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Journal of the Optical Society of America

Journal of the Optical Society of America

  • Vol. 59, Iss. 7 — Jul. 1, 1969
  • pp: 827–828

Energy-Dependent Slater Integrals

MICHAEL WILSON and MARK FRED  »View Author Affiliations


JOSA, Vol. 59, Issue 7, pp. 827-828 (1969)
http://dx.doi.org/10.1364/JOSA.59.000827


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Abstract

Data are presented from Hartree-Fock calculations and from empirical level fitting showing a linear decrease with energy in the various radial integrals which describe Coulomb repulsion and spin-orbit interaction of atomic electrons.

Citation
MICHAEL WILSON and MARK FRED, "Energy-Dependent Slater Integrals," J. Opt. Soc. Am. 59, 827-828 (1969)
http://www.opticsinfobase.org/josa/abstract.cfm?URI=josa-59-7-827


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References

  1. E. U. Condon and G. H. Shortley, The Theory of Atomic Spectra (Cambridge University Press, Cambridge, 1935), Ch. IV.
  2. J. C. Slater, Quantum Theory of Atomic Structure (McGraw-Hill Book Co., New York, 1960).
  3. C. Froese, J. Chem. Phys. 45, 1417 (1966).
  4. M. Blume and R. E. Watson, Proc. Roy. Soc. (London) A270, 127 (1962); M. Wilson, J. Opt. Soc. Am. 58, 855 (1968).
  5. B. G. Wybourne, Spectroscopic Properties of Rare Earths (John Wiley & Sons, Inc., New York, 1965), p. 82.
  6. M. G. Mayer, Phys. Rev. 60, 184 (1941). Cf. Ref. 2, Vol. I, p. 225 for the change of the d well in the transition elements.

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