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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 19, Iss. 6 — Jun. 1, 2002
  • pp: 1349–1354

Laser action from 1,3,5,7-tetramethyl-2,6-diethyl-8-n-propyl pyrromethene-BF2

Heping Zeng, Feng Liang, Zhenrong Sun, Yizhong Yuan, Zuguang Yao, and Zhizhan Xu  »View Author Affiliations


JOSA B, Vol. 19, Issue 6, pp. 1349-1354 (2002)
http://dx.doi.org/10.1364/JOSAB.19.001349


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Abstract

We measured spectroscopic and laser action properties of a novel 8-position substituted pyrromethene-BF2, namely 1,3,5,7-tetramethyl-2,6-diethyl-8-n-propyl pyrromethene-BF2 complex. The laser action was performed with the corresponding dye solution in ethanol, which was placed in a Littman-type laser cavity pumped by the second harmonic of a Q-switched Nd:YAG laser. The spectroscopic measurements clearly indicated that the corresponding dye solution in ethanol exhibited intense absorption in the visible spectral region with large fluorescence quantum yield. It possesses rather low triplet–triplet absorption in the spectral region 460–550 nm and almost negligible triplet-triplet absorption in the lasing spectral region. As a consequence, it lases nearly as efficiently as commercially available benchmark laser dyes such as Rhodamine-6G and outperformed them in wavelength tunability in our laser cavity and pump geometry.

© 2002 Optical Society of America

OCIS Codes
(160.0160) Materials : Materials

Citation
Heping Zeng, Feng Liang, Zhenrong Sun, Yizhong Yuan, Zuguang Yao, and Zhizhan Xu, "Laser action from 1,3,5,7-tetramethyl-2,6-diethyl-8-n-propyl pyrromethene-BF2," J. Opt. Soc. Am. B 19, 1349-1354 (2002)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-19-6-1349


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References

  1. T. G. Pavlopoulos, M. Shah, and J. H. Boyer, “Laser action from a tetramethyl-pyrromethene-BF2 complex,” Appl. Opt. 27, 4998–4999 (1988).
  2. T. G. Pavlopoulos, M. Shah, and J. H. Boyer, “Efficient laser action from 1,3,5,7,8-pentamethyl-BF2 complex and its 2,6-disulfonate derivative,” Opt. Commun. 70, 425–427 (1989).
  3. M. Shah, K. Thangaraj, M.-L. Soong, L. T. Wofford, J. H. Boyer, I. R. Politzer, T. G. Pavlopoulos, “Pyrromethene-BF2 complexes as laser dyes: 1,” Hereoat. Chem. 1, 389–399 (1990).
  4. T. G. Pavlopoulos, J. H. Boyer, M. Shah, K. Thangaraj, and M.-L. Soong, “Laser action from 2,6,8-position trisubsituted 1,3,5,7-tetramethyl pyrromethene-BF2 complexes: part 1,” Appl. Opt. 29, 3885–3886 (1990).
  5. J. H. Boyer, A. Haag, M.-L. Soong, K. Thangaraj, and T. G. Pavlopoulos, “Laser action from 2,6,8-trisubstituted 1,3,5,7-tetramethylpyrromethene-BF2 complexes: part 2,” Appl. Opt. 30, 3788–3789 (1991).
  6. T. G. Pavlopoulos, J. H. Boyer, and G. Sathyamoorthi, “Laser action from a 2,6,8-position trisubstituted 1,3,5,7-tetramethylpyrromethene-BF2 complex: part 3,” Appl. Opt. 37, 7797–7800 (1998).
  7. R. E. Hermes, T. H. Allik, S. Chandra, and J. A. Hutchinson, “High-efficiency pyrromethene doped solid-state dye lasers,” Appl. Phys. Lett. 63, 877–879 (1993).
  8. M. Faloss, M. Canva, P. Georges, A. Brun, F. Chaput, and J. Boilot, “Toward millions of laser pulses with pyrromethene- and perylene-doped xerogels,” Appl. Opt. 36, 6760–6763 (1997).
  9. A. J. Finlayson, N. Peters, P. V. Kolinsky, and M. R. W. Venner, “Flashlamp pumped solid-state dye laser incorporating pyrromethene 597,” Appl. Phys. Lett. 75, 457–459 (1999).
  10. H. Kang and R. Hangland, “Long wavelength chemically reactive dipyrrometheneboron difluoride dyes and conjugates,” United States Patent No. 5274113.
  11. H. Kang and R. Hangland, “Fluorescent fatty acids derived from dipyrrometheneboron difluoride dyes,” United States Patent No. 5338854.
  12. L. Morgen and J. Boyer, “Boron difluoride compounds useful in photodynamic therapy and production of laser light,” United States Patent No. 5446157.
  13. T. G. Pavlopoulos, J. H. Boyer, K. Thangaraj, G. Sathyamoorthi, M. P. Shah, and M.-L. Soong, “Laser dye spectroscopy of some pyrromethene-BF2 complexes,” Appl. Opt. 31, 7089–7094 (1992).
  14. M. P. O’Neil, “Synchronously pumped visible laser dye with twice the efficiency of Rhodamine-6G,” Opt. Lett. 18, 37–38 (1993).
  15. F. L. Arbeloa, T. L. Arbeloa, I. L. Arbeloa, I. Garcia-Moreno, A. Costela, R. Sastre, F. Amat-Guerri, “Photophysical and lasing properties of pyrromethene 567 dye in liquid solution. Environment effects,” Chem. Phys. 236, 331–341 (1998).
  16. S. G. Guggenheimer, J. H. Boyer, K. Thangargj, M. Shah, M.-L. Soong, and T. G. Pavlopoulos, “Efficient laser action from two cw laser pumped pyrromethene-BF2 complexes,” Appl. Opt. 32, 3942–3943 (1993).
  17. T. G. Pavlopoulos, M. Shah, and J. H. Boyer, “Efficient laser action from 1,3,5,7,8-pentamethyl-BF2 complex and its 2,6-disulfonate derivative,” Opt. Commun. 70, 425–427 (1989).
  18. T. Arbeloa, F. Arbeloa, I. Arbeloa, I. Garcia-Moreno, A. Costela, R. Sastre, F. Amat-Guerri, “Correlations between photophysics and lasing properties of dipyrromethene-BF2 dye in solution,” Chem. Phys. Lett. 299, 315–321 (1999).
  19. M. D. Rahn, T. A. King, A. A. Gorman and I. Hamblett, “Photostability enhancement of pyrromethene 567 and perylene orange in oxygen-free liquid and solid dye lasers,” Appl. Opt. 36, 5862–5871 (1997).
  20. Y. Assor, Z. Burshtein, and S. Rosenwaks, “Spectroscopy and laser characteristics of copper-vapor-laser pumped pyrromethene-556 and pyrromethene-567 dye solutions,” Appl. Opt. 37, 4914–4920 (1998).
  21. F. J. Duarte, “Solid-state dye laser oscillator: very compact cavity,” Opt. Commun. 117, 480–484 (1995).
  22. D. S. McClure, “Excited triplet state of some polyatomic molecules. I,” J. Chem. Phys. 19, 670–675 (1951).

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