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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 19, Iss. 1 — Jan. 1, 2002
  • pp: 37–42

Bulk and near-surface second-order nonlinearities generated in a BK7 soft glass by thermal poling

Mingxin Qiu, Toru Mizunami, Ramon Vilaseca, Francesc Pi, and Gaspar Orriols  »View Author Affiliations

JOSA B, Vol. 19, Issue 1, pp. 37-42 (2002)

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Bulk second-order nonlinearity was generated in BK7 glass at a higher temperature and with a longer poling time than near-surface second-order nonlinearity. The temporal decay of the bulk second-order nonlinearity was slower than that of the near-surface second-order nonlinearity. The thickness of the near-surface nonlinear layer increased with poling time. Poled BK7 glass was also measured by x-ray photoelectron spectroscopy. Depletion of Na at the anodic surface and its accumulation at the cathodic surface was observed. At the cathodic surface, a higher-energy peak near O (1s) appeared, which shows peroxy-radical defects. At the anodic surface, a lower-energy peak near Si (2p) appeared, which may be attributed to E centers or to two-coordinated Si defects. The mechanisms of generation of these defects and of the second-order nonlinearities are discussed.

© 2002 Optical Society of America

OCIS Codes
(160.2750) Materials : Glass and other amorphous materials
(160.4330) Materials : Nonlinear optical materials
(190.4160) Nonlinear optics : Multiharmonic generation
(190.4350) Nonlinear optics : Nonlinear optics at surfaces
(240.4350) Optics at surfaces : Nonlinear optics at surfaces

Mingxin Qiu, Toru Mizunami, Ramon Vilaseca, Francesc Pi, and Gaspar Orriols, "Bulk and near-surface second-order nonlinearities generated in a BK7 soft glass by thermal poling," J. Opt. Soc. Am. B 19, 37-42 (2002)

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  1. D. S. Chemla and J. Zyss, eds. Nonlinear Properties of Organic Molecules and Crystals (Academic, New York, 1987).
  2. R. A. Myers, N. Mukherjee, and S. R. J. Brueck, “Large second-order nonlinearity in poled fused silica,” Opt. Lett. 16, 1732–1737 (1991). [CrossRef] [PubMed]
  3. R. Kashyap, G. J. Veldhuis, D. C. Rogers, and P.F. Mckee, “Phase-matched second-harmonic generation by periodic poling of fused silica,” Appl. Phys. Lett. 64, 1332–1334 (1994). [CrossRef]
  4. A. Le Calvez, E. Freysz, and A. Ducasse, “Experimental study of the origin of the second-order nonlinearities induced in thermally poled fused silica,” Opt. Lett. 22, 1547–1549 (1997). [CrossRef]
  5. V. Pruneri, F. Samoggia, G. Bonfrate, P. G. Kazansky, and G. M. Yang, “Thermal poling of silica in air and under vacuum: the influence of charge transport on second harmonic generation, Thermal poling of silica in air and under vacuum: the influence of charge transport on second harmonic generation, ’ Appl. Phys. Lett. 74, 2423–2425 (1999). [CrossRef]
  6. K. Tanaka, K. Kashima, K. Hirao, N. Soga, A. Mito, and H. Nasu, “Second harmonic generation in poled tellurite glasses,” Jpn. J. Appl. Phys., Part 2 32, L843–L845 (1993). [CrossRef]
  7. M.-X. Qiu, T. Mizunami, H. Koya, F. Pi, and G. Orriols, “Large second-order susceptibility in poled ZF7 lead silica for sum-frequency generation,” in Proceedings of Nonlinear Optics ’98, catalog no. 98CH36244 (Institute of Electrical and Electronic Engineers, Piscataway, N.J., 1998), pp. 370–372.
  8. M.-X. Qiu, F. Pi, G. Orriols, and M. Bibiche, “Signal damping of second-harmonic generation in poled soda-lime silicate glasses,” J. Opt. Soc. Am. B 15, 1362–1365 (1998). [CrossRef]
  9. H. Nasu, H. Okamoto, K. Kurachi, J. Matsuoka, K. Kamiya, A. Mito, and H. Hosono, “Second-harmonic generation from electrically poled SiO2 glasses: effects of OH concentration, defects, and poling conditions,” J. Opt. Soc. Am. B 12, 644–649 (1995). [CrossRef]
  10. L. J. Henry, A. D. DeVilbiss, and T. E. Tsai, “Effect of preannealing on the level of second-harmonic generation and defect sites achieved in poled low-water fused silica,” J. Opt. Soc. Am. B 12, 2037–2045 (1995). [CrossRef]
  11. Y. Quiquempois, G. Martinelli, P. Dutherage, P. Bernage, P. Niay, and M. Douay, “Localisation of the induced second-order non-linearity within Infrasil and Suprasil thermally poled glasses,” Opt. Commun. 176, 479–487 (2000). [CrossRef]
  12. M.-X. Qiu, R. Vilaseca, M. Botey, J. Sellares, F. Pi, and G. Orriols, “Double fitting of Maker fringes to characterize near-surface and bulk second-order nonlinearities in poled silica,” Appl. Phys. Lett. 76, 3346–3348 (2000). [CrossRef]
  13. D. E. Carlson, “Ion depletion of glass at a blocking anode: I. Theory and experimental results for alkali silicate glasses,” J. Am. Ceram. Soc. 57, 291–294 (1974). [CrossRef]
  14. M.-X. Qiu, Y. Takagaki, S. Egawa, T. Mizunami, and R. Vilaseca, “Large second-order susceptibility generated in the cathodic face of silica by doping F anions,” Opt. Commun. 172, 97–101 (1999). [CrossRef]
  15. J. Kosikova and J. Schrofel, “Planar optical waveguides prepared in GIL49 and BK7 glass substrates by K+–Na+ ion exchange with the electric field assistance,” J. Electron. Mater. 28, 1088–1095 (1999). [CrossRef]
  16. V. Nazabal, E. Fargin, C. Labrugere, and G. Le Flem, “Second-harmonic generation optimization in thermally poled borophosphate glasses and characterization by XANES and XPS,” J. Non-Cryst. Solids 270, 223–233 (2000). [CrossRef]
  17. K. Tanaka, A. Narazaki, Y. Yonezaki, and K. Hirao, “Poling-induced structural change and second-order nonlinearity of Na+-doped Nb2O5–TeO2 glass,” J. Phys. Condens. Matter 12, L513–L518 (2000). [CrossRef]
  18. M.-X. Qiu, S. Egawa, K. Horimoto, and T. Mizunami, “The thickness evolution of the second-order nonlinear layer in thermally poled fused silica,” Opt. Commun. 189, 161–166 (2001). [CrossRef]
  19. T. Gross, M. Ramm, H. Sonntag, W. Unger, H. M. Weijers, and E. H. Adem, “An XPS analysis of different SiO2 modifications employing a C 1s as well as an Au 4f7/2 static charge reference,” Surf. Interface Anal. 18, 59–64 (1992). [CrossRef]
  20. M.-X. Qiu, T. Mizunami, T. Shimomura, and M. Ohtaki, “Threshold conditions for bulk second-order nonlinearity and near-surface nonlinearity in thermally poled Infrasil silica,” Opt. Rev. 8, 159–162 (2001). [CrossRef]
  21. J. Khaled, T. Fujiwara, M. Ohama, and A. J. Ikushima, “Generation of second harmonic in Ge-doped SiO2 thin films by ultraviolet irradiation under poling electric field,” J. Appl. Phys. 87, 2137–2141 (2000). [CrossRef]
  22. T. G. Alley, S. R. J. Brueck, and M. Wiedenbeck, “Secondary ion mass spectroscopy of space-charge formation in thermally poled fused silica,” J. Appl. Phys. 86, 6634–6640 (1999). [CrossRef]
  23. D. Sprenger, H. Bach, W. Meisel, and P. Gutlich, “Discrete bond model (DBM) of sodium silicate glasses derived from XPS, Raman, and NMR measurements,” J. Non-Cryst. Solids 159, 187–203 (1993). [CrossRef]
  24. D. O. Henderson, M. A. George, Y. S. Tung, R. Mu, A. Burger, S. H. Morgan, W. E. Collins, C. W. White, R. A. Zuhr, and R. H. Magruder III, “X-ray photoelectron and infrared spectroscopies of Cu-implanted silica and borosilicate glasses,” J. Vac. Sci. Technol. A 13, 1254–1259 (1995). [CrossRef]
  25. G. Pacchioni and M. Vitiello, “Infra-red electron paramagnetic resonance and x-ray photoemission spectral properties of point defects in silica from first-principle calculations,” J. Non-Cryst. Solids 245, 175–182 (1999). [CrossRef]
  26. V. S. Kortov, I. N. Shabanova, A. F. Zatsepin, S. F. Lomaeva, V. I. Ushakova, and V. Ya. Bayankin, “Radiation damage to the surface of oxide dielectrics irradiated by fast electrons,” Phys. Chem. Mech. Surf. 2, 529–539 (1984).

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