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Journal of the Optical Society of America

Journal of the Optical Society of America

  • Vol. 60, Iss. 10 — Oct. 1, 1970
  • pp: 1315–1318

Infrared Spectral Studies of Peroxyacetyl Nitrate (PAN)

INGE FILD and D. J. LOVELL  »View Author Affiliations


JOSA, Vol. 60, Issue 10, pp. 1315-1318 (1970)
http://dx.doi.org/10.1364/JOSA.60.001315


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Abstract

Through a photochemical reaction of nitrogen dioxide and 2-trans-butene, peroxyacetyl nitrate (PAN) is formed, which plays an important role in polluted air. The decomposition of this has been studied under two conditions: continued irradiation and in the absence of further irradiation. It was found that the rate of decomposition differed markedly in these two conditions. Different reaction mechanisms are postulated to account for this difference.

Citation
INGE FILD and D. J. LOVELL, "Infrared Spectral Studies of Peroxyacetyl Nitrate (PAN)," J. Opt. Soc. Am. 60, 1315-1318 (1970)
http://www.opticsinfobase.org/josa/abstract.cfm?URI=josa-60-10-1315


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References

  1. E. R. Stephens, P. L. Hanst, R. C. Doerr, and W. E. Scott, Ind. Eng. Chem. 48, 1498 (1956).
  2. E. R. Stephens, E. F. Darley, O. C. Taylor, and W. E. Scott, Proc. Am. Petrol. Inst., Div. Refining 40, III (1960).
  3. N. A. Renzetti and R. J. Bryan, J. Air Pollution Control Assoc. 11, 421 (1961).
  4. D. J. Lovell and J. Strong, Appl. Opt. 8, 1673 (1969).
  5. C. S. Tuesday, in Proc. Intern. Symp. Chem. Reac. Lower Upper Atmosph., San Francisco, CA, 1961, pp. 15–49.

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