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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 16, Iss. 6 — Jun. 1, 1999
  • pp: 998–1006

Two-photon fluorescence cross-section measurements calibrated with hyper-Rayleigh scattering

Philip Kaatz and David P. Shelton  »View Author Affiliations


JOSA B, Vol. 16, Issue 6, pp. 998-1006 (1999)
http://dx.doi.org/10.1364/JOSAB.16.000998


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Abstract

The intensity of two-photon-excited fluorescence measured relative to the intensity of hyper-Rayleigh scattering in the same apparatus was used to determine the two-photon-excited fluorescence cross sections of the xanthene dyes Rhodamine B, Rhodamine 6G, and Fluorescein. The measured cross sections at λ0=1064 nm are σ2PF(2)=1.5±0.3×10-50 cm4 s,2.0±0.4×10-50 cm4 s, and 1.4±0.3×10-52 cm4 s, for the three dyes, respectively. The two-photon-excited fluorescence cross section of Rhodamine B was also calibrated with one-photon-excited fluorescence in this apparatus. The result, σ2PF(2)=2.3±0.7×10-50 cm4 s, is in reasonable agreement with the result calibrated by hyper-Rayleigh scattering. The results for Rhodamine B are 1.5–6 times smaller than previous results calibrated by one-photon-excited fluorescence.

© 1999 Optical Society of America

OCIS Codes
(190.4180) Nonlinear optics : Multiphoton processes
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials
(300.2530) Spectroscopy : Fluorescence, laser-induced
(300.6410) Spectroscopy : Spectroscopy, multiphoton

Citation
Philip Kaatz and David P. Shelton, "Two-photon fluorescence cross-section measurements calibrated with hyper-Rayleigh scattering," J. Opt. Soc. Am. B 16, 998-1006 (1999)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-16-6-998


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References

  1. W. Denk, J. H. Strickler, and W. W. Webb, “Two-photon laser scanning fluorescence microscopy,” Science 248, 73–76 (1990). [CrossRef] [PubMed]
  2. S. Marou, O. Nakamura, and S. Kawata, “Three-dimensional microfabrication with two-photon-absorbed photopolymerization,” Opt. Lett. 22, 132–134 (1997). [CrossRef]
  3. G. S. He, G. C. Xu, P. N. Prasad, B. Reinhardt, J. C. Bhatt, and A. G. Dillard, “Two-photon absorption and optical-limiting properties of novel organic compounds,” Opt. Lett. 20, 435–437 (1995). [CrossRef] [PubMed]
  4. M. Cha, W. E. Torruellas, G. I. Stegeman, W. H. G. Horsthuis, G. R. Möhlmann, and J. Meth, “Two photon absorption of di-alkyl-amino-nitro-stilbene side chain polymer,” Appl. Phys. Lett. 65, 2648–2650 (1994). [CrossRef]
  5. J. P. Hermann and J. Ducuing, “Absolute measurement of two-photon cross sections,” Phys. Rev. A 5, 2557–2568 (1972). [CrossRef]
  6. W. L. Smith, “Two-photon absorption in condensed media,” in CRC Handbook of Laser Science and Technology. III. Optical Materials: Part 1, M. J. Weber, ed. (CRC, Boca Raton, Fla., 1986), p. 229–258.
  7. A. Fischer, C. Cremer, and E. H. K. Stelzer, “Fluorescence of coumarins and xanthenes after two-photon absorption with a pulsed titanium–sapphire laser,” Appl. Opt. 34, 1989–2003 (1995). [CrossRef] [PubMed]
  8. I. M. Catalano and A. Cingolani, “Absolute two-photon fluorescence with low-power lasers,” Appl. Phys. Lett. 38, 745–747 (1981). [CrossRef]
  9. C. Xu and W. W. Webb, “Measurement of two-photon excitation cross sections of molecular fluorophores with data from 690 to 1050 nm,” J. Opt. Soc. Am. B 13, 481–491 (1996). [CrossRef]
  10. S. Li and C. Y. She, “Two-photon absorption cross-section measurements in common laser dyes at 1064 μm,” Opt. Acta 29, 281–287 (1982). [CrossRef]
  11. D. J. Bradley, M. H. R. Hutchinson, and H. Koetser, “Interactions of picosecond laser pulses with organic molecules. II. Two-photon absorption cross sections,” Proc. R. Soc. London, Ser. A 329, 105–119 (1972). [CrossRef]
  12. J. P. Hermann and J. Ducuing, “Dispersion of the two-photon cross section in rhodamine dyes,” Opt. Commun. 6, 101–105 (1972). [CrossRef]
  13. P. Kaatz and D. P. Shelton, “Polarized hyper-Rayleigh light scattering measurements of nonlinear optical chromophores,” J. Chem. Phys. 105, 3918–3929 (1996). [CrossRef]
  14. P. Kaatz and D. P. Shelton, “Spectral measurements of hyper-Rayleigh light scattering,” Rev. Sci. Instrum. 67, 1438–1444 (1996). [CrossRef]
  15. P. Kaatz, E. A. Donley, and D. P. Shelton, “A comparison of molecular hyperpolarizabilities from gas and liquid phase measurements,” J. Chem. Phys. 108, 849–856 (1998). [CrossRef]
  16. C. Xu, J. B. Shear, and W. W. Webb, “Hyper-Rayleigh and hyper-Raman scattering background of liquid water in two-photon excited fluorescence detection,” Anal. Chem. 69, 1285–1287 (1997). [CrossRef] [PubMed]
  17. R. Bersohn, Y. H. Pao, and H. L. Frisch, “Double-quantum light scattering by molecules,” J. Chem. Phys. 45, 3184–3198 (1966). [CrossRef]
  18. D. A. Haner, B. T. McGuckin, R. T. Menzies, C. T. Bruegge, and V. Duval, “Directional–hemispherical reflectance for spectralon by integration of its bidirectional reflectance,” Appl. Opt. 37, 3996–3999 (1998). [CrossRef]
  19. P. Sperber and A. Penzkofer, “S0-Sn two-photon absorption dynamics of rhodamine dyes,” Opt. Quantum Electron. 18, 381–401 (1986). [CrossRef]
  20. D. A. Long, Raman Spectroscopy (McGraw-Hill, New York, 1977).
  21. R. Loudon, The Quantum Theory of Light (Clarendon, Oxford, 1983).
  22. D. P. Shelton, “Raman overtone intensities measured for H2,” J. Chem. Phys. 93, 1491–1495 (1990). [CrossRef]
  23. D. M. Bishop and J. Pipin, “Calculated Raman overtone intensities for H2 and D2,” J. Chem. Phys. 94, 6073–6080 (1991). [CrossRef]
  24. E. W. Van Stryland and L. L. Chase, “Two-photon absorption: inorganic materials,” in CRC Handbook of Laser Science and Technology. Supplement 2: Optical Materials, M. J. Weber, ed. (CRC, Boca Raton, Fla., 1995), pp. 299–328.
  25. I. Shoji, T. Kondo, A. Kitamoto, M. Shirane, and R. Ito, “Absolute scale of second-order nonlinear-optical coefficients,” J. Opt. Soc. Am. B 14, 2268–2294 (1997). [CrossRef]
  26. D. A. Roberts, “Simplified characterization of uniaxial and biaxial nonlinear optical crystals: a plea for standardization of nomenclature and conventions,” IEEE J. Quantum Electron. 28, 2057–2074 (1992). [CrossRef]
  27. K. Hagimoto and A. Mito, “Determination of the second-order susceptibility of ammonium dihydrogen phosphate and α-quartz at 633 and 1064 nm,” Appl. Opt. 34, 8276–8282 (1995). [CrossRef] [PubMed]
  28. N. N. Vsevolodov, L. P. Kostikov, L. P. Kayushin, and V. I. Gorbatenkov, “Two-photon absorption of laser radiation by chlorophyll-a and certain organic dyes,” Biophysics (GB) 18, 807 (1973).
  29. D. M. Bishop and J. Pipin, “Improved dynamic hyperpolarizabilities and field-gradient polarizabilities for helium,” J. Chem. Phys. 91, 3549–3551 (1989). [CrossRef]
  30. D. P. Shelton, “Nonlinear-optical susceptibilities of gases measured at 1064 and 1319 nm,” Phys. Rev. A 42, 2578–2592 (1990). [CrossRef] [PubMed]
  31. E. A. Donley and D. P. Shelton, “Hyperpolarizabilities measured for interacting molecular pairs,” Chem. Phys. Lett. 215, 156–162 (1993); “Erratum,” 228, 701 (1994). [CrossRef]
  32. D. P. Shelton and J. E. Rice, “Measurements and calculations of the hyperpolarizabilities of atoms and small molecules in the gas phase,” Chem. Rev. 94, 3–29 (1994). [CrossRef]
  33. R. J. Bartlett and H. Sekino, “Can quantum chemistry provide reliable molecular hyperpolarizabilities?” in Nonlinear Optical Materials: Theory and Modeling, S. P. Kama and A. T. Yeates, eds., ACS Symp. Ser. 628, 23–57 (1996). [CrossRef]
  34. P. Norman, Y. Luo, D. Jonsson, H. Ågren, K. O. Sylvester-Hvid, and K. V. Mikkelsen, “Hyperpolarizability depolarization ratios of nitroanilines,” J. Chem. Phys. 107, 9063–9066 (1997). [CrossRef]

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