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Journal of the Optical Society of America

Journal of the Optical Society of America

  • Vol. 40, Iss. 7 — Jul. 1, 1950
  • pp: 438–440

Raman Spectrum of 1,3-Butadiene in the Gaseous and Liquid States

CHARLES M. RICHARDS and J. RUD NIELSEN  »View Author Affiliations


JOSA, Vol. 40, Issue 7, pp. 438-440 (1950)
http://dx.doi.org/10.1364/JOSA.40.000438


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Abstract

The Raman spectrum of gaseous 1,3-butadiene has been photographed with a three-prism glass spectrograph of linear dispersion 15 A/mm near 4358A. Polarization data have been obtained for the liquid. The observed Raman spectrum has been interpreted in some detail in terms of a planar trans-configuration of the molecule. Two fundamentals have been added to previous assignments, and several assignments have been made more specific. It is concluded that at room temperature a small fraction of the molecules have a cis-configuration.

Citation
CHARLES M. RICHARDS and J. RUD NIELSEN, "Raman Spectrum of 1,3-Butadiene in the Gaseous and Liquid States," J. Opt. Soc. Am. 40, 438-440 (1950)
http://www.opticsinfobase.org/josa/abstract.cfm?URI=josa-40-7-438

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