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Journal of the Optical Society of America

Journal of the Optical Society of America

  • Vol. 58, Iss. 7 — Jul. 1, 1968
  • pp: 924–932

Theoretical Study of pm-pm-1l Spectra

ROBERT D. COWAN  »View Author Affiliations


JOSA, Vol. 58, Issue 7, pp. 924-932 (1968)
http://dx.doi.org/10.1364/JOSA.58.000924


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Abstract

Theoretical calculation of energy levels and spectra ab nitio are described forinitio transitions of the type pm-pm-1l, especially 3pm-3pm-13d transitions in the Ar I and Cl I isoelectronic sequences. Strong changes of wvavefunction composition occur in going from neutral atoms to ions as a result of collapse of the 3d wavefunction; for m = 2 and 6 these take the form of coupling changes, and for m = 3-5 they take the form of changes of parentage composition. Abnormally low Ti v 3p6-3p54d intensities are explained as an interference effect in evaluation of the dipole radial integral.

Citation
ROBERT D. COWAN, "Theoretical Study of pm-pm-1l Spectra," J. Opt. Soc. Am. 58, 924-932 (1968)
http://www.opticsinfobase.org/josa/abstract.cfm?URI=josa-58-7-924

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