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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 12, Iss. 6 — Jun. 1, 1995
  • pp: 1021–1027

Measurement of nonresonant third-order susceptibilities of various gases by the nonlinear interferometric technique

Jae Won Hahn and Eun Seong Lee  »View Author Affiliations


JOSA B, Vol. 12, Issue 6, pp. 1021-1027 (1995)
http://dx.doi.org/10.1364/JOSAB.12.001021


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Abstract

We applied nonlinear interferometry of coherent anti-Stokes Raman spectroscopy (CARS) to measure the nonresonant third-order susceptibilities of various gases. Using argon as an internal calibration standard, we determined the effective nonresonant susceptibilities of acetylene, carbon dioxide, methane, nitrogen, oxygen, propane, carbon monoxide, Freon, and hydrogen from the amplitudes of the interference fringes of the CARS signals generated in the two gas cells. The electronic susceptibility was calculated by subtracting the off-resonant term of each molecule from the measured effective nonresonant susceptibility, and the results of this work are compared with the published data. The overall uncertainty is estimated to be less than 5%.

© 1995 Optical Society of America

Citation
Jae Won Hahn and Eun Seong Lee, "Measurement of nonresonant third-order susceptibilities of various gases by the nonlinear interferometric technique," J. Opt. Soc. Am. B 12, 1021-1027 (1995)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-12-6-1021


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References

  1. P. R. Regnier and J. P. E. Taran, "On the possibility of measuring gas concentrations by stimulated anti-Stokes scattering," Appl. Phys. Lett. 23, 240–242 (1973). [CrossRef]
  2. W. B. Rho, P. W. Schreibre, and J. P. E. Taran, "Singlepulse coherent anti-Stokes Raman scattering," Appl. Phys. Lett. 29, 174–176 (1976). [CrossRef]
  3. I. A. Stenhouse, D. R. Williams, J. B. Cole, and M. D. Swords, "CARS measurements in an internal combustion engine," Appl. Opt. 18, 3819–3825 (1979). [PubMed]
  4. W. M. Tolles, J. W. Nibler, J. R. McDonald, and A. B. Harvey, "A review of the theory and application of coherent anti-Stokes Raman spectroscopy," Appl. Spectrosc. 31, 253–271 (1977). [CrossRef]
  5. L. A. Rahn, S. C. Johnston, R. L. Farrow, and P. L. Mattern, "CARS thermometry in an internal combustion engine," in Temperature, Its Measurement and Control in Science and Industry, J. F. Schooley, ed. (Instrument Society of America, Pittsburgh, 1982), Vol. 5, Part 1, pp. 609–613.
  6. A. C. Eckbreth, G. M. Dobbs, J. H. Stufflebeam, and P. A. Tellex, "CARS temperature and species measurements in augmented jet engine exhausts," Appl. Opt. 23, 1328–1339 (1984). [CrossRef] [PubMed]
  7. G. L. Switzer, W. M. Roquemore, R. B. Bradley, P. W. Schreiber, and W. B. Rho, "CARS measurements in a bluffbody stabilized diffusion flame," Appl. Opt. 18, 2343–2345 (1979). [CrossRef] [PubMed]
  8. D. A. Greenhalgh, F. M. Porter, and W. A. England, "The application of coherent anti-Stokes Raman scattering to turbulent combustion thermometry," Combust. Flame 49, 171–181 (1983). [CrossRef]
  9. W. A. England, J. M. Milne, S. N. Jenny, and D. A. Greenhalgh, "Application of CARS to an operating chemical reactor," Appl. Spectrosc. 38, 867–875 (1984). [CrossRef]
  10. D. A. Klick, K. A. Marko, and L. Rimai, "Broadband singlepulse CARS spectra in a fired internal combustion engine," Appl. Opt. 20, 1178–1181 (1981). [CrossRef] [PubMed]
  11. S. A. J. Druet and J. P. E. Taran, "CARS spectroscopy," Prog. Quantum Electron. 7, 1–72 (1981). [CrossRef]
  12. J. W. Nibler and G. V. Knighten, "Coherent anti-Stokes Raman spectroscopy," in Raman Spectroscopy of Gases and Liquids, A. Weber, ed. (Springer-Verlag, Berlin, 1979), pp. 253–299. [CrossRef]
  13. R. J. Hall and A. C. Eckbreth, "Coherent anti-Stokes Raman spectroscopy (CARS): Application to combustion diagnostics," in Laser Applications, J. F. Ready and R. K. Erf, eds. (Academic, Orlando, Fla., 1984), Vol. 5, pp. 213–309.
  14. R. L. Farrow, R. P. Lucht, G. L. Clark, and R. E. Palmer, "Species concentration measurements using CARS with nonresonant susceptibility normalization," Appl. Opt. 24, 2241–2251 (1985). [CrossRef] [PubMed]
  15. R. L. Farrow and L. A. Rahn, "Interpreting coherent anti-Stokes Raman spectra measured with multimode Nd:YAG pump lasers," J. Opt. Soc. Am. B 2, 903–907 (1985). [CrossRef]
  16. M. Alden and W. Wendt, "Application of CARS spectroscopy to the detection of SO2," Appl. Spectrosc. 42, 1421–1426 (1988). [CrossRef]
  17. J. W. Hahn, S. N. Park, E. S. Lee, C. Rhee, K. T. Kang, S. H. Chung, C. Y. Choi, and Y. D. Huh, "Measuring the concentration of minor species from the modulation dip of the nonresonant background of broadband CARS spectra," Appl. Spectrosc. 47, 710–714 (1993). [CrossRef]
  18. J. Chang, J. Ducuing, and N. Bloembergen, "Relative phase measurement between fundamental and second-harmonic light," Phys. Rev. Lett. 15, 6–8 (1965). [CrossRef]
  19. Y. Yacoby, R. Fitzgibbon, and B. Lax, "Coherent cancellation of background in four-wave mixing spectroscopy," J. Appl. Phys. 51, 3072–3077 (1980). [CrossRef]
  20. G. Marowsky and G. Lupke, "CARS-background suppression by phase-controlled nonlinear interferometry," Appl. Phys. B 51, 49–51 (1990). [CrossRef]
  21. W. G. Rado, "The nonlinear third-order dielectric susceptibility coefficients of gases and optical third-harmonic generation," Appl. Phys. Lett. 11, 123–125 (1967). [CrossRef]
  22. T. Lundeen, S. Y. Hou, and J. W. Nibler, "Nonresonant thirdorder susceptibilities for various gases," J. Chem. Phys. 79, 6301–6305 (1983). [CrossRef]
  23. G. J. Rosasco and W. S. Hurst, "Measurement of resonant and nonresonant third-order nonlinear susceptibilities by coherent Raman spectroscopy," Phys. Rev. A 32, 281–299 (1985). [CrossRef] [PubMed]
  24. S. La and L. E. Harris, "Relative value of the third-order nonresonant susceptibility of water," Appl. Opt. 25, 4501–4503 (1986). [CrossRef]
  25. R. L. Farrow, R. P. Lucht, and L. A. Rahn, "Measurements of the nonresonant third-order susceptibilities of gases using coherent anti-Stokes Raman spectroscopy," J. Opt. Soc. Am. B 4, 1241–1246 (1987). [CrossRef]
  26. J. F. Ward and C. K. Miller, "Measurements of nonlinear optical polarizabilities for twelve small molecules," Phys. Rev. A 19, 826–833 (1979). [CrossRef]
  27. D. Heiman, R. W. Hellwarth, M. D. Levenson, and G. Martin, "Raman-induced Kerr effect," Phys. Rev. Lett. 36, 189–192 (1976). [CrossRef]
  28. G. J. Rosasco and W. S. Hurst, "Dispersion of the electronic contribution to the third-order nonlinear susceptibility of H2," J. Opt. Soc. Am. B 3, 1251–1256 (1986). [CrossRef]
  29. E. S. Lee, J. W. Hahn, S. N. Park, and C. Rhee, "Study on the interference of nonlinear-optical signals," J. Korean Opt. Soc. 3, 239–243 (1992).
  30. M. Born and E. Wolf, Principle of Optics, 5th ed. (Pergamon, Oxford, 1975), pp. 87–90.
  31. J. W. Hahn, S. N. Park, E. S. Lee, and C. Rhee, "Construction and performance test of a coherent anti-Stokes Raman spectrometer," Korean J. Appl. Phys. 4, 314–320 (1991).
  32. A. C. Eckbreth, "BOXCARS: Cross-beam phase-matched CARS generation in gases," Appl. Phys. Lett. 32, 421–423 (1978). [CrossRef]
  33. J. W. Hahn, S. N. Park, and C. Rhee, "Fabry–Perot wavemeter for shot-by-shot analysis of pulsed lasers," Appl. Opt. 32, 1095–1099 (1993). [CrossRef] [PubMed]
  34. H. W. Schrotter and H. W. Klockner, "Raman scattering cross sections in gases and liquids," in Raman Spectroscopy of Gases and Liquids, A. Weber, ed. (Springer-Verlag, Berlin, 1979), pp. 123–166. [CrossRef]
  35. J. Martin, "Raman intensities of propane in the gas phase," J. Raman Spectrosc. 16, 139–142 (1985). [CrossRef]
  36. M. G. Littman and H. J. Metcalf, "Spectral narrow pulsed dye laser without beam expander," Appl. Opt. 17, 2224–2227 (1978). [CrossRef] [PubMed]
  37. R. E. Palmer, "The CARSFIT computer code for calculating coherent anti-Stokes Raman spectra: user and programmer information," Sandia National Laboratories Rep. SAND89–8206.UC–13, 20 (Sandia National Laboratories, Livermore, Calif., 1989).
  38. G. Herzberg, Molecular Spectra and Molecular Structure, II. Infrared and Raman Spectra of Polyatomic Molecules (Van Nostrand Reinhold, New York, 1945), p. 276, pp. 370–372, pp. 394–395.
  39. W. L. Barnes, J. Susskind, R. H. Hunt, and E. K. Plyler, "Measurement and analysis of the v3 band of methane," J. Chem. Phys. 56, 5160–5172 (1972). [CrossRef]
  40. S. N. Suchard and J. E. Melzer, Spectroscopic Data (Information for Industry/Plenum, New York, 1976), Vol. 2, pp. 435–462.
  41. K. H. Hellwege, Landolt–Bornstein Numerical Data and Functional Relationships in Science and Technology, Group II: Atomic and Molecular Physics (Springer-Verlag, Berlin, 1983), Vol. 14, pp. 2–148
  42. D. P. Shelton and J. E. Rice, "Measurements and calculations of the hyperpolarizabilities of atoms and small molecules in the gas phase," Chem. Rev. 94, 3–29 (1994). [CrossRef]
  43. B. Lange and J. Wolfrum, "The impact of laser field statistics in determination of temperature and concentration by multiple USED CARS," Appl. Phys. B 51, 53–58 (1990). [CrossRef]

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