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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Vol. 19, Iss. 8 — Aug. 1, 2002
  • pp: 1890–1900

Frequency-dependent first hyperpolarizabilities from linear absorption spectra

Anne Myers Kelley  »View Author Affiliations

JOSA B, Vol. 19, Issue 8, pp. 1890-1900 (2002)

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The first hyperpolarizabilities (β) of donor–acceptor-substituted push–pull molecules are generally described by a model in which the lowest excited electronic state dominates the optical response. It is shown that within the usual assumptions accompanying this two-state model, β(-2ω; ω, ω) can be expressed in terms of a Kramers–Kronig transform of the linear optical absorption spectrum. The method is applied to p–nitroaniline and several other push–pull chromophores, and results are compared with experimental data where available. Comparison of calculated and measured frequency dispersions is suggested as a purely experimental method, requiring no additional parameters, to test the assumptions of the two-state model.

© 2002 Optical Society of America

OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(160.4890) Materials : Organic materials
(190.4400) Nonlinear optics : Nonlinear optics, materials
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials
(300.6420) Spectroscopy : Spectroscopy, nonlinear

Anne Myers Kelley, "Frequency-dependent first hyperpolarizabilities from linear absorption spectra," J. Opt. Soc. Am. B 19, 1890-1900 (2002)

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