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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 17, Iss. 4 — Apr. 1, 2000
  • pp: 572–579

Nonlinear optical properties of solgel-derived glasses doped with copper selenide nanoparticles

K. V. Yumashev, N. N. Posnov, I. A. Denisov, P. V. Prokoshin, V. P. Mikhailov, V. S. Gurin, V. B. Prokopenko, and A. A. Alexeenko  »View Author Affiliations

JOSA B, Vol. 17, Issue 4, pp. 572-579 (2000)

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Transient differential absorption spectra of solgel glasses that contain copper selenide nanoparticles (NP’s) have been studied with a picosecond pump–probe technique. Oxidation of copper selenide NP’s results in the appearance of an additional absorption band peaked at ∼1 μm, which can be transiently bleached under laser excitation. Excited-state absorption related to mid-gap surface trap states was observed. The absorption recovery time was found to be ∼300 ps. The intensity-dependent transmission of oxidized copper selenide NP’s in solgel glass at 1.08 μm has been measured. Permanent laser-induced absorption changes in the glasses were studied with nanosecond pulses as a function of laser exposure. Passive Q switching of 1.06-μm Nd3+:Y3Al5O12, 1.34-μm Nd3+:YAlO3, and 1.54-μm Er3+: glass lasers has been realized with the glasses containing copper selenide NP’s used as saturable absorbers. Q-switched pulses with 100-ns (1.06 μm), 90-ns (1.34 μm), and 60-ns (1.54 μm) pulse widths were obtained.

© 2000 Optical Society of America

OCIS Codes
(140.3540) Lasers and laser optics : Lasers, Q-switched
(160.6060) Materials : Solgel
(320.7130) Ultrafast optics : Ultrafast processes in condensed matter, including semiconductors

K. V. Yumashev, N. N. Posnov, I. A. Denisov, P. V. Prokoshin, V. P. Mikhailov, V. S. Gurin, V. B. Prokopenko, and A. A. Alexeenko, "Nonlinear optical properties of solgel-derived glasses doped with copper selenide nanoparticles," J. Opt. Soc. Am. B 17, 572-579 (2000)

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  1. N. Peyghambarian, B. Fluegel, D. Hulin, A. Migus, M. Joffre, A. Antonetti, S. W. Koch, M. Lindberg, “Femtosecond optical nonlinearities of CdSe quantum dots,” IEEE J. Quantum Electron. 25, 2516–2522 (1989).
  2. Y. D. Yoffe, “Low-dimensional systems: quantum size effects and electronic properties of semiconductor microcrystallites (zero-dimensional systems) and some quasi-two-dimensional systems,” Adv. Phys. 42, 173–266 (1993).
  3. S. V. Gaponenko, Optical Properties of Semiconductor Nanocrystals (Cambridge U. Press, Cambridge, 1998).
  4. M. C. Schanne-Klein, F. Hache, D. Ricard, and C. Flytzanis, “Optical phase conjugation in Schott CdSSe-doped glasses: origin of the nonlinear response,” J. Opt. Soc. Am. B 9, 2234–2239 (1992).
  5. N. F. Borelli, D. W. Hall, H. J. Holland, and D. W. Smith, “Quantum confinement effects of semiconducting microcrystallites in glass,” J. Appl. Phys. 61, 5399–5409 (1987).
  6. J. Butty, Y. Z. Hu, N. Peyghambarian, Y. H. Kao, and J. D. Mackenzie, “Quasicontinuous gain in sol-gel derived CdS quantum dots,” Appl. Phys. Lett. 67, 2672–2674 (1995).
  7. U. Keller, K. J. Weingarten, F. X. Kartner, D. Kopf, B. Braun, I. D. Jung, R. Fluck, C. Honninger, N. Matuschek, and J. A. der Au, “Semiconductor saturable absorber mirrors (SESAM’s) for femtosecond to nanosecond pulse generation in solid-state lasers,” IEEE J. Sel. Top. Quantum Electron. 2, 435–451 (1996).
  8. G. Bret and F. Gires, “Giant pulse laser and light amplifier using variable transmission coefficient glasses as light switches,” Appl. Phys. Lett. 4, 175–179 (1964).
  9. E. Munin, A. B. Villaverde, and M. Bass, “Broad band, tunable passive Q-switching with semiconductor doped glass filters,” Opt. Commun. 108, 278–282 (1994).
  10. N. Sarukura, Y. Ishida, T. Yanagawa, and H. Nakano, “All-solid-state cw passively mode locked Ti:sapphire laser using a colored glass filter,” Appl. Phys. Lett. 57, 229–230 (1990).
  11. I. P. Bilinsky, B. E. Bouma, and J. G. Fujimoto, “Self-starting KLM Ti:Al2O3 laser using semiconductor-doped glass structure,” in Conference on Lasers and Electro-Optics (CLEO/U.S.), Vol. 6 of 1998 OSA Technical Digest Series (Optical Society of America, Washington, D.C., 1998), pp. 333–334.
  12. K. V. Yumashev, V. P. Mikhailov, P. V. Prokoshin, S. P. Jmako, and I. V. Bodnar, “CuInSSe-doped glass saturable absorbers for passive mode-locking of neodymium lasers,” Appl. Phys. Lett. 65, 2768–2770 (1994).
  13. P. T. Guerreiro, S. Ten, N. F. Borrelli, J. Butty, G. E. Jabbour, and N. Peyghambarian, “PbS quantum-dot doped glasses as saturable absorbers for mode-locking of a Cr:forsterite laser,” Appl. Phys. Lett. 71, 1595–1597 (1997).
  14. K. V. Yumashev, A. M. Malyarevich, P. V. Prokoshin, N. N. Posnov, V. S. Gurin, and M. V. Artemyev, “Optical transient bleaching/absorption of surface-oxidized CuInS2 nanocrystals,” Appl. Phys. B 65, 545–548 (1997).
  15. K. V. Yumashev, P. V. Prokoshin, A. M. Malyarevich, V. P. Mikhailov, M. V. Artemyev, and V. S. Gurin, “Optical transient bleaching and induced absorption of surface-modified copper sulfide nanocrystals,” Appl. Phys. B 64, 73–78 (1997).
  16. A. M. Malyarevich, N. N. Posnov, I. A. Denisov, K. V. Yumashev, and V. P. Mikhailov, “Ultrafast optical processes in new Cu-Fe-S nanoparticles,” in ICONO’98: Ultrafast Phenomena and Interaction of Super-Strong Laser Fields with Matter: Nonlinear Optics and High-Field Physics, M. V. Fedorov, V. M. Gordienko, V. V. Shuvalov, and V. D. Taranukhin, eds., Proc. SPIE 3735, 121–128 (1999).
  17. L. Spanhel, E. Arpac, and H. Schmidt, “Semiconductor clusters in the sol-gel process: synthesis and properties of CdS nanocomposites,” J. Non-Cryst. Solids 147/148, 657–662 (1992).
  18. M. Nogami, S. Suzuki, and K. Nagasaka, “Sol-gel processing of small-sized CdSe crystal-doped silica glasses,” J. Non-Cryst. Solids 135, 182–188 (1991).
  19. T. Rajh, M. I. Vucemilovic, N. M. Dimitrijevic, O. I. Micic, and A. J. Nozik, “Size quantization of colloidal semiconductor particles in silicate glasses,” Chem. Phys. Lett. 143, 305–308 (1988).
  20. V. S. Gurin, V. B. Prokopenko, I. M. Melnichenko, E. N. Poddenezhny, A. A. Alexeenko, and K. V. Yumashev, “Formation of ultrafine particles of copper and copper sulfide in silica films and glasses prepared by sol-gel technique,” J. Non-Cryst. Solids 232–234, 162–168 (1998).
  21. V. S. Gurin, V. B. Prokopenko, A. A. Alexeenko, I. M. Melnichenko, V. P. Mikhailov, K. V. Yumashev, and M. A. Malyarevich, “Formation and optical characteristics of copper chalcogenide nanocrystals in amorphous matrices,” Funct. Mater. 6, 464–468 (1999).
  22. K. L. Chopra and S. R. Das, Thin Film Solar Cells (Plenum, New York, 1983).
  23. V. V. Gorbachev, Semiconductor Compounds A2IBIV (Metallurgia, Moscow, 1980, in Russian), p. 132.
  24. Z. Vucic, O. Milat, V. Horvatic, and Z. Ogorelec, “Composition-induced phase transition splitting in cuprous selenide,” Phys. Rev. B 24, 5398–5401 (1981).
  25. R. D. Heyding and R. M. Murray, “The crystal structure of Cu1.8Se, Cu3Se2, alpha- and gamma-CuSe, CuSe2 and CuSe2-II,” Can. J. Chem. 54, 841–848 (1976).
  26. W. Rudolph and H. Weber, “Analysis of saturable absorbers, interacting with gaussian pulses,” Opt. Commun. 34, 491–496 (1980).
  27. P. Roussignol, D. Ricard, J. Lukasik, and C. Flytzanis, “New results on optical phase conjugation in semiconductor-doped glasses,” J. Opt. Soc. Am. B 4, 5–13 (1987).
  28. M. Mitsunaga, H. Shinojima, and K. Kubodera, “Laser annealing effect on carrier recombination time in CdSxSe1−x-doped glasses,” J. Opt. Soc. Am. B 5, 1448–1454 (1988).
  29. J. Malhotra, D. J. Hagan, and B. G. Potter, “Laser-induced darkening in semiconductor-doped glasses,” J. Opt. Soc. Am. B 8, 1531–1536 (1991).
  30. T. Yanagawa, H. Nakano, Y. Ishida, and K. Kubodera, “Host glass dependence of photodarkening in colored filter glasses,” Opt. Commun. 100, 118–123 (1993).
  31. V. I. Klimov and V. A. Karavanskii, “Mechanisms for optical nonlinearities and ultrafast carrier dynamics in CuxS nanocrystals,” Phys. Rev. B 54, 8087–8094 (1996).
  32. V. I. Klimov, P. Haring-Bolivar, H. Kurz, and V. A. Karavanskii, “Optical nonlinearities and carrier trapping dynamics in CdS and CuxS nanocrystals,” Superlattices Microstruct. 20, 395–404 (1996).
  33. A. E. Siegman, Lasers (University Science, Mill Valley, Calif., 1986).

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