53	34826 _11/2–73657°_9/2

2557.905	500	39082.77	34826 _11/2–73909°_11/2
2552.463	10000	39166.09	22897 _9/2 –62063°_11/2
2519.775	3000	39674.14	36466 _15/2–76140°_13/2
2504.713	2000	39912.71	27547 _7/2 –67460°_9/2
2489.437	30000	40157.61	27557 _17/2–67715°_15/2

2471.232	500	40453.42	33605 _5/2 –74058°_7/2
2457.859	500	40673.51	33236 _11/2–73909°_11/2
2435.307	500	41050.13	33831 _9/2 –74882°_7/2
2406.630	4000	41539.24	25920 _11/2–67460°_9/2
2389.515	400	41836.75	25878 _15/2–67715°_15/2

2375.830	700	42077.71	38610 _9/2 –80688°_11/2
2375.325	1000	42086.66	33831 _9/2 –75918°_7/2
2363.973	500	42288.74	31368 _7/2 –73657°_9/2
2361.234	1000	42337.79	33802 _11/2–76140°_13/2
2357.049	3000	42412.96	25302 _13/2–67715°_15/2

2355.646	100	42438.22	41233 _7/2 –83671°_7/2
2353.102	400	42484.09	31368 _7/2 –73852°_5/2
2349.048	90	42557.41	39882 _7/2 –82440°_7/2
2348.897	80	42560.14	46786 _7/2 –89347°_7/2
2347.462	60	42586.16	31323 _13/2–73909°_11/2
2347.430	300	42586.74	26252 _11/2–68839°_13/2
2345.607	500	42619.83	31037 _9/2 –73657°_9/2
2344.742	3	42635.56	47070 _7/2 –89706°_9/2
2344.590	100	42638.32	39934 _7/2 –82573°_5/2
2342.853	40	42669.93	0°_7/2 –42669 _9/2

2342.045	300	42684.65	38003 _9/2 –80688°_11/2
2341.910	20	42687.11	40754 _5/2 –83441°_3/2
2341.736	500	42690.28	31368 _7/2 –74058°_7/2
2338.365	1000	42751.82	25920 _11/2–68672°_11/2
2335.010	400	42813.24	40403 _3/2 –83216°_5/2

2333.053	20	42849.15	41233 _7/2 –84082°_7/2
2331.804	3000	42872.10	31037 _9/2 –73909°_11/2
2330.869	200	42889.30	46816 _9/2 –89706°_9/2
2330.046	40	42904.44	33236 _11/2–76140°_13/2
2329.465	20	42915.14	0°_7/2 –42915 _5/2

2329.343	20	42917.39	40754 _5/2 –83671°_7/2
2329.289	6000	42918.38	25920 _11/2–68839°_13/2
2328.497	6000	42932.98	25920 _11/2–68853°_9/2
2327.251	300	42955.97	38055 _7/2 –81011°_7/2
2327.015	100	42960.32	25878 _15/2–68839°_13/2

2326.192	5000	42975.52	33831 _9/2 –76807°_9/2
2324.621	500	43004.56	33802 _11/2–76807°_9/2
2324.429	100	43008.11	38003 _9/2 –81011°_7/2
2323.769	100	43020.33	38055 _7/2 –81075°_9/2
2323.713	100	43021.36	31037 _9/2 –74058°_7/2

2322.833	200	43037.66	40403 _3/2 –83441°_3/2
2320.955	500	43072.48	38003 _9/2 –81075°_9/2
2319.967	3	43090.82	33630 _7/2 –76721°_5/2
2318.654	40	43115.22	37367 _7/2 –80483°_5/2
2318.608	40	43116.08	33605 _5/2 –76721°_5/2

2318.354	10	43120.80	32797 _9/2 –75918°_7/2
2318.308	40	43121.66	30535 _9/2 –73657°_9/2
2318.128	40	43125.00	30532 _11/2–73657°_9/2
2317.350	400	43139.48	0°_7/2 –43139 _7/2
2316.170	20	43161.46	39278 _5/2 –82440°_7/2

2315.355	40	43176.65	33630 _7/2 –76807°_9/2
2314.881	200	43185.49	27547 _7/2 –70732°_9/2
2312.720	5000	43225.84	33831 _9/2 –77057°_11/2
2311.162	20000	43254.98	33802 _11/2–77057°_11/2
2310.322	10	43270.70	40400 _9/2 –83671°_7/2

2309.715	60	43282.07	39934 _7/2 –83216°_5/2
2309.056	3	43294.42	39278 _5/2 –82573°_5/2
2307.249	8	43328.33	40754 _5/2 –84082°_7/2
2306.404	60	43344.20	45732 _7/2 –89076°_5/2
2305.033	5000	43369.98	25302 _13/2–68672°_11/2

2304.821	400	43373.97	30535 _9/2 –73909°_11/2
2304.644	100	43377.30	30532 _11/2–73909°_11/2
2297.433	200	43513.44	31368 _7/2 –74882°_7/2
2296.214	20000	43536.53	25302 _13/2–68839°_13/2
2294.728	500	43564.72	33831 _9/2 –77396°_7/2

2292.108	80	43614.52	45732 _7/2 –89347°_7/2
2289.760	8	43659.24	37028 _9/2 –80688°_11/2
2289.578	10	43662.71	39934 _7/2 –83597°_9/2
2287.208	400	43707.95	37367 _7/2 –81075°_9/2
2286.574	200	43720.06	31368 _7/2 –75088°_9/2

2285.694	40	43736.89	39934 _7/2 –83671°_7/2
2284.175	4	43765.98	33630 _7/2 –77396°_7/2
2284.046	80	43768.45	0°_7/2 –43768 _5/2
2282.977	200	43788.94	39882 _7/2 –83671°_7/2
2282.857	100	43791.24	33605 _5/2 –77396°_7/2

2281.272	100	43821.67	33236 _11/2 –77057°_11/2
2280.852	40	43829.73	38610 _9/2 –82440 °_7/2
2280.082	100	43844.54	31037 _9/2–74882°_7/2
2276.907	1000	43905.67	8774°_5/2 –52679 _5/2
2269.389	200	44051.10	31037 _9/2 –75088°_9/2

2267.313	3	44091.43	36391 _5/2 –80483°_5/2
2263.655	7	44162.68	39278 _5/2 –83441°_3/2
2261.751	20	44199.85	39882 _7/2 –84082°_7/2
2258.672	10	44260.10	32797 _9/2 –77057°_11/2
2255.674	70	44318.92	36369 _13/2–80688°_11/2

2254.197	80	44347.96	31570 _5/2 –75918°_7/2
2249.696	40	44436.68	38003 _9/2 –82440°_7/2
2248.587	4	44458.59	32262 _7/2 –76721°_5/2
2247.486	10	44480.37	26252 _11/2–70732°_9/2
2246.704	30	44495.85	0°_7/2 –44495 _9/2

2246.678	200	44496.36	0°_7/2 –44496 _7/2
2243.981	400	44549.84	31368 _7/2 –75918°_7/2
2243.656	20	44556.29	30532 _11/2–75088°_9/2
2243.341	200	44562.54	22897 _9/2 –67460°_9/2
2242.442	15	44580.41	44496 _7/2 –89076°_5/2

2241.179	7	44605.53	36405 _7/2 –81011°_7/2
2237.949	10	44669.90	36405 _7/2 –81075°_9/2
2231.247	400	44804.06	25920 _11/2–70724°_11/2
2230.855	300	44811.93	25920 _11/2–70732°_9/2
2230.597	15	44817.12	31323 _13/2–76140°_13/2

2228.926	7	44850.71	44496 _7/2 –89347°_7/2
2224.651	4	44936.89	35751 _9/2 –80688°_11/2
2217.974	3	45072.16	37367 _7/2 –82440°_7/2
2213.598	40	45161.25	38055 _7/2 –83216°_5/2
2212.250	100	45188.76	28720 _13/2–73909°_11/2

2211.195	5	45210.32	44495 _9/2 –89706°_9/2
2206.406	7	45308.44	43768 _5/2 –89076°_5/2
2205.614	10	45324.71	35751 _9/2 –81075°_9/2
2200.881	80	45422.17	25302 _13/2–70724°_11/2
2200.078	2	45438.75	31368 _7/2 –76807°_9/2

2198.296	10	45475.58	30664 _15/2–76140°_13/2
2192.587	40	45593.97	38003 _9/2 –83597°_9/2
2191.902	20	45608.22	30532 _11/2–76140°_13/2
2191.526	10	45616.04	38055 _7/2 –83671°_7/2
2185.939	5000	45732.62	0°_7/2 –45732 _7/2

2183.910	300	45775.11	22897 _9/2 –68672°_11/2
2182.980	800	45794.60	0°_7/2 –45794 _7/2
2182.271	10	45809.48	31570 _5/2 –77379°_3/2
2179.807	3	45861.26	34826 _11/2–80688°_11/2
2175.298	10	45956.31	22897 _9/2 –68853°_9/2

2168.040	20	46110.14	27547 _7/2 –73657°_9/2
2165.363	5	46167.14	36405 _7/2 –82573°_5/2
2158.898	20	46305.38	27547 _7/2 –73852°_5/2
2156.289	200	46361.40	31368 _7/2 –77729°_5/2
2149.324	8	46511.62	27547 _7/2 –74058°_7/2

2148.843	60	46522.03	30535 _9/2–77057°_11/2
2148.685	20	46525.45	30532 _11/2–77057°_11/2
2136.674	200	46786.96	0°_7/2 –16786 _7/2
2135.491	3	46812.87	8774°_5/2 –55586 _7/2
2135.308	1	46816.88	0°_7/2 –46816 _9/2

2123.800	40	47070.54	0°_7/2 –47070 _9/2
2118.893	1	47179.53	33831 _9/2 –81011°_7/2

2108.815	1	47404.97	26252 _11/2–73657°_9/2
2107.096	500	47443.64	8774°_5/2 56217 _5/2
2102.761	1	47541.44	27547 _7/2 –75088°_9/2
2099.109	500	47624.14	0°_7/2 –47624 _5/2
2096.799	1	47676.60	36405 _7/2 –84082°_7/2

2083.153	4	47988.87	25920 _11/2–73909°_11/2
1977.106	40	50562.50	0°_7/2 –50562 _7/2

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Librarians

Configuration	Designation	J	Energy/hc (cm⁻¹)
4f¹³	²F°	$3 \frac{1}{2}$	0.00
		$2 \frac{1}{2}$	8 774.02
4f¹²5d	$({{}^{3}H}_{6}) \frac{3}{2}$	$4 \frac{1}{2}$	22 897.47
		$7 \frac{1}{2}$	25 878.84
		$5 \frac{1}{2}$	26 252.40
		$6 \frac{1}{2}$	28 720.87
4f¹²6s	$({{}^{3}H}_{6}) \frac{1}{2}$	$6 \frac{1}{2}$	25 302.65
		$5 \frac{1}{2}$	25 920.78
4f¹²5d	$({{}^{3}H}_{6}) \frac{5}{2}$	$3 \frac{1}{2}$	27 457.25
		$8 \frac{1}{2}$	27 557.98
		$5 \frac{1}{2}$	30 532.34
		$4 \frac{1}{2}$	30 535.69
		$7 \frac{1}{2}$	30 664.98
		$6 \frac{1}{2}$	31 323.46
4f¹²6s	$({{}^{3}F}_{4}) \frac{1}{2}$	$4 \frac{1}{2}$	31 037.52
		$3 \frac{1}{2}$	31 368.59
4f¹²5d	$({{}^{3}F}_{4}) \frac{3}{2}$	$2 \frac{1}{2}$	31 570.50
		$3 \frac{1}{2}$	32 262.88
		$4 \frac{1}{2}$	32 797.68
		$5 \frac{1}{2}$	33 236.12
	$({{}^{3}H}_{5}) \frac{3}{2}$	$3 \frac{1}{2}$	33 630.68
		$6 \frac{1}{2}$	34 124.20
		$5 \frac{1}{2}$	36 810.12
		$4 \frac{1}{2}$	37 028.88
	$({{}^{3}H}_{5}) \frac{5}{2}$	$2 \frac{1}{2}$	33 605.40
		$3 \frac{1}{2}$	36 405.98
		$7 \frac{1}{2}$	36 466.44
		$4 \frac{1}{2}$	38 610.32
		$6 \frac{1}{2}$	39 496.32
		$5 \frac{1}{2}$	39 604.23
4f¹²6s	$({{}^{3}H}_{5}) \frac{1}{2}$	$5 \frac{1}{2}$	33 802.80
		$4 \frac{1}{2}$	33 831.91
4f¹²5d	$({{}^{3}F}_{4}) \frac{5}{2}$	$5 \frac{1}{2}$	34 826.83
		$4 \frac{1}{2}$	35 751.15
		$6 \frac{1}{2}$	36 369.12
		$3 \frac{1}{2}$	37 367.92
		$1 \frac{1}{2}$
		$2 \frac{1}{2}$	39 278.57
	$({{}^{3}H}_{4}) \frac{3}{2}$	$2 \frac{1}{2}$	36 391.74
		$5 \frac{1}{2}$	39 142.50
		$4 \frac{1}{2}$	40 400.90
		$3 \frac{1}{2}$	45 732.62
4f¹²6s	$({{}^{3}H}_{4}) \frac{1}{2}$	$4 \frac{1}{2}$	38 003.36
		$3 \frac{1}{2}$	38 055.53
	$({{}^{3}F}_{3}) \frac{1}{2}$	$2 \frac{1}{2}$
		$3 \frac{1}{2}$	39 882.62
	$({{}^{3}F}_{2}) \frac{1}{2}$	$1 \frac{1}{2}$	40 403.59
		$2 \frac{1}{2}$	40 754.18
4f¹²5d	$({{}^{3}F}_{3}) \frac{3}{2}$	$3 \frac{1}{2}$	39 934.71
		$4 \frac{1}{2}$	42 669.92
		$2 \frac{1}{2}$	42 915.07
		$1 \frac{1}{2}$	43 160.58
	$({{}^{3}F}_{2}) \frac{3}{2}$	$2 \frac{1}{2}$
		$1 \frac{1}{2}$
		$3 \frac{1}{2}$	41 233.38
		$\frac{1}{2}$
	$({{}^{3}H}_{4}) \frac{5}{2}$	$1 \frac{1}{2}$
		$2 \frac{1}{2}$
		$6 \frac{1}{2}$	41 864.33
		$5 \frac{1}{2}$	42 952.97
		$4 \frac{1}{2}$	43 022.30
		$3 \frac{1}{2}$	45 794.62
	$({{}^{3}F}_{3}) \frac{5}{2}$	$3 \frac{1}{2}$	43 139.50
		$2 \frac{1}{2}$	43 768.40
		$4 \frac{1}{2}$	44 495.79
		$1 \frac{1}{2}$
		$5 \frac{1}{2}$
		$\frac{1}{2}$
	$({{}^{3}F}_{2}) \frac{5}{2}$	$3 \frac{1}{2}$	44 496.38
		$\frac{1}{2}$
		$1 \frac{1}{2}$
		$4 \frac{1}{2}$	47 070.54
		$2 \frac{1}{2}$	47 624.18
4f¹²6s	$({{}^{1}G}_{4}) \frac{1}{2}$	$3 \frac{1}{2}$	46 786.94
		$4 \frac{1}{2}$	46 816.79
4f¹²5d	$({{}^{1}G}_{4}) \frac{3}{2}$	$5 \frac{1}{2}$	47 603.51
		$4 \frac{1}{2}$
		$3 \frac{1}{2}$	51 071.25
		$2 \frac{1}{2}$	52 679.70
	$({{}^{1}G}_{4}) \frac{5}{2}$	$3 \frac{1}{2}$	50 562.58
		$4 \frac{1}{2}$	51 634.22
	$({{}^{1}D}_{2}) \frac{3}{2}$	$2 \frac{1}{2}$	56 217.70
	$({{}^{1}D}_{2}) \frac{5}{2}$	$3 \frac{1}{2}$	55 586.87
4f¹²6p	$({{}^{3}H}_{6}) \frac{1}{2} °$	$5 \frac{1}{2}$	62 063.57
		$6 \frac{1}{2}$	62 572.76
	$({{}^{3}H}_{6}) \frac{3}{2} °$	$4 \frac{1}{2}$	67 460.01
		$7 \frac{1}{2}$	67 715.59
		$5 \frac{1}{2}$	68 672.59
		$6 \frac{1}{2}$	68 839.17
	$({{}^{3}F}_{4}) \frac{1}{2} °$	$3 \frac{1}{2}$	67 881.05
		$4 \frac{1}{2}$	68 853.73
	$({{}^{3}H}_{5}) \frac{1}{2} °$	$5 \frac{1}{2}$	70 724.84
		$4 \frac{1}{2}$	70 732.76
	$({{}^{3}F}_{4}) \frac{3}{2} °$	$4 \frac{1}{2}$	73 657.35
		$2 \frac{1}{2}$	73 852.67
		$5 \frac{1}{2}$	73 909.63
		$3 \frac{1}{2}$	74 058.85
	$({{}^{3}H}_{4}) \frac{1}{2} °$	$3 \frac{1}{2}$	74 882.03
		$4 \frac{1}{2}$	75 088.63
	$(^{3} H_{5}) \frac{3}{2} °$	$3 \frac{1}{2}$	75 918.48
		$6 \frac{1}{2}$	76 140.58
		$4 \frac{1}{2}$	76 807.38
		$5 \frac{1}{2}$	77 057.78
	$({{}^{3}F}_{3}) \frac{1}{2} °$	$2 \frac{1}{2}$	76 721.50
		$3 \frac{1}{2}$	77 396.62
	$({{}^{3}F}_{2}) \frac{1}{2} °$	$1 \frac{1}{2}$	77 379.98
		$2 \frac{1}{2}$	77 729.94
	$({{}^{3}H}_{4}) \frac{3}{2} °$	$2 \frac{1}{2}$	80 483.17
		$5 \frac{1}{2}$	80 688.04
		$3 \frac{1}{2}$	81 011.48
		$4 \frac{1}{2}$	81 075.87
	$({{}^{3}F}_{3}) \frac{3}{2} °$	$3 \frac{1}{2}$	82 440.04
		$2 \frac{1}{2}$	82 573.05
		$1 \frac{1}{2}$
		$4 \frac{1}{2}$
	$({{}^{3}F}_{2}) \frac{3}{2} °$	$2 \frac{1}{2}$	83 216.81
		$\frac{1}{2}$
		$1 \frac{1}{2}$	83 441.25
		$3 \frac{1}{2}$	83 671.59
	$({{}^{1}G}_{4}) \frac{1}{2} °$	$4 \frac{1}{2}$	83 597.38
		$3 \frac{1}{2}$	84 082.50
	$({{}^{1}G}_{4}) \frac{3}{2} °$	$2 \frac{1}{2}$	89 076.80
		$5 \frac{1}{2}$
		$3 \frac{1}{2}$	89 347.11
		$4 \frac{1}{2}$	89 706.10

Abstract

Cited By

Figures (5)

Tables (6)

Equations (1)

Journal of the Optical Society of America