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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 18, Iss. 12 — Dec. 1, 2001
  • pp: 1846–1853

Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors

A. Galvan-Gonzalez, G. I. Stegeman, A. K-Y. Jen, X. Wu, M. Canva, A. C. Kowalczyk, X. Q. Zhang, H. S. Lackritz, S. Marder, S. Thayumanavan, and G. Levina  »View Author Affiliations

JOSA B, Vol. 18, Issue 12, pp. 1846-1853 (2001)

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The photostability of various electro-optic active guest–host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyamino- or diarylamino-benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was found in the probability that an absorbed photon will lead to a photodegraded chromophore. The most photostable chromophore contained a tricyanovinyl acceptor and a diarylaminobenzene bridge unit.

© 2001 Optical Society of America

OCIS Codes
(160.2100) Materials : Electro-optical materials
(160.4330) Materials : Nonlinear optical materials
(190.4400) Nonlinear optics : Nonlinear optics, materials
(260.5130) Physical optics : Photochemistry

A. Galvan-Gonzalez, G. I. Stegeman, A. K-Y. Jen, X. Wu, M. Canva, A. C. Kowalczyk, X. Q. Zhang, H. S. Lackritz, S. Marder, S. Thayumanavan, and G. Levina, "Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors," J. Opt. Soc. Am. B 18, 1846-1853 (2001)

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  1. R. A. Hill, S. Dreher, A. Knoesen, and D. R. Yankelevich, “Reversible optical storage utilizing pulsed, photoinduced, electric-field-assisted reorientation of azobenzenes,” Appl. Phys. Lett. 66, 2156–2158 (1995).
  2. D. Chen, H. R. Fetterman, A. Chen, W. H. Steier, L. R. Dalton, W. Wang, and Y. Shi, “Demonstration of 110 GHz electro-optic polymer modulators,” Appl. Phys. Lett. 70, 3335–3337 (1997).
  3. For example, A. Grunnet-Jepsen, C. L. Thompson, R. J. Twieg, and W. E. Moerner, “High performance photorefractive polymer with improved stability,” Appl. Phys. Lett. 70, 1515–1517 (1997).
  4. For example, G. Gu, D. Z. Garbuzov, P. E. Burrows, S. Venkatesh, S. R. Forrest, and M. E. Thompson, “High-external-quantum-efficiency organic light-emitting devices,” Opt. Lett. 22, 396–399 (1997).
  5. Y. Shi, C. Zhang, H. Zhang, J. Betchel, L. Dalton, B. Robinson, and W. Steier, “Low (sub 1 volt) halfwave voltage polymeric electro-optic modulator achieved by controlling chromophore shape,” Science 288, 119–122 (2000).
  6. I. Ledoux, J. Zyss, E. Barni, C. Barolo, N. Diulgheroff, P. Quagliotto, and G. Viscardi, “Properties of novel azodyes containing powerful acceptor groups and thiophene moiety,” Synth. Met. 115, 213–217 (2000).
  7. A. K. Y. Jen, Y. Liu, L. Zheng, S. Liu, K. J. Drost, Y. Zhang, and L. Dalton, “Synthesis and characterization of highly efficient, chemically and thermally stable chromophores with chromone-containing electron acceptors for NLO applications,” Adv. Mater. 11, 452–455 (1999).
  8. For example, D. H. Choi, J. H. Park, N. Kim, and S.-D. Lee, “Improved temporal stability of the second-order nonlinear optical effect in a sol-gel matrix bearing an active chromophore,” Chem. Mater. 10, 705–709 (1998).
  9. M. Stahelin, C. A. Walsh, D. M. Burland, R. D. Miller, R. J. Twieg, and W. Volksen, “Orientational decay in poled polymer second-order nonlinear optical guest-host polymers: temperature dependence and effects of poling geometry,” J. Appl. Phys. 73, 8471–8479 (1993).
  10. For example, R. J. Twieg, D. M. Burland, J. L. Hedrick, V. Y. Lee, R. D. Miller, C. R. Moylan, W. Volksen, and C. A. Walsh, “Progress on nonlinear optical chromophores and polymers with useful nonlinearity and thermal stability,” Mater. Res. Soc. Symp. Proc. 328, 421–431 (1994).
  11. Y. M. Cai and A. K-Y. Jen, “Thermally stable poled polyquinoline thin film with very large electro-optic response,” Appl. Phys. Lett. 117, 299–301 (1995).
  12. H. Ma, J. Y. Wu, P. Herguth, B. Q. Chen, and A. K.-Y. Jen, “A novel class of high-performance perfluorocyclobutane-containing polymers for second-order nonlinear optics,” Chem. Mater. 12, 1187–1189 (2000).
  13. X. M. Wu, J. Y. Wu, Y. Q. Liu, and A. K-Y. Jen, “Facile approach to nonlinear optical side-chain aromatic polyimides with large second-order nonlinearity and thermal stability,” J. Am. Chem. Soc. 121, 472–473 (1999).
  14. M. A. Mortazavi, H. N. Yoon, and C. C. Teng, “Optical power handling properties of polymeric nonlinear optical waveguides,” J. Appl. Phys. 74, 4871–4873 (1993).
  15. M. Mortazavi, K. Song, H. Yoon, and McCulloh, “Optical power handling of nonlinear polymers,” Polymer Reprints 35, 198–199 (1994).
  16. R. A. Norwood, D. R. Holcomb, and F. F. So, “Polymers for nonlinear optics: absorption, two photon absorption,” Nonlinear Opt. 6, 193–204 (1993).
  17. M. Cha, W. E. Torruellas, G. I. Stegeman, W. H. G. Horsthuis, G. R. Mohlmann, and J. Meth, “Two photon absorption of DANS (Di-alkyl-amino-nitro-stilbene) side chain polymer,” Appl. Phys. Lett. 65, 2648–2650 (1994).
  18. Ph. Pretre, E. Sidlick, A. Knoesen, D. J. Dyer, and R. J. Twieg, “Optical dispersion properties of tricyanovinylaniline polymer films for ultrashort optical pulse diagnostics,” ACS Symp. Ser. 695, 328–341 (1996).
  19. Q. Zhang, M. Canva, and G. Stegeman, “Wavelength dependence of 4-dimethylamino-4′nitrostilbene polymer thin film photodegradation,” Appl. Phys. Lett. 73, 912–914 (1998).
  20. A. Galvan-Gonzalez, M. Canva, G. Stegeman, R. Twieg, T. Kowalczyk, and H. Lackritz, “Effect of temperature and atmospheric environment on the photodegradation of some Disperse Red 1-type polymers,” Opt. Lett. 24, 1741–1743 (1999).
  21. A. Galvan-Gonzalez, M. Canva, and G. Stegeman, “Local and external factors affecting the photodegradation of 4N, N′-dimethylamino-4′-nitrostilbene polymer films,” Appl. Phys. Lett. 75, 3306–3308 (1999).
  22. A. Galvan-Gonzalez, M. Canva, G. Stegeman, R. Twieg, K. Chan, T. Kowalczyk, X. Zhang, H. Lackritz, S. Marder, and S. Thayumanavan, “Systematics behavior of electro-optic chromophore photostability,” Opt. Lett. 25, 332–334 (2000).
  23. A. Galvan-Gonzalez, M. Canva, G. I. Stegeman, L. Sukhomlinova, R. J. Twieg, K.-P. Chan, T. C. Kowalczyk, and H. S. Lackritz, “Photodegradation of azobenzene nonlinear optical chromophores: the influence of structure and environment,” J. Opt. Soc. Am. B 17, 1992–2000 (2000).
  24. A. Galvan-Gonzalez, K. D. Belfield, G. I. Stegeman, M. Canva, K.-P. Chan, K. Park, L. Sukhomlinova, and R. J. Twieg, “Photostability enhancement of an azobenzene photonic polymer,” Appl. Phys. Lett. 77, 2083–2085 (2000).
  25. A. Dubois, M. Canva, A. Brun, F. Chaput, and J.-P. Boilot, “Photostability of dye molecules trapped in solid matrices,” Appl. Opt. 35, 3193 (1996).
  26. A. C. Le Duff, V. Ricci, T. Pliska, M. Canva, G. Stegeman, K. Chan, and R. Twieg, “Importance of chromophore environment on the near-infrared absorption of polymeric waveguides,” Appl. Opt. 39, 947–953 (2000).

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