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Journal of the Optical Society of America

Journal of the Optical Society of America

  • Vol. 68, Iss. 2 — Feb. 1, 1978
  • pp: 235–242

Infrared emission spectrum of neutral vanadium (V I)

D. S. Davis, K. L. Andrew, and J. Verges  »View Author Affiliations


JOSA, Vol. 68, Issue 2, pp. 235-242 (1978)
http://dx.doi.org/10.1364/JOSA.68.000235


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Abstract

The first spectrum of vanadium has been observed in the 1.0–5.6µm extraphotographic infrared region by means of Fourier spectroscopic techniques. These observations have produced measurements for about 450 infrared V I lines and preliminary analysis has led to a revision and extension of the spectroscopic terms arising from the 3d5 configuration. The 4F term at about 37 000 cm-1 formerly ascribed to 3d5 has been reassigned to 3d44s. The lowest term of the 3d5 configuration, 6S5/2 at 20 202.47 ± 0.05 cm-1 has been reaffirmed by means of high-precision infrared measurements. In addition, three probable new 3d5 terms, 4G at about 34 200 cm-1, 4P at about 33 000 cm-1 and 2F at about 35 700 cm-1 have been tentatively identified.

© 1978 Optical Society of America

Citation
D. S. Davis, K. L. Andrew, and J. Verges, "Infrared emission spectrum of neutral vanadium (V I)," J. Opt. Soc. Am. 68, 235-242 (1978)
http://www.opticsinfobase.org/josa/abstract.cfm?URI=josa-68-2-235

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