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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 16, Iss. 1 — Jan. 1, 1999
  • pp: 3–11

Spectroscopic studies of Mn4+ ions in yttrium orthoaluminate

M. A. Noginov and G. B. Loutts  »View Author Affiliations

JOSA B, Vol. 16, Issue 1, pp. 3-11 (1999)

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The absorption and emission spectra and the luminescence kinetics of Mn4+:YAlO3, the potential crystal for holographic recording and optical data storage, were studied at room and liquid-nitrogen temperatures. The spectroscopic properties of Mn:YAlO3 were compared with those of Mn:GdAlO3,Mn:Y3Al5O12, and Cr:YAlO3. It was found that a single-site occupancy of Mn4+ ions in YAlO3 and GdAlO3 at room temperature changes to a multisite occupancy at low temperature. Possible reasons for such a transformation are discussed. The parameters Dq and B in Mn4+:YAlO3 were determined to be 2115 and 680 cm-1, correspondingly.

© 1999 Optical Society of America

OCIS Codes
(160.2900) Materials : Optical storage materials
(160.6990) Materials : Transition-metal-doped materials
(210.4810) Optical data storage : Optical storage-recording materials
(300.1030) Spectroscopy : Absorption
(300.2140) Spectroscopy : Emission

M. A. Noginov and G. B. Loutts, "Spectroscopic studies of Mn4+ ions in yttrium orthoaluminate," J. Opt. Soc. Am. B 16, 3-11 (1999)

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  1. G. B. Loutts, M. Warren, L. Taylor, R. R. Rakhimov, H. R. Ries, G. Miller III, M. A. Noginov, M. Curley, N. Noginova, N. Kukhtarev, H. J. Caulfield, and P. Venkateswarlu, “Manganese-doped yttrium orthoaluminate: a potential material for holographic recording and data storage,” Phys. Rev. B 57, 3706–3709 (1998). [CrossRef]
  2. M. A. Noginov, N. Noginova, M. Curley, N. Kukhtarev, H. J. Caulfield, P. Venkateswarlu, and G. B. Loutts, “Optical characterization of Mn:YAlO3, material for holographic recording and data storage,” J. Opt. Soc. Am. B 15, 1463–1468 (1998). [CrossRef]
  3. R. R. Rakhimov, A. L. Wilkerson, G. B. Loutts, M. A. Noginov, N. Noginova, W. Lindsay, and H. R. Ries, “Spin and valence states of manganese ions in manganese-doped yttrium orthoaluminate,” Solid State Commun. 108, 549–555 (1998). [CrossRef]
  4. V. A. Antonov, P. A. Arsenev, Sh. A. Vakhidov, and E. M. Ibragimova, “Colour centers in yttrium aluminate crystals activated with transition metal ions,” Phys. Status Solidi A 22, 391–399 (1974). [CrossRef]
  5. V. A. Antonov, P. A. Arsenev, I. G. Linda, and V. L. Farshtendiker, “Studies of some point defects in YAlO3 and GdAlO3 single crystals,” Phys. Status Solidi A 15, K63–K68 (1973). [CrossRef]
  6. R. Diehl and G. Brant, “Crystal structure refinement of YAlO3, a promising laser material,” Mater. Res. Bull. 10, 85–90 (1975). [CrossRef]
  7. R. D. Shannon, “Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides,” Acta Crystallogr., Sect. A: Found. Crystallogr. 32, 751–767 (1976). [CrossRef]
  8. P. Dorenbos, M. V. Korzhik, A. P. Kudryavtseva, S. V. Lyubetskii, B. I. Minkov, V. P. Pavlenko, and A. A. Fyodorov, “Influence of growth defects on the scintillation characteristics of YAlO3:Ce single crystals,” J. Appl. Spectrosc. 59, 633–638 (1993). [CrossRef]
  9. R. Korczak and C. B. Staff, “Czochralski growth of neodymium-doped yttrium orthoaluminate,” J. Cryst. Growth 20, 71–72 (1973). [CrossRef]
  10. S. Kück, S. Hartung, S. Hurling, K. Petermann, and G. Huber, “Optical transitions in Mn3+-doped garnets,” Phys. Rev. B 57, 2203–2216 (1998). [CrossRef]
  11. P. D. Dernier and R. G. Maines, “High pressure synthesis and crystal data of the rare earth orthoaluminates,” Mater. Res. Bull. 6, 433–440 (1971). [CrossRef]
  12. S. Geshwind, P. Kisliuk, M. P. Klein, J. P. Remeika, and D. L. Wood, “Sharp-line fluorescence, electron paramagnetic resonance, and thermoluminescence of Mn4+ in α-Al2O3,” Phys. Rev. 126, 1684–1686 (1962). [CrossRef]
  13. L. A. Riseberg and M. J. Weber, “Spectrum and anomalous temperature dependence of the 2E→4A2 emission in Y3Al5O12:Mn4+,” Solid State Commun. 9, 791–794 (1974). [CrossRef]
  14. K. Petermann and G. Huber, “Broad band fluorescence of transition metal doped garnets and tungstates,” J. Lumin. 31/32, 71–77 (1984). [CrossRef]
  15. J. F. Donegan, T. J. Glynn, G. F. Imbusch, and J. P. Remeika, “Luminescence and fluorescence narrowing studies of Y3Al5O12:Mn3+,” J. Lumin. 36, 93–100 (1986). [CrossRef]
  16. A. van Die, A. C. H. I. Leenaers, W. F. van der Weg, and G. Blasse, “A search for luminescence of the trivalent manganese ion in solid aluminates,” Mater. Res. Bull. 22, 781–787 (1987). [CrossRef]
  17. A. Brenier, C. Pedrini, C. Madej, G. Boulon, and A. Suchocki, “Mn4+ multisites and Mn4+→Tm3+ energy transfers in Gd3Ga5O12 garnet,” J. Phys. IV 1, C7–285–C7–288 (1991).
  18. A. Brenier, A. Suchoski, C. Pedrini, G. Boulon, and C. Madej, “Spectroscopy of Mn4+-doped Ga-substituted gadolinium gallium garnet,” Phys. Rev. B 46, 3219–3227 (1992). [CrossRef]
  19. N. V. Asafev, N. A. Eskov, V. V. Kochurikhin, V. A. Myzina, P. A. Ryabochkina, V. B. Sulaev, S. N. Ushakov, and L. I. Tsymbal, “Spectral studies of calcium-niobium-gallium-garnet single crystals doped with Mn ions,” Opt. Spectrosc. 69, 229–230 (1990).
  20. B. Henderson and G. F. Imbusch, Optical Spectroscopy of Inorganic Solids (Clarendon, Oxford, 1989).
  21. R. G. Burns, Mineralogical Applications of Crystal Field Theory, 2nd ed. (Cambridge U. Press, Cambridge, 1993).
  22. J. A. Mares, G. Boulon, A. Brenier, L. Lou, S. T. Rotman, and H. Lura, “Cr3+, Nd3+ multisites, pairs, and energy transfer processes in laser crystal YAlO3,” J. Phys. III 4, C-385–C4–388 (1994).
  23. Z. N. Zonn, V. A. Ioffe, and P. P. Feofilov, “Luminescence of chromium and manganese ions in lanthanum aluminate crystals,” Opt. Spectrosc. 19, 541–543 (1965).
  24. V. A. Antonov and P. A. Arsenev, “Properties of ions of the iron transition group in the lattice of single crystals of gadolinium aluminate,” Phys. Status Solidi A 20, K157–K161 (1973). [CrossRef]
  25. M. J. Weber and T. E. Varitimos, “Optical spectra and relaxation of Cr3+ ions in YAlO3,” J. Appl. Phys. 45, 810–816 (1974). [CrossRef]
  26. See, for example, E. V. Zharikov, in Redkozemel’nyye Scandievye Granaty: Voprosy Materialovedeniya (Rare Earth Scandium Garnets: The Materials Science Aspects), I. A. Shcherbakov, ed., Vol. 26 of Proceedings of the General Physics Institute (Nauka, Moscow, 1990).
  27. Th. Förster, “Zwischenmolekulare Energiewanderung und Fluoreszenz,” Ann. Phys. (Leipzig) 2, 55–75 (1948). [CrossRef]
  28. J. P. van der Ziel, “Spectrum of exchange coupled Cr3+ pairs in YAlO3,” J. Chem. Phys. 57, 2442–2450 (1972). [CrossRef]
  29. S. R. Rotman, E. Luria, J. A. Mares, G. Boulon, A. Brenier, and L. Lou, “Time decay of excited chromium- and neodymium-doped yttrium aluminum perovskite,” J. Appl. Phys. 80, 1094–1098 (1996). [CrossRef]

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