Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group

Calculation of the emission spectrum of Eu3+ in a tetragonal site in SrF2

Not Accessible

Your library or personal account may give you access

Abstract

A model is presented for predicting the emission spectra of trivalent lanthanide ions in sites of tetragonal symmetry in fluorite-structure crystal hosts. The utility of the model is examined by comparing the results of the calculations performed with the experimental data for the Eu3+:SrF2 system. The a priori calculated energy-level scheme is found to reproduce the 14 experimentally observed crystal-field levels of the 7FJ multiplets of Eu3+ with a rms deviation of 24.5 cm−1. Reasonably accurate model predictions of most emission-line intensities can also be obtained by including contributions from electrostatic shielding, wave-function expansion, and a modified energy separation between the 4f configuration and the g symmetry perturbing states.

© 1988 Optical Society of America

Full Article  |  PDF Article
More Like This
Doping concentration induced phase transition in Eu3+-doped β-PbF2 nano-particles

Hui Guo, Hua Yu, Xinxing Zhang, Lifen Chang, Zijian Lan, Yiming Li, and Lijuan Zhao
Opt. Express 21(21) 24742-24752 (2013)

Spectroscopy and gain measurements of Nd3+ in SrF2 and other fluorite-structure hosts

Stephen A. Payne, John A. Caird, L. L. Chase, L. K. Smith, N. D. Nielsen, and William F. Krupke
J. Opt. Soc. Am. B 8(4) 726-740 (1991)

Investigation of site-selective symmetries of Eu3+ ions in KPb2Cl5 by using optical spectroscopy

Concepción Cascales, Joaquín Fernández, and Rolindes Balda
Opt. Express 13(6) 2141-2152 (2005)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (3)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (2)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (6)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved