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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 16, Iss. 1 — Jan. 1, 1999
  • pp: 83–89

Effective nonlinear coefficients of organic powders measured by second-harmonic generation in total reflection: numerical and experimental analysis

R. Kremer, A. Boudrioua, J. C. Loulergue, and A. Iltis  »View Author Affiliations

JOSA B, Vol. 16, Issue 1, pp. 83-89 (1999)

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A second-harmonic wave generated by an evanescent wave (SHEW) is used to measure the effective nonlinear coefficient of organic materials in powder form. The SHEW signal is less sensitive than the powder method to the phase-matching conditions of the material. For this reason, the SHEW technique can be used to survey a wide variety of samples. The effective nonlinear coefficient and the refractive indices of the sample are obtained as fitting parameters. The influence of experimental conditions on the fitting process is discussed. The results obtained from our powders are compared with the nonlinear coefficients of the same materials in bulk crystal form. Good agreement is found between experimental results and literature values.

© 1999 Optical Society of America

OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(160.4760) Materials : Optical properties
(160.4890) Materials : Organic materials
(190.2620) Nonlinear optics : Harmonic generation and mixing
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials

R. Kremer, A. Boudrioua, J. C. Loulergue, and A. Iltis, "Effective nonlinear coefficients of organic powders measured by second-harmonic generation in total reflection: numerical and experimental analysis," J. Opt. Soc. Am. B 16, 83-89 (1999)

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  1. S. Sottini, D. Grando, L. Palchetti, E. Ricceri, and G. Gabrielli, “Organic films for guided nonlinear optics,” Mater. Sci. Eng. C 5, 167 (1998).
  2. E. Van Tomme, P. P. Van Daele, R. G. Baets, and P. E. Lagasse, “Integrated optics devices based on nonlinear optical polymers,” IEEE J. Quantum Electron. 27, 778 (1991). [CrossRef]
  3. S. Dirr, A. Bohler, S. Wiess, H. H. Johannes, and W. Kowalsky, “Organic light emitting diodes with reduced spectral and spatial halfwidths,” Jpn. J. Appl. Phys., Part 1 37, 1457 (1998). [CrossRef]
  4. X. Zhu, Y. M. Chen, M. Kamath, R. J. Jeng, J. Kumar, and S. K. Tripathy, “Efficient Cerenkov second harmonic generation crosslinked poled polymer waveguides,” Nonlinear Opt. 4, 175 (1993).
  5. D. Y. Chen, N. Okamoto, T. Sasaki, S. Tasaka, and R. Matsushima, “2nd harmonic-generation from mixtures of organic nonlinear materials MNA and PNA,” IEIC Trans. Commun. Electron. Inf. Sys. 74, 946 (1991).
  6. J. Jerphagnon and S. K. Kurtz, “Maker fringes: a detailed comparison of theory and experiment for isotropic and uniaxial crystals,” J. Appl. Phys. 41, 1667 (1970). [CrossRef]
  7. S. K. Kurtz and T. T. Perry, “A powder technique for the evaluation of nonlinear optical materials,” J. Appl. Phys. 39, 3798 (1968). [CrossRef]
  8. M. Kiguchi, M. Kato, N. Kumegawa, and Y. Taniguchi, “Technique for evaluating second-order nonlinear optical materials in powder form,” J. Appl. Phys. 75, 4432 (1994). [CrossRef]
  9. M. Kiguchi, M. Kato, N. Kumegawa, and Y. Taniguchi, “A new measurement of second harmonic generation efficiency,” Mol. Cryst. Liq. Cryst. 227, 133 (1993). [CrossRef]
  10. M. Kiguchi, M. Kato, M. Okunaka, and Y. Taniguchi, “New method of measuring second harmonic generation efficiency using powder crystals,” Appl. Phys. Lett. 60, 1933 (1992). [CrossRef]
  11. M. Kiguchi, M. Kato, N. Kumegawa, M. Okunaka, and Y. Taniguchi, “Simple evaluation for second-order nonlinear optical materials in powder form,” Nonlinear Opt. 9, 223 (1995).
  12. J. Kawamata, K. Inoue, T. Inabe, M. Kiguchi, M. Kato, and Y. Taniguchi, “Large second-harmonic generation coefficients of bis(benzylidene)cycloalkanones estimated by the second-harmonic wave generated with the evanescent wave technique,” Chem. Phys. Lett. 249, 29 (1996). [CrossRef]
  13. N. Bloembergen and P. S. Pershan, “Light waves at the boundary of nonlinear media,” Phys. Rev. 128, 606 (1962). [CrossRef]
  14. J. Zyss, J. F. Nicoud, and M. Coquillay, “Chirality and hydrogen bonding in molecular crystals for phase-matched second-harmonic generation: N-(4-nitrophenyl)-(L)-prolinol (NPP),” J. Chem. Phys. 81, 4160 (1984). [CrossRef]
  15. M. Kiguchi, “Comparison of error properties of techniques used for measuring second-order nonlinear optical coefficients with least-squares fitting,” J. Opt. Soc. Am. B 12, 871 (1995). [CrossRef]
  16. R. L. Sutherland, Handbook of Nonlinear Optics (Marcel Dekker, New York, 1988).
  17. J. Zyss, D. S. Chemla, and J. F. Nicoud, “Demonstration of efficient nonlinear optical crystals with vanishing molecular dipole moment: second harmonic generation in 3-methyl-4-nitropyridine-1-oxide,” J. Chem. Phys. 74, 4800 (1981). [CrossRef]
  18. J. D. Bierlein, L. K. Cheng, Y. Wang, and W. Tam, “Linear and nonlinear optical properties of 3-methyl-4-methoxy-4-nitrostilbene single crystals,” Appl. Phys. Lett. 56, 423 (1990). [CrossRef]
  19. P. V. Vidakovic, M. Coquillay, and F. Salin, “N-(4-nitrophenyl)-N-methylamino-acetonitrile: a new organic material for efficient second harmonic generation in bulk and waveguide configurations: I. Growth, crystal structure, and characterization of organic crystal-cored fibers,” J. Opt. Soc. Am. B 4, 998 (1987). [CrossRef]

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