TABLE I
(a). Operational data for the sliding spark source exposures on the 10. 7 m normal incidence spectrograph at N. B. S. in Washington, D. C.
λ range Discharge current (A) (Peak value) Spectrum Exposure time (min) Repetition rate 40 ms 300 In 10 1530–850 Å 700 In 5 1500 In 3 Cu-hollow cathode (100 mA) 10 Cu-hollow cathode (100 mA) 30 1500 In 10 950–270 Å 700 In 10 300 In 15
(b). Operational data for triggered spark source exposures on the 3 m normal incidence spectrograph.
Exposure Charging potential (kV) No. of turns of inductance coil No. of flashes 1 10 0 10 2 5 3 15 3 5 9 20 4 5 14 25
TABLE II
(a) Energy levels of the 4d 8 5s configuration in In v . (b) New energy levels of the 4d 8 5p configuration in In v .a
Energy level (cm-1 ) Configuration Designation J Experimental Calculated Exp.-Cal. Mixing percentage (a) 4d 8 (3 F )5s (3 F )4 F
9
2 160 427. 8 160 417. 3 +10. 5 99% (3 F )4 F + 1%(1 G )2 G (3 F )4 F
7
2 163 979. 3 163 901. 3 +78. 0 83% (3 F )4 F + 16% (3 F )2 F + 1% (1 G )2G (3 F )4 F
5
2 167 760. 4 167 633. 8 +126. 6 93% (3 F )4 F + 4% (1 D )2 D + 2% (3 F )2 F (3 F )4 F
3
2 169 229. 9 169 156. 6 +73. 3 84% (3 F )4 F + 15% (1 D )2 D + 1% (3 P )2 P 4d 8 (3 F )5s (3 F )2 F
7
2 171 289. 4 171 288. 0 +1. 4 82% (3 F )2 F + 16% (3 F )4 F + 1% (1 G )2 G (3 F )2 F
5
2 177 669. 3 177 658. 8 +10. 5 53% (3 F )2 F + 44% (3 P )4 P + 3% (3 F )4 F 4d 8 (3 P )5s (3 P )4 P
5
2 173 370. 3 173 574. 0 −203. 7 38% (3 P )4 P + 31% (1 D )2 D + 30% (3 F )2 F (3 P )4 P
3
2 178 288. 3 178 347. 6 −59. 3 59% (3 P )4 P + 21% (1 D )2 D + 12% (3 P )2 P (3 P )4 P
1
2 180 492. 2 180 451. 7 +40. 5 98%(3 P )4 P + 2%(1 S )2 S 4d 8 (1 D )5s (1 D )2 D
5
2 185 621. 7 185 805. 2 −183. 5 65% (1 D )2 D + 17% (3 P )4 P + 14% (3 F )2 F (1 D )2 D
3
2 182 193. 6 182 260. 4 −66. 8 40% (1 D )2 D + 36% (3 P )4 P + 18% (3 P )2 P 4d 8 (1 G )5s (1 G )2 G
9
2 188 395. 8 188 457. 3 −61. 5 99% (1 G )2 G + 1% (3 F )4 F (1 G )2 G
7
2 188 574. 5 188 558. 0 +16. 5 98% (1 G )2 G + 2% (3 F )2 F 4d 8 (3 P )5s (3 P )2 P
1
2 188 639. 1 188 513. 1 +126. 0 98% (1 G )2 G + 2% (3 F )2 F (3 P )2 P
3
2 188 648. 5 188 624. 7 +23. 8 70% (3 P )2 P + 28% (1 D )2 + 2% (3 F )4 F 4d 8 (1 S )5s (1 S )2 S
1
2 220 692. 6 220 624. 9 +67. 7 96% (1 S )2 S + 2% (3 P )4 + 2% (3 P )2 P
(b) 4d 8 (3 F )5p (3 F )4 D 0
7
2 235 382. 7 235 495. 3 −112. 6 77% (3 F )4 D + 11% (3 F )4 F + 5% (3 P )4 D (3 F )4 D 0
1
2 248 164. 2 248 135. 3 +28. 9 64% (3 F )4 D + 25% (3 P )4 D + 7% (1 D )4 P 4d 8 (3 F )5p (3 F )4 G 0
11
2 244 282. 2 244 054. 9 +227. 3 99% (3 F )4 G + 1% (1 G )2 H (3 F )4 G 0
9
2 238 628. 6 238 598. 6 +30. 0 42% (3 F )4 G + 35% (3 F )2 G + 22% (3 F )4 F (3 F )4 G 0
7
2 243 798. 1 243 649. 9 +148. 2 67% (3 F )4 G + 15% (3 F )4 F + 13% (3 F )2 G 4d 8 (3 F )5p (3 F )4 F 0
9
2 247 254. 1 247 161. 5 +92. 6 72% (3 F )4 F + 25% (3 F )2 G + 2% (3 F )4 G 4d 8 (3 F )5p (3 F )2 G 0
9
2 251 868. 3 251 716. 4 +151. 9 56% (3 F )4 G + 38% (3 F )2 G + 6% (3 F )4 F 4d 8 (3 P )5p b (3 P )2 P 0
1
2 261 207. 7 261 413. 7 −206. 0 39% (3 P )2 P + 36% (1 D )2 P + 8% (3 P )4 P 4d 8 (1 G )5p (1 G )2 H 0
9
2 262 350. 4 262 370. 4 −20. 0 93% (1 G )2 H + 6% (1 G )2 G + 1% (3 F )4 G (1 G )2 H 0
11
2 268 956. 7 268 837. 6 +119. 1 99% (1 G )2 H + 1% (3 F )4 G 4d 8 (3 P )5p (3 P )4 S 0
3
2 272 845. 8 272 722. 5 +123. 3 86% (3 P )4 S + 5% (1 D )2 P + 2% (3 P )4 P 4d 8 (1 D )5p b (1 D )2 P 0
1
2 275 317. 8 275 285. 6 +32. 2 41% (1 D )2 P + 32% (3 P )2 P + 20% (3 P )2 S 4d 8 (1 G )5p (1 G )2 G 0
9
2 277 481. 3 277 563. 4 −82. 1 93% (1 G )2 G + 5% (1 G )2 H + 1% (3 F )4 F
a The other levels were reported by Joshi
et al. 1 The improved values of these levels are given in
Table III .
b Only the designation changed.
TABLE III
Parameters used for the 4d 8 5s and 4d 8 5p configurations in In v .
Fitted parameter value (cm-1 ) Parameter 4d 8 5s 4d 8 5p E av 177 073. 0 ± 63. 5 258 118. 5 ± 47. 3 F 2 (dd )76 642. 1 ± 273. 2 77 018. 3 ± 213. 3 F 2 (dd )55 894. 0 ± 316. 9 56 043. 7 ± 238. 3 ζd 2960. 0 ± 34. 4 2979. 5 ± 27. 7 ζp ⋯ 5135. 4 ± 42. 3 F 2 (dp )⋯ 26 106. 0 ±163. 6 G 1 (dp )⋯ 8753. 1 ± 99. 2 G 2 (ds )13 698. 0 ± 181. 6 ⋯ G 3 (dp )⋯ 8108. 2 ± 344. 5 β 0. 0 (fixed) 0. 0 (fixed) T 0. 0 (fixed) 0. 0 (fixed) α 1 23. 87 ± 5. 95 25. 28 ± 4. 46 α 2 ⋯ 0. 0 (fixed) Mean error σ a 117 125
a σ =[(Σ(Exp. Val. − Cal. Val.)
2 /(
m −
n ))]
1/2 , where
m is the number of known levels,
n is the number of free parameters.
TABLE IV
Composition of the largest percentage component of the levels in LS - and Jj -coupling parametric calculations for the 4d 8 5p configuration.
Levela (cm-1 ) Largest percentage component J LS Jj 298 293. 5
1
2 92% (1 S )2 P 92% (1 S 0 , 2 P 1/2 ) 275 317. 8
1
2 41% (1 D )2 P 46% (3 P 2 , 2 P 3/2 ) 270 844. 8
1
2 70% (3 P )2 S 55% (3 P 1 , 2 P 3/2 ) 263 009. 0
1
2 64% (3 P )4 D 58% (3 P 0 , 2 P 1/2 ) 261 207. 7
1
2 39% (3 P )2 P 36% (1 D 2 , 2 P 3/2 ) 253 297. 9
1
2 88% (3 P )4 P 62% (3 P 1 , 2 P 1/2 ) 248 164. 2
1
2 64% (3 F )4 D 64% (3 P 2 , 2 P 3/2 ) 305 343. 5
3
2 94% (1 S )2 P 94% (1 S 0 , 2 P 3/2 ) 272 845. 8
3
2 86% (3 P )2 S 40% (3 P 1 , 2 P 3/2 ) 270 200. 6
3
2 69% (3 P )2 D 42% (3 P 0 , 2 P 3/2 ) 268 230. 3
3
2 52% (3 P )2 P 39% (3 P 2 , 2 P 3/2 ) 265 904. 9
3
2 57% (1 D )2 P 64% (1 D 2 , 2 P 3/2 ) 263 558. 2
3
2 29% (3 P )4 D 24% (3 F 3 , 2 P 3/2 ) 262 088. 8
3
2 33% (3 P )2 P 60% (3 P 1 , 2 P 1/2 ) 257 290. 2
3
2 43% (3 F )4 F 38% (3 F 2 , 2 P 3/2 ) 252 621. 2
3
2 49% (3 P )4 P 41% (3 P 2 , 2 P 1/2 ) 246 721. 2
3
2 30% (3 P )4 D 27% (3 F 3 , 2 P 3/2 ) 245 553. 3
3
2 41% (3 D )4 D 51% (3 F 2 , 2 P 1/2 ) 272 573. 3
5
2 55% (1 G )4 F 55% (1 G 4 , 2 P 3/2 ) 268 860. 6
5
2 43% (3 P )2 D 53% (3 P 1 , 2 P 3/2 ) 266 067. 0
5
2 32% (1 D )2 D 38% (3 D 2 , 2 P 3/2 ) 262 965. 0
5
2 26% (3 P )2 D 35% (3 P 2 , 2 P 1/2 ) 258 597. 6
5
2 24% (3 P )2 P 34% (3 F 2 , 2 P 3/2 ) 257 128. 1
5
2 39% (3 F )2 F 26% (3 F 2 ,2 P 3/2 ) 253 870. 7
5
2 48% (3 P )4 P 31% (3 F 4 , 2 P 3/2 ) 252 690. 3
5
2 35% (3 F )4 F 67% (3 F 3 , 2 P 3/2 ) 249 639. 3
5
2 35% (3 F )2 D 23% (3 F 2 , 2 P 1/2 ) 245 121. 4
5
2 58% (3 F )4 G 53% (3 F 2 , 2 P 1/2 ) 241 510. 4
5
2 70% (3 F )4 D 44% (3 F 3 ,2 P 1/2 ) 276 575. 3
7
2 88% (1 G )2 G 84% (1 G 4 ,2 P 3/2 ) 271 234. 0
7
2 51% (1 D )2 F 51% (1 D 2 , 2 P 3/2 ) 264 126. 2
7
2 46% (1 G )2 F 44% (3 P 2 , 2 P 3/2 ) 261 262. 1
7
2 26% (1 G )2 F 23% (1 D 2 , 2 P 3/2 ) 254 804. 1
7
2 47% (3 F )2 G 69% (3 F 2 , 2 P 3/2 ) 253 925. 7
7
2 45% (3 F )4 F 85% (3 F 3 , 2 P 3/2 ) 248 506. 7
7
2 54% (3 F )2 F 62% (3 F 4 , 2 P 3/2 ) 243 798. 1
7
2 67% (3 F )4 G 82% (3 F 3 ,2 P 1/2 ) 235 382. 7
7
2 77% (3 F )4 D 83% (3 F 4 , 2 P 1/2 ) 277 481. 3
9
2 93% (1 G )2 G 90% (1 G 4 , 2 P 3/2 ) 262 350. 4
9
2 93% (1 G )2 H 90% (1 G 4 , 2 P 1/2 ) 251 868. 3
9
2 56% (3 F )4 G 98% (3 F 3 , 2 P 3/2 ) 247 254. 1
9
2 72% (3 F )4 F 98% (3 F 4 , 2 P 3/2 ) 238 628. 6
9
2 42% (3 F )4 G 97% (3 F 4 , 2 P 1/2 ) 268 956. 7
11
2 99% (1 G )2 H 99% (1 G 4 , 2 P 3/2 ) 244 282. 2
11
2 99% (3 F )4 G 99% (3 F 4 , 2 P 3/2 )
a Revised odd level value.
TABLE V
Newly classified lines in In v .
Lambda Sigma Int Char Even level Odd level Diff. 757. 723 131 974. 3 22 1 (3P )4P 5/2 (1S )2P 3/2 1. 1 B 835. 275 119 721. 0 84 4 (1D )2D 5/2 (1S )2P 3/2 −0. 8 B 856. 924 116 696. 4 29 1 (3P )2P 3/2 (1S )2P 3/2 1. 4 B 861. 329 116 099. 6 7 1 (1D )2D 3/2 (1S )2P 1/2 −0. 3 902. 474 110 806. 5 46 1 (3F )4F 9/2 (1D )2F 7/2 0. 3 921. 412 108 529. 1 9 1 (3F )4F 9/2 (1G )2H 11/2 0. 2 932. 355 107 255. 3 61 1 (3F )4F 7/2 (1D )2F 7/2 0. 6 S 949. 776 105 288. 0 77 7 (3F )2F 7/2 (1G )2G 7/2 2. 1 953. 460 104 881. 2 32 1 (3F )4F 7/2 (3P )2D 5/2 −0. 1 964. 341 103 697. 8 81 1 (3F )4F 9/2 (1G )2F 7/2 −0. 6 966. 434 103 473. 2 6 1 (3F )4F 5/2 (1D )2F 7/2 −0. 4 968. 952 103 204. 3 6 1 (3P )4P 5/2 (1G )2G 7/2 −0. 7 976. 183 102 439. 8 12 1 (3F )4F 5/2 (3P )2D 3/2 −0. 4 979. 556 102 087. 1 63 1 (3F )4F 7/2 (1D )2D 5/2 −0. 6 987. 326 101 283. 7 44 1 (3F )2F 7/2 (1G )2F 5/2 −0. 2 989. 120 101 100. 0 33 1 (3F )4F 5/2 (3P )2D 5/2 −0. 2 990. 388 100 970. 5 15 1 (3F )4F 3/2 (3P )2D 3/2 −0. 2 991. 727 100 834. 2 72 4 (3F )4F 9/2 (3P )4D 7/2 −0. 1 998. 537 100 146. 5 64 1 (3F )4F 7/2 (1G )2F 7/2 −0. 4 1000. 554 99 944. 6 47 1 (3F )2F 7/2 (1D )2F 7/2 0. 0 1003. 711 99 630. 3 7 1 (3F )4F 3/2 (3P )2D 5/2 −0. 4 B 1005. 278 99 475. 0 77 4 (3P )4P 5/2 (3P )4S 3/2 −0. 5 1008. 034 99 203. 0 22 1 (3P )4P 5/2 (1G )2F 5/2 0. 0 1010. 092 99 000. 9 61 1 (3F )4F 3/2 (3P )2P 3/2 0. 5 B 1010. 251 98 985. 3 45 1 (3F )4F 7/2 (3P )4D 5/2 −0. 4 1011. 058 98 906. 3 10 1 (3F )2F 5/2 (1G )2G 7/2 0. 3 1017. 226 98 306. 6 50 4 (3F )4F 5/2 (1D )2D 5/2 0. 0 1018. 906 98 144. 5 21 1 (3F )4F 5/2 (1D )2P 3/2 0. 0 1024. 895 97 571. 0 69 4 (3F )2F 7/2 (3P )2D 5/2 −0. 2 1027. 930 97 282. 9 17 1 (3F )4F 7/2 (3P )4D 7/2 0. 1 1032. 658 96 837. 5 27 1 (3F )4F 3/2 (1D )2D 5/2 0. 4 1037. 706 96 366. 4 21 1 (3F )4F 5/2 (1G )2F 7/2 0. 6 1043. 858 95 798. 5 73 4 (3F )4F 5/2 (3F )2D 3/2 0. 7 1047. 219 95 491. 0 19 1 (3P )4P 5/2 (3P )2D 5/2 0. 7 1050. 366 95 204. 9 22 1 (3F )4F 5/2 (3P )4D 5/2 0. 3 1050. 666 95 177. 7 85 4 (3F )2F 5/2 (3P )4S 3/2 1. 2 1053. 704 94 903. 3 58 4 (3F )2F 5/2 (1G )2F 5/2 −0. 7 1054. 572 94 825. 2 12 7 (3P )4P 1/2 (3P )2P 1/2 −0. 4 1056. 880 94 618. 1 67 4 (3F )4F 7/2 (1D )2F 5/2 −0. 2 1057. 550 94 558. 2 76 4 (3P )4P 3/2 (3P )4S 3/2 0. 7 1060. 128 94 328. 2 51 1 (3F )4F 5/2 (3P )4D 3/2 −0. 2 (3F )4F 3/2 (3F )2D 3/2 −0. 1 M 1060. 611 93 285. 3 44 1 (3P )4P 3/2 (1G )2F 5/2 0. 3 1066. 331 93 779. 5 84 4 (3F )4F 3/2 (3P )4D 1/2 0. 4 1068. 773 93 565. 2 76 4 (3F )2F 5/2 (1D )2F 7/2 0. 5 1069. 536 93 498. 5 80 4 (3F )4F 9/2 (3F )4F 7/2 0. 6 1073. 835 93 124. 2 40 1 (1D )2D 3/2 (3P )2P 1/2 0. 0 1076. 907 92 858. 5 82 4 (3F )4F 3/2 (3P )4D 3/2 −0. 4 1077. 157 92 837. 0 71 4 (3F )2F 7/2 (1G )2F 7/2 0. 2 1078. 779 92 697. 4 75 4 (3P )4P 5/2 (1D )2D 5/2 0. 7 1080. 422 92 556. 4 58 4 (3P )4P 3/2 (3P )2S 1/2 −0. 1 1080. 678 92 534. 5 80 4 (3P )4P 5/2 (1D )2P 3/2 −0. 1 (3F )2F 5/2 (3P )2D 3/2 3. 2 M 1082. 802 92 353. 0 71 7 (3P )4P 1/2 (3P )4S 3/2 −0. 6 1087. 992 91912. 4 66 1 (3P )4P 3/2 (3P )2D 3/2 0. 1 1090. 805 91 675. 4 67 4 (3F )2F 7/2 (3P )4D 5/2 −0. 2 1093. 613 91 440. 0 17 1 (3F )4F 9/2 (3F )2G 9/2 −0. 5 1096. 591 91 191. 7 82 4 (3F )2F 5/2 (3P )2D 5/2 0. 4 1098. 166 91 060. 9 5 1 (3F )2F 7/2 (1G )2H 9/2 −0. 1 1099. 464 90 953. 4 65 4 (1D )2D 5/2 (1G )2G 7/2 −0. 2 1100. 873 90 837. 0 60 1 (3F )4F 5/2 (1D )2F 5/2 −0. 2 1101. 016 90 825. 2 58 1 (3F )4F 7/2 (3F )2G 7/2 0. 4 1101. 859 90 755. 7 85 4 (3P )4P 5/2 (1G )2F 7/2 −0. 2 1103. 116 90 652. 3 83 1 (1D )2D 3/2 (3P )4S 3/2 0. 1 1104. 088 90 572. 5 72 4 (3P )4P 3/2 (3P )2D 5/2 0. 8 1104. 232 90 560. 7 52 2 (3F )2F 5/2 (3P )2P 3/2 −0. 3 1106. 436 90 380. 3 61 1 (1D )2D 3/2 (1G )2F 5/2 0. 6 1106. 779 90 352. 3 66 4 (3P )4P 1/2 (3P )2S 1/2 −0. 3 1108. 794 90 188. 1 77 1 (3P )4P 5/2 (3F )2D 3/2 0. 2 1111. 445 89 973. 0 74 4 (3F )2F 7/2 (3P )4D 7/2 0. 3 1111. 777 89 946. 1 83 4 (3F )4F 7/2 (3F )4F 7/2 −0. 3 1111. 818 89 942. 8 68 7 (3P )4P 3/2 (3P )2P 3/2 0. 8 1112. 450 89 891. 7 83 1 (3F )4F 7/2 (3P )4P 5/2 0. 3 1114. 717 89 708. 9 73 1 (3P )4P 1/2 (3P )2D 3/2 0. 5 1116. 942 89 530. 2 77 1 (3F )4F 5/2 (3F )4F 3/2 0. 4 1118. 974 89 367. 6 81 4 (3F )4F 5/2 (3F )2F 5/2 −0. 1 D (3F )4F 3/2 (1D )2F 5/2 −0. 1 D 1122. 516 89 085. 6 89 4 (1G )2G 9/2 (1G )2G 9/2 0. 1 1124. 776 88 906. 6 87 4 (1G )2G 7/2 (1G )2G 9/2 −0. 2 1127. 183 88 716. 7 70 7 (3P )4P 5/2 (3P )4D 3/2 −1. 8 1127. 255 88 711. 1 71 1 (3F )4F 7/2 (3F )4F 5/2 0. 1 1128. 019 88 651. 0 57 4 (1D )2D 3/2 (3P )2S 1/2 −0. 2 1134. 048 88179. 7 76 4 (1G )2G 9/2 (1G )2G 7/2 0. 2 1135. 347 88 078. 8 79 4 (3F )4F 9/2 (3F )2F 7/2 −0. 1 1135. 587 88 060. 2 86 4 (3F )4F 3/2 (3F )4F 3/2 −0. 1 1136. 346 88 001. 4 90 4 (1G )2G 7/2 (1G )2G 7/2 0. 6 1137. 685 87 897. 8 85 7 (3F )4F 3/2 (3F )2F 5/2 −0. 4 1137. 787 87 889. 9 89 4 (3F )4F 7/2 (3F )2G 9/2 0. 9 (3P )4P 5/2 (3P )4D 7/2 −1. 9 M 1139. 242 87 777. 7 78 4 (3P )4P 3/2 (1D )2D 5/2 −1. 0 1139. 736 87 739. 6 72 4 (3P )4P 1/2 (3P )2P 3/2 1. 5 1141. 335 87 616. 7 81 4 (3P )4P 3/2 (1D )2P 3/2 0. 1 1145. 387 87 306. 7 78 7 (3F )2F 7/2 (1D )2F 5/2 −1. 5 1146. 476 87 223. 8 79 4 (1D )2D 5/2 (3P )4S 3/2 −0. 3 1148. 851 87 043. 5 87 4 (3F )4F 5/2 (3F )2G 7/2 −0. 2 1150. 062 86 951. 8 77 4 (1D )2D 5/2 (1G )2F 5/2 0. 2 1151. 722 86 826. 5 88 1 (3F )4F 9/2 (3F )4F 9/2 0. 2 1153. 694 86 678. 1 61 7 (3P )2P 1/2 (3P )2P 1/2 −0. 6 1153. 836 86 667. 4 86 4 (1D )2D 3/2 (3P )2D 5/2 0. 4 D (3P )2P 3/2 (3P )2P 1/2 −1. 9 D 1156. 651 86 456. 5 86 4 (3F )2F 5/2 (1G )2F 7/2 −0. 4 1160. 560 86 165. 3 84 4 (3F )4F 5/2 (3F )4F 7/2 0. 0 1161. 303 86 110. 2 67 1 (3F )4F 5/2 (3P )4P 5/2 −0. 1 1164. 299 85 888. 6 68 4 (3F )2F 5/2 (3F )2D 3/2 −0. 3 1164. 972 85 839. 0 32 1 (3F )2F 7/2 (3F )2F 5/2 0. 3 1167. 409 85 659. 8 68 1 (3F )4F 7/2 (3F )2D 5/2 −0. 2 1168. 056 85 612. 3 88 4 (1D )2D 5/2 (1D )2F 7/2 0. 0 1170. 785 85 412. 8 75 4 (3P )4P 1/2 (1D )2P 3/2 0. 1 1172. 393 85 295. 6 68 4 (3F )2F 5/2 (3F )4D 5/2 −0. 1 1172. 758 85 269. 1 80 4 (3P )4P 3/2 (3F )2D 3/2 −0. 8 1173. 340 85 226. 8 54 1 (3P )4P 5/2 (1D )2F 5/2 −0. 5 1177. 446 84 929. 6 85 4 (3F )4F 5/2 (3F )4F 5/2 −0. 3 1178. 400 84 860. 8 55 1 (3F )4F 5/2 (3P )4P 3/2 0. 0 1180. 352 84 720. 5 46 1 (3P )4P 3/2 (3P )4D 1/2 −0. 2 1180. 969 84 676. 2 77 4 (3P )4P 3/2 (3P )4D 5/2 −0. 5 1181. 328 84 650. 5 78 1 (1S )2S 1/2 (1S )2P 3/2 −0. 4 1182. 335 84 578. 4 72 4 (1D )2D 5/2 (3F )2D 3/2 −0. 5 1183. 048 84 527. 4 85 4 (3F )4F 7/2 (3F )2F 7/2 0. 0 1184. 565 84 419. 2 69 4 (3F )2F 5/2 (3P )4D 3/2 −0. 3 1187. 562 84206. 1 51 1 (3P )2P 1/2 (3P )4S 3/2 −0. 6 1187. 692 84 196. 9 59 1 (3P )2P 3/2 (3P )4S 3/2 −0. 4 1189. 520 84 067. 5 50 1 (3F )4F 3/2 (3P )4P 1/2 −0. 5 1190. 489 83 999. 1 84 4 (1G )2G 7/2 (1G )2F 5/2 0. 3 B 1191. 583 83 922. 0 80 4 (3P )4P 5/2 (3F )4F 3/2 2. 1 D (3P )2P 3/2 (1G )2F 5/2 −2. 8 D 1192. 277 83 873. 1 83 1 (1D )2D 3/2 (1D )2D 5/2 −0. 3 1192. 540 83 854. 6 82 4 (3F )4F 9/2 (3F )4G 11/2 0. 2 1193. 292 83 801. 8 63 1 (3P )4P 3/2 (3P )4D 3/2 1. 3 B 1193. 936 83 756. 6 79 4 (3P )4P 5/2 (3F )2F 5/2 −1. 2 1194. 573 83 711. 9 76 4 (1D )2D 3/2 (1D )2P 3/2 0. 6 1196. 280 83 592. 5 82 4 (3F )2F 5/2 (3P )4D 7/2 −0. 3 1197. 395 83514. 6 75 1 (3F )2F 7/2 (3F )2G 7/2 −0. 1 1198. 170 83460. 6 73 1 (3F )4F 3/2 (3F )4F 5/2 0. 2 1199. 169 83391. 1 80 4 (3F )4F 3/2 (3P )4P 3/2 −0. 2 1199. 478 83 369. 6 50 7 (3F )4F 9/2 (3F )4G 7/2 −0. 7 1200. 842 83 274. 9 81 4 (3F )4F 7/2 (3F )4F 9/2 0. 1 1201. 366 83 238. 6 67 4 (1D )2D 5/2 (3P )2D 5/2 −0. 3 1203. 871 83 065. 4 74 4 (3P )4P 1/2 (3F )2D 3/2 −0. 6 1206. 002 82 918. 6 70 1 (3P )4P 3/2 (1D )2P 1/2 −0. 8 1207. 178 82 837. 8 75 4 (1G )2G 9/2 (1D )2F 7/2 −0. 4 1209. 785 82 659. 3 65 4 (1G )2G 7/2 (1D )2F 7/2 −0. 2 1210. 125 82 636. 1 82 4 (3F )2F 7/2 (3F )4F 7/2 −0. 2 1210. 537 82 608. 0 68 4 (1D )2D 5/2 (3P )2P 3/2 −0. 6 1210. 937 82 580. 7 77 4 (3F )2F 7/2 (3P )4P 5/2 −0. 6 1211. 880 82 516. 4 78 4 (3P )4P 1/2 (3P )4D 1/2 −0. 4 1216. 453 82 206. 2 84 1 (3P )2P 1/2 (3P )2S 1/2 0. 5 1216. 595 82 196. 6 74 1 (3P )2P 3/2 (3P )2S 1/2 0. 3 1221. 311 81 879. 2 51 1 (3F )4F 5/2 (3F )2D 5/2 0. 3 1225. 534 81 597. 1 61 1 (3P )4P 1/2 (3P )4D 3/2 0. 5 1226. 063 81561. 9 85 4 (3P )2P 1/2 (3P )2D 3/2 0. 4 1226. 207 81 552. 3 75 1 (3P )2P 3/2 (3P )2D 3/2 0. 2 1227. 999 81 433. 3 87 4 (3P )4P 5/2 (3F )2G 7/2 −0. 5 1228. 482 81 401. 3 88 1 (3F )2F 7/2 (3F )4F 5/2 0. 4 1229. 028 81 365. 1 41 1 (1D )2D 3/2 (3F )2D 3/2 0. 5 1232. 401 81 142. 4 75 1 (3F )4F 7/2 (3F )4G 5/2 0. 3 1235. 659 80 928. 5 87 4 (3F )2F 5/2 (1D )2F 5/2 0. 2 1237. 383 80 815. 7 60 1 (1D )2D 3/2 (3P )4D 1/2 0. 3 1238. 056 80 771. 8 66 4 (1D )2D 3/2 (3P )4D 5/2 0. 4 1238. 447 80 746. 3 87 4 (3F )4F 5/2 (3F )2F 7/2 0. 0 1238. 926 80 715. 1 76 1 (3P )4P 1/2 (1D )2P 1/2 −0. 4 1241. 024 80 578. 6 84 4 (3F )2F 7/2 (3F )2G 9/2 −0. 3 1241. 298 80 560. 8 84 4 (1G )2G 9/2 (1G )2H 11/2 −0. 1 1241. 362 80 556. 7 68 7 (3P )4P 5/2 (3F )4F 7/2 1. 3 1242. 210 80 501. 7 88 4 (3P )4P 5/2 (3P )4P 5/2 1. 3 B 1243. 070 80 446. 0 86 4 (1D )2D 5/2 (1D )2D 5/2 0. 7 1243. 631 80 409. 7 86 4 (3F )4F 3/2 (3F )2D 5/2 0. 3 1245. 181 80 309. 6 86 4 (3P )4P 3/2 (1D )2F 5/2 0. 3 1245. 574 80 284. 3 85 4 (1D )2D 5/2 (1D )2P 3/2 1. 10 D (1G )2G 7/2 (3P )2D 5/2 −1. 8 D 1246. 693 80 212. 2 85 1 (3P )2P 3/2 (3P )2D 5/2 0. 1 1251. 635 79 895. 5 81 4 (1D )2D 3/2 (3P )4D 3/2 0. 3 1252. 835 79 819. 0 83 4 (3F )4F 7/2 (3F )4G 7/2 0. 2 1255. 947 79 621. 2 84 4 (3F )2F 5/2 (3F )4F 3/2 0. 3 1256. 428 79 590. 7 38 1 (3P )2P 1/2 (3P )2P 3/2 −0. 5 1256. 569 79 581. 8 83 4 (3P )2P 3/2 (3P )2P 3/2 0. 0 1258. 503 79 459. 5 83 4 (3F )2F 5/2 (3F )2F 5/2 0. 7 1260. 714 79 320. 1 82 1 (3P )4P 5/2 (3F )4F 5/2 0. 1 1261. 817 79 250. 8 83 4 (3P )4P 5/2 (3P )4P 3/2 −0. 1 1265. 589 79 014. 6 86 4 (1D )2D 3/2 (1D )2P 1/2 0. 5 1265. 796 79 001. 7 78 1 (3P )4P 3/2 (3F )4F 3/2 −0. 2 S 1266. 446 78 961. 1 86 1 (3F )4F 5/2 (3F )4D 3/2 0. 3 1266. 862 78 935. 2 87 4 (3F )4F 3/2 (3F )4D 1/2 0. 9 1268. 384 78840. 5 85 4 (3P )4P 3/2 (3F )2F 5/2 0. 7 1273. 811 78 504. 6 79 1 (1D )2D 5/2 (1G )2F 7/2 0. 1 1276. 318 78 350. 4 85 4 (3F )2F 7/2 (3F )2D 5/2 0. 5 1278. 758 78 200. 9 84 4 (3F )4F 9/2 (3F )4G 9/2 0. 1 1283. 094 77 936. 6 81 4 (1D )2D 5/2 (3F )2D 3/2 0. 1 1285. 468 77 792. 7 84 4 (3F )4F 5/2 (1D )2D 3/2 −0. 2 1288. 640 77 601. 2 73 1 (1S )2S 1/2 (1S )2P 1/2 0. 3 1289. 800 77 531. 4 83 4 (3F )4F 7/2 (3F )4D 5/2 0. 3 1290. 449 77 492. 4 87 4 (3F )4F 3/2 (3F )4D 3/2 1. 1 D (1G )2G 7/2 (1D )2D 5/2 −0. 1 D 1291. 674 77 418. 9 78 4 (3P )2P 3/2 (1D )2D 5/2 0. 4 1292. 639 77 361. 1 86 4 (3F )4F 5/2 (3F )4G 5/2 0. 1 1292. 930 77 343. 7 87 4 (1D )2D 5/2 (3P )4D 5/2 0. 4 1294. 242 77 265. 3 72 1 (3P )2P 1/2 (1D )2P 3/2 −0. 5 1294. 393 77 256. 3 71 1 (3P )2P 3/2 (1D )2P 3/2 −0. 1 1295. 035 77 218. 0 89 4 (3F )2F 7/2 (3F )2F 7/2 0. 7 1296. 427 77135. 1 88 4 (3F )2F 5/2 (3F )2G 7/2 0. 3 1302. 114 76 798. 2 58 7 (3P )4P 1/2 (3F )4F 3/2 0. 2 1307. 745 76 467. 5 80 4 (1D )2D 5/2 (3P )4D 3/2 0. 4 1308. 835 76 403. 8 63 1 (1D )2D 3/2 (1D )2F 5/2 −0. 2 1310. 207 76 323. 8 81 4 (3F )4F 3/2 (1D )2D 3/2 0. 4 1311. 147 76 269. 1 79 1 (3P )4P 5/2 (3F )2D 5/2 0. 1 1311. 360 76 256. 7 80 1 (3F )2F 5/2 (3F )4F 7/2 0. 3 1312. 308 76201. 6 84 1 (3F )2F 5/2 (3P )4P 5/2 0. 2 1315. 139 76 037. 6 85 4 (3F )4F 5/2 (3F )4G 7/2 −0. 1 1316. 406 75 964. 4 87 4 (3F )2F 7/2 (3F )4F 9/2 −0. 3 1317. 671 75 891. 5 87 4 (3F )4F 3/2 (3F )4G 5/2 0. 0 1320. 468 75 730. 7 87 4 (1G )2G 9/2 (1G )2F 7/2 0. 3 1322. 036 75 640. 9 85 4 (1D )2D 5/2 (3P )4D 7/2 0. 5 1323. 059 75 582. 4 12 1 (3P )4P 3/2 (3P )4P 5/2 0. 0 1323. 595 75 551. 8 56 1 (1G )2G 7/2 (1G )2F 7/2 0. 1 1330. 909 75 136. 6 84 4 (3P )4P 5/2 (3F )2F 7/2 0. 2 1331. 627 75 096. 1 82 4 (1D )2D 3/2 (3F )4F 3/2 −0. 5 1332. 958 75 021. 1 84 4 (3F )2F 5/2 (3F )4F 5/2 0. 1 1333. 154 75 010. 1 87 4 (3P )4P 3/2 (3P )4P 1/2 0. 5 1334. 123 74 955. 6 85 4 (3F )4F 9/2 (3F )4D 7/2 0. 7 1334. 214 74 950. 5 85 7 (3F )2F 5/2 (3P )4P 3/2 −1. 4 1334. 515 74 933. 6 89 4 (1D )2D 3/2 (3F )2F 5/2 −0. 95 1334. 771 74 919. 2 71 1 (3P )2P 1/2 (3F )2D 3/2 0. 1 1334. 969 74 908. 1 48 3 (3P )2P 3/2 (3F )2D 3/2 −1. 6 B 1339. 599 74 649. 2 82 4 (3F )4F 7/2 (3F )4G 9/2 −0. 1 1344. 265 74 390. 1 59 7 (1G )2G 7/2 (3P )4D 5/2 −0. 4 1344. 574 74 373. 0 78 4 (3P )2P 1/2 (3P )4D 1/2 3. 1 B 1344. 780 74 361. 6 63 7 (3P )2P 3/2 (3P )4D 1/2 1. 1 S 1345. 294 74 333. 2 70 1 (3P )4P 3/2 (3P )4P 3/2 0. 3 1345. 598 74 316. 4 85 4 (3P )2P 3/2 (3P )4D 5/2 −0. 1 1352. 175 73 954. 9 84 4 (1G )2G 9/2 (1G )2H 9/2 0. 3 1354. 423 73 832. 2 83 1 (3F )2F 7/2 (3F )4G 5/2 0. 2 1355. 458 73 775. 8 85 4 (1G )2G 7/2 (1G )2H 9/2 −0. 1 1355. 929 73 750. 2 70 1 (3F )4F 5/2 (3F )4D 5/2 0. 2 1361. 482 73449. 4 73 1 (3P )2P 1/2 (3P )4D 3/2 −0. 3 1361. 643 73 440. 7 73 1 (3P )2P 3/2 (3P )4D 3/2 0. 4 1363. 306 73351. 1 85 4 (3P )4P 5/2 (3F )4D 3/2 0. 2 1370. 310 72 976. 2 73 4 (1D )2D 5/2 (1D )2F 5/2 0. 3 1372. 382 72 866. 0 86 4 (1G )2G 9/2 (3P )4D 7/2 −0. 3 1373. 489 72 807. 3 86 4 (3P )4P 1/2 (3P )4P 1/2 1. 6 B 1375. 773 72 686. 4 43 1 (1G )2G 7/2 (3P )4D 7/2 −1. 2 S 1377. 995 72 569. 2 67 1 (3P )2P 1/2 (1D )2P 1/2 0. 6 1378. 185 72 559. 2 39 1 (3P )2P 3/2 (1D )2P 1/2 0. 0 1379. 139 72 509. 0 81 1 (3F )2F 7/2 (3F )4G 7/2 0. 3 1383. 512 72 279. 8 66 1 (3F )4F 3/2 (3F )4D 5/2 −0. 7 1385. 368 72 183. 0 88 4 (3P )4P 5/2 (1D )2D 3/2 0. 0 1386. 403 72 129. 1 88 4 (3P )4P 1/2 (3P )4P 3/2 0. 1 1389. 474 71 969. 7 87 4 (3F )2F 5/2 (3F )2D 5/2 −0. 3 1393. 750 71748. 9 88 4 (3P )4P 5/2 (3F )4G 5/2 −2. 2 S 1395. 146 71 677. 1 87 1 (1D )2D 3/2 (3F )4P 5/2 0. 0 1395. 311 71 668. 6 83 4 (1D )2D 5/2 (3F )4F 3/2 0. 1 1398. 468 71 506. 8 82 4 (1D )2D 5/2 (3F )2F 5/2 0. 4 1400. 480 71 404. 1 85 1 (3F )4F 7/2 (3F )4D 7/2 0. 7 1401. 526 71 350. 8 77 4 (3P )4P 3/2 (3F )2D 5/2 −0. 2 1406. 383 71 104. 4 90 4 (1D )2D 3/2 (3P )4P 1/2 0. 1 S 1418. 510 70 496. 5 78 4 (1D )2D 3/2 (3F )4F 5/2 −0. 2 1419. 892 70 427. 9 85 4 (3P )4P 5/2 (3F )4G 7/2 0. 1 1424. 073 70 221. 1 86 4 (3F )2F 7/2 (3F )4D 5/2 0. 1 1428. 096 70 023. 3 82 4 (1G )2G 7/2 (1D )2F 5/2 0. 2 1429. 623 69 948. 5 84 7 (3P )2P 3/2 (1D )2F 5/2 −0. 6 1431. 100 69 876. 3 80 1 (3P )4P 3/2 (3F )4D 1/2 0. 4 1448. 192 69 051. 6 73 4 (3F )2F 5/2 (3F )4D 3/2 −0. 3 1456. 849 68 641. 3 2 1 (3P )2P 3/2 (3F )4F 3/2 −0. 4 1458. 713 68 553. 6 46 4 (1G )2G 7/2 (3F )2F 5/2 0. 0 1460. 289 68 479. 6 57 1 (3P )2P 3/2 (3F )2F 5/2 0. 0 1461. 292 68 432. 6 85 4 (3P )4P 3/2 (3F )4D 3/2 −0. 3 1464. 043 68 304. 0 32 3 (1D )2D 5/2 (3F )4F 7/2 0. 0 1465. 225 68 248. 9 62 2 (1D )2D 5/2 (3P )4P 5/2 −0. 1 1467. 565 68 140. 1 87 4 (3P )4P 5/2 (3F )4D 5/2 0. 0 1473. 106 67 883. 8 86 4 (3F )2F 5/2 (1D )2D 3/2 −0. 2 1477. 736 67 671. 1 85 1 (3P )4P 1/2 (3F )4D 1/2 −0. 9 1478. 780 67 623. 3 16 1 (3F )4F 5/2 (3F )4D 7/2 1. 0 B 1482. 545 67 451. 6 65 1 (3F )2F 5/2 (3F )4G 5/2 −0. 5 1482. 679 67 445. 5 70 1 (1D )2D 3/2 (3F )2D 5/2 −0. 2 1485. 019 67 339. 2 88 4 (3F )2F 7/2 (3F )4G 9/2 0. 0 1491. 020 67 068. 2 73 4 (1D )2D 5/2 (3F )4F 5/2 −0. 4 1505. 838 66 408. 2 46 4 (1G )2G 9/2 (3F )2G 7/2 −0. 1 1512. 214 66 128. 2 87 4 (3F )2F 5/2 (3F )4G 7/2 −0. 6 1515. 831 65 970. 4 65 1 (1D )2D 3/2 (3F )4D 1/2 −0. 2 1526. 026 65 529. 7 89 4 (1G )2G 9/2 (3F )4F 7/2 −0. 2 1546. 825 64 648. 6 28 1 (3P )2P 3/2 (3P )4P 1/2 −0. 8 S 1559. 674 64 116. 0 55 7 (1G )2G 7/2 (3F )4P 5/2 0. 2 1560. 160 64 096. 0 28 1 (3F )2F 7/2 (3F )4D 7/2 2. 7 1578. 249 63 361. 4 39 1 (1D )2D 3/2 (1D )2D 3/2 1. 7
Int is the intensity (scale 0–100).
Char is the character of line: 1, normal line; 2, diffuse line; 3, very diffuse line; 4, broad line; 7, line on shoulder of stronger line.
Diff. is the difference
σ obs . −
σ calc ., where
σ calc . is the wave-number as calculated from the experimentally determined level values.
M means masked by In
v .
D means doubly classified.
B means masked by non-In
v .
S means the observed intensity of the line is stronger than expected.