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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Editor: Henry van Driel
  • Vol. 29, Iss. 7 — Jul. 1, 2012
  • pp: 1661–1671

Universal properties of the optimized off-resonant intrinsic second hyperpolarizability

David S. Watkins and Mark G. Kuzyk  »View Author Affiliations


JOSA B, Vol. 29, Issue 7, pp. 1661-1671 (2012)
http://dx.doi.org/10.1364/JOSAB.29.001661


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Abstract

We seek to identify universal properties shared by all quantum systems with large intrinsic second hyperpolarizability ( γ int )—an invariant quantity that removes the effects of simple scaling. A large- γ int quantum system is generated by varying the shape of a trial potential until γ int is optimized. A variety of starting potentials yield a set of systems with distinctly shaped optimized potentials, but are found to share universal properties that separate into classes determined by the magnitude and sign of γ int . However, the fact that the best systems are 0.6 times the fundamental limit suggests that exotic Hamiltonians may be required to reach the upper bound. The observed regularity hints at a deeper relationship between optimized systems that may provide useful insights applicable to designing better materials. Being general, this approach applies to any quantum system, including molecules, nanoparticles, or quantum gases.

© 2012 Optical Society of America

OCIS Codes
(020.5580) Atomic and molecular physics : Quantum electrodynamics
(160.4330) Materials : Nonlinear optical materials
(190.0190) Nonlinear optics : Nonlinear optics
(230.5590) Optical devices : Quantum-well, -wire and -dot devices
(160.4236) Materials : Nanomaterials
(250.5590) Optoelectronics : Quantum-well, -wire and -dot devices

ToC Category:
Quantum Optics

History
Original Manuscript: January 24, 2012
Manuscript Accepted: March 19, 2012
Published: June 14, 2012

Citation
David S. Watkins and Mark G. Kuzyk, "Universal properties of the optimized off-resonant intrinsic second hyperpolarizability," J. Opt. Soc. Am. B 29, 1661-1671 (2012)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-29-7-1661


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