Vacuum ultraviolet spectrum of six-times ionized xenon, Xe vii

G. H. Cavalcanti; F. R. T. Luna; A. G. Trigueiros; F. Bredice; H. Sobral; R. Hutton; M. Wang

doi:10.1364/JOSAB.14.002459

Journal of the Optical Society of America B
Vol. 14,
Issue 10,
pp. 2459-2462
(1997)
•https://doi.org/10.1364/JOSAB.14.002459

Vacuum ultraviolet spectrum of six-times ionized xenon, Xe vii

G. H. Cavalcanti, F. R. T. Luna, A. G. Trigueiros, F. Bredice, H. Sobral, R. Hutton, and M. Wang

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G. H. Cavalcanti, F. R. T. Luna, A. G. Trigueiros, F. Bredice, H. Sobral, R. Hutton, and M. Wang, "Vacuum ultraviolet spectrum of six-times ionized xenon, Xe vii," J. Opt. Soc. Am. B 14, 2459-2462 (1997)

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Abstract

The theta-pinch spectrum of six-times ionized xenon, Xe vii, has been recorded in the vacuum ultraviolet region of 300–1300 Å, and 27 new transitions have been identified as combinations between levels of the $5 p 2 - 5 p 5 d$ and $5 s 5 d - 5 p 5 d$ transition arrays. From these transitions, 11 new levels have been determined. The energy-level assignments have been interpreted when the theoretical energy-level values were fitted with a least-squares approach. Hartree–Fock calculations with relativistic corrections were used to predict energy levels and transitions.

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Intensitya	Wavelengths (Å) (This study)	Wavelengths (Å) (Previous study)	Transition
40	482.86		$5 p^{2}^{1} D_{2} - 5 p 5 d^{1} P_{1}^{0}$
20	494.23		$5 p^{2}^{1} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
20	535.99		$5 p^{2}^{3} P_{2} - 5 p 5 d^{1} F_{3}^{0}$
40	548.73		$5 p^{2}^{3} P_{1} - 5 p 5 d^{3} D_{2}^{0}$
20	576.24		$5 p^{2}^{3} P_{2} - 5 p 5 d^{3} P_{1}^{0}$
20	580.68		$5 s 5 p^{3} P_{1}^{0} - 5 p 2^{1} S_{0}$
40	581.47		$5 p^{2}^{3} P_{2} - 5 p 5 d^{3} D_{3}^{0}$
40	598.09		$5 p^{2}^{3} P_{1} - 5 p 5 d^{1} D_{2}^{0}$
10	605.88		$5 p^{2}^{3} P_{2} - 5 p 5 d 3 D_{2}^{0}$
20	608.71	608.8b	$5 s 5 p^{1} P_{1}^{0} - 5 s 5 d^{1} D_{2}$
80	624.62		$5 p^{2}^{3} P_{2}^{0} - 5 p 5 d^{3} D_{1}^{0}$
40	643.39		$5 s 5 d^{3} D_{1} - 5 p 5 d^{1} P_{1}^{0}$
10	666.60		$5 p^{2}^{3} P_{2} - 5 p 5 d^{1} D_{2}^{0}$
20	667.92		$5 s 5 d^{3} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
10	726.56		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} P_{1}^{0}$
10	731.57		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} P_{1}^{0}$
20	737.38		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} P_{2}^{0}$
40	749.02		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} D_{3}^{0}$
20	764.05		$5 s 5 d^{1} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
20	805.36		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} D^{0}$
10	844.59		$5 s 5 d^{1} D_{2} - 5 p 5 d^{3} P_{2}^{0}$
20	857.63		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{4}^{0}$
10	928.86		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} F_{3}^{0}$
10	942.94		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{3}^{0}$
10	990.42		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} F_{2}^{0}$
10	999.64		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} F_{2}^{0}$
10	1016.19		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{2}^{0}$
20	1231.57		$5 s 5 d^{1} D_{2} - 5 p 5 d^{3} F_{2}^{0}$

Designation	Energy $({cm}^{- 1})$	$E (obs) - E (calc)$ a $({cm}^{- 1})$	Percentageb Composition
$4 d^{10} 5 p 5 d^{3} F_{2}^{0}$	$388742.2 \pm 2.0$	13	$83 + 14 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{3} F_{3}^{0}$	$396377.6 \pm 7.0$	$- 113$	$93 + 4 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{1} D_{2}^{0}$	$401873.4 \pm 5.0$	165	$50 + 21 (^{2} P)^{3} P + 9 (^{2} P)^{3} F + 8 (^{2} P)^{3} D + 11 (5 s 6 p$ $(^{2} S)^{3} P)$
$4 d^{10} 5 p 5 d^{3} F_{4}^{0}$	$406934.6 \pm 2.5$	$- 43$	98
$4 d^{10} 5 p 5 d^{3} D_{1}^{0}$	$411940.9 \pm 2.5$	$- 58$	$65 + 18 (^{2} P)^{3} P + 5 (^{2} S)^{3} P + 4 (^{2} P) +^{1} P + 5 (5 s 6 p$ $(^{2} S)^{1} P) + 5 (5 s 6 p (^{2} S) +^{3} P$
$4 d^{10} 5 p 5 d^{3} D_{2}^{0}$	$416910.4 \pm 6.0$	13	$40 + 31 (^{2} P)^{3} P + 19 (^{2} P)^{1} D + 4 (^{2} P)^{3} F + 5 (5 s 6 p$ $(^{2} S)^{3} P)$
$4 d^{10} 5 p 5 d^{3} D_{3}^{0}$	$423839.6 \pm 5.0$	$- 12$	$92 + 4 (^{2} P)^{3} F$
$4 d^{10} 5 p 5 d^{3} P_{0}^{0}$	424966.9c	100
$4 d^{10} 5 p 5 d^{3} P_{1}^{0}$	$425402.2 \pm 4.0$	64	$71 + 25 (^{2} P)^{3} D$
$4 d^{10} 5 p 5 d^{3} P_{2}^{0}$	$425947.7 \pm 2.5$	$- 57$	$81 + 15 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{1} F_{3}^{0}$	$438426.7 \pm 2.0$	$- 124$	$68 + 25 (5 s 5 f (^{2} S)^{1} F)$
$4 d^{10} 5 p 5 d^{1} P_{1}^{0}$	$443198.9 \pm 3.0$	66	$87 + 4 (^{2} P)^{3} D + 4 (5 d 4 f (^{2} F)^{1} P)$

Configuration	Parameter	HFR Value $({cm}^{- 1})$	Fitted Value $({cm}^{- 1})$	Ratio Fitted/HFR
$4 d^{10} 5 s 2$	$E^{av}$	0.0	10 586(103)	–
$4 d^{10} 5 p^{2}$	$E^{av}$	246 754	246 868(56)	1.000
$4 d^{10} 5 p^{2}$	$F^{2} (5 p 5 p)$	59 133	41 272(364)	0.700
$4 d^{10} 5 p^{2}$	$ζ_{3 p}$	10 573	11 318(56)	1.070
$4 d^{10} 5 s 5 d$	$E_{av}$	291 716	295 662(55)	1.013
$4 d^{10} 5 s 5 d$	$G^{2} (5 s 5 d)$	$38 852$	43 362(346)	1.116
$4 d^{10} 5 s 5 d$	$ζ_{5 d}$	849	1 078(56)	1.300
		aCI Integrals
$5 s^{2} - 5 p^{2}$		76 811	88 334b	1.150
$5 p^{2} - 5 s 5 d$		64 977	46 700b	0.719
		c $SD = 99 {cm}^{- 1}$
$4 d^{10} 5 s 5 p$	$E_{av}$	116 351	119 886(71)	1.030
	$G^{1} (5 s 5 p)$	76 823	60 389(268)	0.786
	$ζ_{5 p}$	10 652	11 752(113)	1.103
$4 d^{10} 5 p 5 d$	$E_{av}$	414 384	417 275(44)	1.007
	$F^{2} (5 p 5 d)$	49 801	42 404(822)	0.851
	$G^{1} (5 p 5 d)$	58 636	56 018(265)	0.955
	$G^{3} (5 p 4 d)$	37 484	25 566(726)	0.682
	$ζ_{5 p}$	10 759	11 546(168)	1.073
	$ζ_{5 d}$	866	1 033(103)	1.193
		aCI Integrals
$5 s 5 p - 5 p 5 d$	$R^{1} (5 s 5 p 5 p 5 d)$	65 650	76 314b	1.162
$5 s 5 p - 5 p 5 d$	$R^{1} (5 s 5 p 5 d 5 p)$	48 308	41 062b	0.850
		c $SD = 129 {cm}^{- 1}$

Intensitya	Wavelengths (Å) (This study)	Wavelengths (Å) (Previous study)	Transition
40	482.86		$5 p^{2}^{1} D_{2} - 5 p 5 d^{1} P_{1}^{0}$
20	494.23		$5 p^{2}^{1} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
20	535.99		$5 p^{2}^{3} P_{2} - 5 p 5 d^{1} F_{3}^{0}$
40	548.73		$5 p^{2}^{3} P_{1} - 5 p 5 d^{3} D_{2}^{0}$
20	576.24		$5 p^{2}^{3} P_{2} - 5 p 5 d^{3} P_{1}^{0}$
20	580.68		$5 s 5 p^{3} P_{1}^{0} - 5 p 2^{1} S_{0}$
40	581.47		$5 p^{2}^{3} P_{2} - 5 p 5 d^{3} D_{3}^{0}$
40	598.09		$5 p^{2}^{3} P_{1} - 5 p 5 d^{1} D_{2}^{0}$
10	605.88		$5 p^{2}^{3} P_{2} - 5 p 5 d 3 D_{2}^{0}$
20	608.71	608.8b	$5 s 5 p^{1} P_{1}^{0} - 5 s 5 d^{1} D_{2}$
80	624.62		$5 p^{2}^{3} P_{2}^{0} - 5 p 5 d^{3} D_{1}^{0}$
40	643.39		$5 s 5 d^{3} D_{1} - 5 p 5 d^{1} P_{1}^{0}$
10	666.60		$5 p^{2}^{3} P_{2} - 5 p 5 d^{1} D_{2}^{0}$
20	667.92		$5 s 5 d^{3} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
10	726.56		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} P_{1}^{0}$
10	731.57		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} P_{1}^{0}$
20	737.38		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} P_{2}^{0}$
40	749.02		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} D_{3}^{0}$
20	764.05		$5 s 5 d^{1} D_{2} - 5 p 5 d^{1} F_{3}^{0}$
20	805.36		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} D^{0}$
10	844.59		$5 s 5 d^{1} D_{2} - 5 p 5 d^{3} P_{2}^{0}$
20	857.63		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{4}^{0}$
10	928.86		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} F_{3}^{0}$
10	942.94		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{3}^{0}$
10	990.42		$5 s 5 d^{3} D_{1} - 5 p 5 d^{3} F_{2}^{0}$
10	999.64		$5 s 5 d^{3} D_{2} - 5 p 5 d^{3} F_{2}^{0}$
10	1016.19		$5 s 5 d^{3} D_{3} - 5 p 5 d^{3} F_{2}^{0}$
20	1231.57		$5 s 5 d^{1} D_{2} - 5 p 5 d^{3} F_{2}^{0}$

Designation	Energy $({cm}^{- 1})$	$E (obs) - E (calc)$ a $({cm}^{- 1})$	Percentageb Composition
$4 d^{10} 5 p 5 d^{3} F_{2}^{0}$	$388742.2 \pm 2.0$	13	$83 + 14 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{3} F_{3}^{0}$	$396377.6 \pm 7.0$	$- 113$	$93 + 4 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{1} D_{2}^{0}$	$401873.4 \pm 5.0$	165	$50 + 21 (^{2} P)^{3} P + 9 (^{2} P)^{3} F + 8 (^{2} P)^{3} D + 11 (5 s 6 p$ $(^{2} S)^{3} P)$
$4 d^{10} 5 p 5 d^{3} F_{4}^{0}$	$406934.6 \pm 2.5$	$- 43$	98
$4 d^{10} 5 p 5 d^{3} D_{1}^{0}$	$411940.9 \pm 2.5$	$- 58$	$65 + 18 (^{2} P)^{3} P + 5 (^{2} S)^{3} P + 4 (^{2} P) +^{1} P + 5 (5 s 6 p$ $(^{2} S)^{1} P) + 5 (5 s 6 p (^{2} S) +^{3} P$
$4 d^{10} 5 p 5 d^{3} D_{2}^{0}$	$416910.4 \pm 6.0$	13	$40 + 31 (^{2} P)^{3} P + 19 (^{2} P)^{1} D + 4 (^{2} P)^{3} F + 5 (5 s 6 p$ $(^{2} S)^{3} P)$
$4 d^{10} 5 p 5 d^{3} D_{3}^{0}$	$423839.6 \pm 5.0$	$- 12$	$92 + 4 (^{2} P)^{3} F$
$4 d^{10} 5 p 5 d^{3} P_{0}^{0}$	424966.9c	100
$4 d^{10} 5 p 5 d^{3} P_{1}^{0}$	$425402.2 \pm 4.0$	64	$71 + 25 (^{2} P)^{3} D$
$4 d^{10} 5 p 5 d^{3} P_{2}^{0}$	$425947.7 \pm 2.5$	$- 57$	$81 + 15 (^{2} P)^{1} D$
$4 d^{10} 5 p 5 d^{1} F_{3}^{0}$	$438426.7 \pm 2.0$	$- 124$	$68 + 25 (5 s 5 f (^{2} S)^{1} F)$
$4 d^{10} 5 p 5 d^{1} P_{1}^{0}$	$443198.9 \pm 3.0$	66	$87 + 4 (^{2} P)^{3} D + 4 (5 d 4 f (^{2} F)^{1} P)$

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Journal of the Optical Society of America B