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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 15, Iss. 1 — Jan. 1, 1998
  • pp: 426–431

Novel electro-optic molecular cocrystals with ideal chromophoric orientation and large second-order optical nonlinearities

Man Shing Wong, Feng Pan, Martin Bösch, Rolf Spreiter, Christian Bosshard, Peter Günter, and Volker Gramlich  »View Author Affiliations


JOSA B, Vol. 15, Issue 1, pp. 426-431 (1998)
http://dx.doi.org/10.1364/JOSAB.15.000426


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Abstract

We show, for the first time to our knowledge, that highly nonlinear optically active as well as orientationally optimized crystalline materials for second-order nonlinear optics can be prepared by a proper design of short hydrogen-bonded molecular aggregates derived from a specially developed merocyanine dye. One of the cocrystals is shown to be a very useful and highly efficient crystalline material for electro-optic devices because of the perfect chromophoric orientation, the large electro-optic coefficient r111=30±3 pm/V at λ=1535 nm, and the greatly improved physical properties such as higher melting point and crystal properties such as crystallinity. In addition, we demonstrate that one can vary or tune the linear and nonlinear optical properties of this cocrystal without modifying the chromophoric orientation in the crystal lattice by changing the crystal growth conditions.

© 1998 Optical Society of America

OCIS Codes
(160.2100) Materials : Electro-optical materials
(160.4330) Materials : Nonlinear optical materials
(160.4890) Materials : Organic materials
(190.0190) Nonlinear optics : Nonlinear optics
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials

Citation
Man Shing Wong, Feng Pan, Martin Bösch, Rolf Spreiter, Christian Bosshard, Peter Günter, and Volker Gramlich, "Novel electro-optic molecular cocrystals with ideal chromophoric orientation and large second-order optical nonlinearities," J. Opt. Soc. Am. B 15, 426-431 (1998)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-15-1-426


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References

  1. Ch. Bosshard, K. Sutter, Ph. Pretre, J. Hulliger, M. Flörsheimer, P. Kaatz, and P. Günter, in Organic Nonlinear Optical Materials, A. F. Garito and F. Kajzar, eds., Vol. 1 of Advances in Nonlinear Optics (Gordon & Breach, Basel, Switzerland, 1995).
  2. J. F. Nicoud and R. J. Twieg, “Design and synthesis of organic molecular compounds for efficient second-harmonic generation,” in Nonlinear Optical Properties of Organic Molecules and Crystals I, D. S. Chemla and J. Zyss, eds. (Academic, Orlando, Fla., 1987), pp. 227–296.
  3. L. T. Cheng, W. Tam, S. H. Stevenson, G. R. Meredith, G. Rikken, and S. Marder, “Experimental investigations of organic molecular nonlinear optical polarizabilities. 1. Methods and results on benzene and stilbene derivatives,” J. Phys. Chem. 95, 10631–10643 (1991). [CrossRef]
  4. L. T. Cheng, W. Tam, S. R. Marder, A. E. Stiegman, G. Rikken, and C. W. Spangler, “Experimental investigations of organic molecular nonlinear optical polarizabilities. 2. A study of conjugation dependences,” J. Phys. Chem. 95, 10643–10653 (1991). [CrossRef]
  5. W. Tam, B. Guerin, J. C. Calabrese, and S. H. Stevenson, “3-Methyl-4-methoxy-4-nitrostilbene (MMONS): crystal structure of a highly efficient material for second-harmonic generation,” Chem. Phys. Lett. 154, 93–96 (1989). [CrossRef]
  6. S. Marder, L.-T. Cheng, B. G. Tiemann, A. C. Friedli, M. Blanchard-Desce, J. W. Perry, and J. Sindhoj, “Large first hyperpolarizability in push–pull polyenes by tuning of the bond length alternation and aromaticity,” Science 263, 511–514 (1994). [CrossRef] [PubMed]
  7. M. S. Wong, C. Bosshard, F. Pan, and P. Günter, “Non-classical donor–acceptor chromophores for second-order nonlinear optics,” Adv. Mater. 8, 677–680 (1996). [CrossRef]
  8. M. S. Wong, U. Meier, F. Pan, C. Bosshard, V. Gramlich, and P. Günter, “Five-membered heteroaromatic hydrazone derivatives for second-order nonlinear optics,” Adv. Mater. 8, 416–420 (1996). [CrossRef]
  9. F. Pan, M. S. Wong, V. Gramlich, C. Bosshard, and P. Günter, “Crystal engineering based on short hydrogen bonds—co-crystallization of a highly nonlinear optical merocyanine dye with nitrophenol derivatives,” Chem. Commun. 1996, 557–1558 (1996).
  10. M. S. Wong, F. Pan, V. Gramlich, C. Bosshard, and P. Günter, “Self-assembly of acentric co-crystal of a highly hyperpolarizable merocyanine dye with optimized alignment for nonlinear optics,” Adv. Mater. 9, 554–557 (1997). [CrossRef]
  11. S. K. Kurtz and T. T. Perry, “A powder technique for the evaluation of nonlinear optical materials,” J. Appl. Phys. 39, 3798–3813 (1968). [CrossRef]
  12. M. S. Shumate, “Interferometric measurement of large indices of refraction,” Appl. Opt. 5, 327–331 (1966). [CrossRef] [PubMed]
  13. S. Follonier, Ch. Bosshard, U. Meier, G. Knöpfle, C. Serbutoviez, F. Pan, and P. Günter, “New nonlinear optical organic crystal: 4-dimethyl-aminobenzaldehyde-4-nitrophenyl-hydrazone,” J. Opt. Soc. Am. B 14, 593–601 (1997). [CrossRef]
  14. J. Jerphagnon and S. K. Kurtz, “Maker fringes: detailed comparison of theory and experiment for isotropic and uniaxial crystals,” J. Appl. Phys. 41, 1667–1681 (1970). [CrossRef]
  15. D. A. Roberts, “Simplified characterization of uniaxial and biaxial nonlinear optical crystals: a plea for standardization of nomenclature and conventions,” IEEE J. Quantum Electron. 28, 2057–2074 (1992). [CrossRef]
  16. R. C. Miller, “Optical second-harmonic generation in piezoelectric crystals,” Appl. Phys. Lett. 5, 17–19 (1964). [CrossRef]
  17. S. Kurtz, J. Jerphagnon, and M. M. Choy, “Nonlinear dielectric susceptibilities,” in Elastic, Piezoelectric, Pyroelectric, Piezooptic, Electrooptic Constants, and Nonlinear Dielectric Susceptibilities of Crystals, Vol. III/11 of Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology, K.-H. Hellwege and A. M. Hellwege, eds. (Springer-Verlag, Berlin, 1979), Chap. 6, pp. 671–743. For the nonlinear optical susceptibility d11 of quartz we used the arithmetic average of the different values reported in this reference.
  18. J. L. Oudar, “Optical nonlinearities of conjugated molecules. Stilbene derivatives and highly polar aromatics,” J. Chem. Phys. 67, 446–457 (1977). [CrossRef]

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