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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 16, Iss. 12 — Dec. 1, 1999
  • pp: 2269–2277

Spectroscopic investigations of the 4f5d energy levels of Pr3+ in fluoride crystals by excited-state absorption and two-step excitation measurements

Mathieu Laroche, Alain Braud, Sylvain Girard, Jean Louis Doualan, Richard Moncorge, Michel Thuau, and Larry D. Merkle  »View Author Affiliations


JOSA B, Vol. 16, Issue 12, pp. 2269-2277 (1999)
http://dx.doi.org/10.1364/JOSAB.16.002269


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Abstract

Excited-state absorption spectra obtained by a pulsed pump–probe technique specially designed for the near-UV spectral domain were recorded in three Pr3+-doped fluoride crystals (KY3F10,LiYF4, and BaY2F8). These excited-state absorption spectra correspond to optical transitions from the  3P0 or the  1D2 metastable levels of the 4f2 configuration up to the first energy levels of the 4f5d electronic configuration. The position, the anisotropic behavior, and the line shape of the observed excited-state absorption bands are discussed and compared with ground-state absorption (from level  3H4) or direct excitation spectra available in the literature. Subsequently, two-step excitation into the 4f5d high-lying energy levels of Pr3 by means of  3P0 and  1D2 is shown to be an efficient way to produce broadband UV fluorescence by use of pump beams in the blue and the near UV.

© 1999 Optical Society of America

OCIS Codes
(020.4180) Atomic and molecular physics : Multiphoton processes
(140.3580) Lasers and laser optics : Lasers, solid-state
(160.3380) Materials : Laser materials
(160.5690) Materials : Rare-earth-doped materials
(190.7220) Nonlinear optics : Upconversion
(300.6540) Spectroscopy : Spectroscopy, ultraviolet

Citation
Mathieu Laroche, Alain Braud, Sylvain Girard, Jean Louis Doualan, Richard Moncorge, Michel Thuau, and Larry D. Merkle, "Spectroscopic investigations of the 4ƒ5d energy levels of Pr3+ in fluoride crystals by excited-state absorption and two-step excitation measurements," J. Opt. Soc. Am. B 16, 2269-2277 (1999)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-16-12-2269


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References

  1. D. J. Erlich, P. F. Moulton, and R. M. Osgood, Jr., “Ultraviolet solid-state Ce:YLF laser at 325 nm,” Opt. Lett. 4, 184–186 (1979). [CrossRef]
  2. D. J. Erlich, P. F. Moulton, and R. M. Osgood, Jr., “Optically pumped Ce:LaF3 laser at 286 nm,” Opt. Lett. 5, 339–341 (1980). [CrossRef]
  3. W. Waynant and P. H. Klein, “Vacuum ultraviolet laser emission from Nd3+LaF3,” Appl. Phys. Lett. 46, 14–16 (1985). [CrossRef]
  4. M. A. Dubinskii, V. V. Semashko, A. K. Naumov, R. Yu. Abdulsabirov, and S. L. Korableva, “Ce3+-doped colquiriite. A new concept of all-solid-state tunable ultraviolet laser,” J. Mod. Opt. 40, 1–5 (1993). [CrossRef]
  5. J. F. Pinto, G. H. Rosenblatt, L. Esterowitz, and G. J. Quarles, “Tunable solid-state laser action in Ce3+:LiSrAlF6,” Electron. Lett. 30, 240–241 (1994). [CrossRef]
  6. C. D. Marshall, S. A. Payne, J. A. Speth, W. F. Krupke, G. J. Quarles, V. Castillo, and B. H. T. Chai, “Ultraviolet laser emission properties of Ce3+-doped LiSrAlF6 and LiCaAlF6,” J. Opt. Soc. Am. B 11, 2054–2065 (1994). [CrossRef]
  7. N. Sarukura, M. A. Dubinskii, Z. Liu, V. V. Semashko, A. K. Naumov, S. L. Korableva, R. Y. Abdulsabirov, K. Edamatsu, Y. Suzuki, T. Itoh, and Y. Segawa, “Ce3+-activated fluoride crystals as prospective active media for widely tunable ultraviolet ultrafast lasers with direct 10-ns pumping,” IEEE J. Sel. Top. Quantum Electron. 1, 792–804 (1995). [CrossRef]
  8. J. F. Pinto, L. Esterowitz, and T. J. Carrig, “Solid-state UV radiation from 223–243 nm,” in Advanced Solid State La-sers, C. R. Pollock and W. R. Bosenberg, eds., Vol. 10 of OSA Trends in Optics and Photonics Series (1997), pp. 14–15.
  9. Z. Liu, H. Ohtake, N. Sarukura, M. Dubinskii, R. Yu. Abdulsabirov, and S. L. Korableva, “All-solid-state tunable ultraviolet picosecond Ce3+:LiLuF4 laser with direct pumping by the fifth harmonic of a Nd:YAG laser,” in Advanced Solid State Lasers, W. R. Bosenberg and M. M. Fejer, eds., Vol. 19 of OSA Trends in Optics and Photonics Series (1998), pp. 13–15.
  10. P. Rambaldi, R. Moncorgé, J. P. Wolf, C. Pedrini, and J. Y. Gesland, “Efficient and stable pulsed laser operation of Ce:LiLuF4 around 308 nm,” Opt. Commun. 146, 163–166 (1998). [CrossRef]
  11. J. K. Lawson and S. A. Payne, “Excited-state absorption of Pr3+-doped fluoride crystals,” Opt. Mater. 2, 225–232 (1993). [CrossRef]
  12. D. S. Hamilton, S. K. Gayen, G. J. Pogatshnik, R. D. Ghen, and W. J. Miniscalco, “Optical-absorption and photo ionization measurements from the excited-state of Ce3+:Y3Al5O12,” Phys. Rev. 39, 8807–8815 (1989). [CrossRef]
  13. Ki-Loo Sim and D. S. Hamilton, “Optical gain and loss studies in Ce3+:YLiF4,” J. Opt. Soc. Am. B 6, 1401–1406 (1989). [CrossRef]
  14. N. V. Kuleshov, V. G. Shcherbitsky, A. A. Lagatsky, V. P. Mikhailov, B. I. Minkov, T. Danger, T. Sandrock, and G. Huber, “Spectroscopy, excited-state absorption and stimulated emission in Pr3+-doped Gd2SiO5 and Y2SiO5 crystals,” J. Lumin. 71, 27–35 (1997). [CrossRef]
  15. L. Esterowitz, F. J. Bartoli, R. E. Allen, D. E. Wortman, C. A. Morrison, and R. P. Leavitt, “Energy levels and line intensities of Pr3+ in LiYF4,” Phys. Rev. B 19, 6442–6455 (1979). [CrossRef]
  16. G. M. Renfro, J. C. Windscheif, W. A. Sibley, and R. F. Belt, “Optical transitions of Pr3+ and Er3+ ions in LiYF4,” J. Lumin. 22, 51–68 (1980). [CrossRef]
  17. J. L. Adam, W. A. Sibley, and D. R. Gabbe, “Optical absorption and emission of LiYF4:Pr3+,” J. Lumin. 33, 391–407 (1985). [CrossRef]
  18. W. W. Piper, J. A. DeLuca, and F. S. Ham, “Cascade fluorescence decay in Pr3+-doped fluorides: achievement of a quantum yield greater than unity for emission of visible light,” J. Lumin. 8, 344–348 (1974). [CrossRef]
  19. B. M. Antipenko, “Spectroscopic properties of the system BaYb2F8: rare earth ions,” Opt. Spektrosk. 56, 72–77 (1984).
  20. A. A. Kaminskii and S. E. Sarkisov, “Stimulated-emission spectroscopy of Pr3+ ions in monoclinic BaY2F8 fluoride,” Phys. Status Solidi A 97, K163–K168 (1986). [CrossRef]
  21. S. P. Chernov, L. I. Devyatkova, O. N. Ivanova, A. A. Kaminskii, V. V. Mikhailin, S. N. Rudnev, and T. V. Uvarova, “5d14fn−1–4fn absorption and luminescence of Ce3+, Pr3+ and Nd3− ions in BaY2F8 single crystals,” Phys. Status Solidi A 88, K169–K173 (1985). [CrossRef]
  22. C. A. Morrison, D. F. Wortman, R. P. Leavitt, and H. P. Jenssen, “Assessment of Pr3+:KY3F10 as blue–green laser,” Rep. HDL-TR 1897 (Harry Diamond Laboratories, Adelphi, Md., 1980).
  23. A. Braud, S. Girard, J. L. Doualan, and R. Moncorgé, “Spectroscopy and fluorescence dynamics of (Tm3+, Tb3+) and of (Tm3+, Eu3+) doped LiYF4 single crystals for 1.5 μm laser operation,” IEEE J. Quantum Electron. 34, 2246–2255 (1998). [CrossRef]
  24. R. A. McFarlane, “Upconversion laser in BaY2F8:Er 5% pumped by ground-state and excited-state absorption,” J. Opt. Soc. Am. B 11, 871–880 (1994). [CrossRef]
  25. K. H. Yang and J. A. Deluca, “Vacuum-ultraviolet excitation studies of 5d14fn−1 to 4fn and 4fn to 4fn transitions of Nd3+-, Er3+- and Tm3+-doped trifluorides,” Phys. Rev. B 17, 4246–4255 (1978). [CrossRef]
  26. J. C. Krupa and M. Queffelec, “UV and VUV optical excitations in wide band gap materials doped with rare earth ions: 4f–5d transitions,” J. Alloys Compd. 250, 287–292 (1997). [CrossRef]
  27. E. Sarantopoulou, A. C. Cefalas, M. A. Dubinskii, C. A. Nicolaides, R. Yu. Abdulsabirov, S. L. Korableva, A. K. Naumov, and V. V. Semasko, “VUV and UV fluorescence and absorption studies of Pr3+-doped LiLuF4 single crystals,” Opt. Lett. 19, 499–501 (1994). [CrossRef] [PubMed]
  28. A. A. Kaplyanski and A. K. Przhevuskii, “Deformation splitting and enhancement of spectral lines and structure of excited levels of Eu2+ in alkali-earth fluoride crystals,” Opt. Spectrosc. 19, 331–338 (1965).
  29. T. Hoshina and S. Z. Kuboniwa, “4f–5d transition of Tb3+ and Ce3+ in MPO4 (M=Sc, Y and Lu),” J. Phys. Soc. Jpn. 31, 828–840 (1971). [CrossRef]
  30. J. Sugar, “Analysis of the spectrum of triply ionized Praseodymium (PrIV),” J. Opt. Soc. Am. 55, 1058–1061 (1965). [CrossRef]
  31. J. S. Griffith, “The theory of transition-metal ions” (Cambridge U. Press, Cambridge, UK, 1964).

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