Branching ratios and transition probabilities in rhodium i

D. W. Duquette; J. E. Lawler

doi:10.1364/JOSAB.2.001948

Journal of the Optical Society of America B
Vol. 2,
Issue 12,
pp. 1948-1952
(1985)
•https://doi.org/10.1364/JOSAB.2.001948

Branching ratios and transition probabilities in rhodium i

D. W. Duquette and J. E. Lawler

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D. W. Duquette and J. E. Lawler, "Branching ratios and transition probabilities in rhodium i," J. Opt. Soc. Am. B 2, 1948-1952 (1985)

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Abstract

Branching ratios and absolute transition probabilities for 115 lines in rhodium i are reported. The branching ratios generally agree with branching ratios deduced from the Corliss–Bozman monograph. Although there are some revisions of branching ratios used in recent work on the solar abundance of Rh, the scatter in solar-abundance values determined from different lines is not reduced by the revised branching ratios.

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Level Energy Lifetime	Transition		Branching Ratio		gA (10⁸ sec⁻¹)

	Wave Number (cm⁻¹)	λ in Air (nm)	CB	This Expt.
4d⁸(³F)5p z⁴D_7/2
27075.26 cm⁻¹	14352.19	696.57	0.017	0.004 (3)	0.03 (2)
10.6 (5) nsec	17854.04	559.94	0.024	0.014 (10)	0.10 (7)
	19284.03	518.42	0.005	0.002 (1)	0.013 (9)
	21384.29	467.50	0.019	0.007 (2)	0.051 (15)
	23765.40	420.66	0.008	0.001 (1)	0.009 (9)
	25545.29	391.35	0.012	0.003 (1)	0.020 (9)
	27075.26	369.24	0.903	0.969 (23)	7.3 (4)
4d⁸(³F)5p z⁴G_9/2
28542.69 cm⁻¹	13754.82	726.82	0.004	0.004 (4)	0.04 (4)
10.1 (5) nsec	15819.62	631.95	0.003	0.004 (3)	0.04 (3)
	22851.72	437.48	0.272	0.166 (13)	1.64 (15)
	27012.72	370.09	0.414	0.391 (17)	3.9 (3)
	28542.69	350.25	0.308	0.435 (22)	4.3 (3)
4d⁸(³F)5p z⁴D_5/2
28859.64 cm⁻¹	16891.41	591.85	0.001	0.001 (1)	0.006 (6)
10.4 (5) nsec	18546.23	539.04	0.014	0.010 (3)	0.057 (15)
	19638.42	509.06	0.010	0.005 (2)	0.030 (9)
	21068.41	474.51	0.009	0.005 (2)	0.031 (9)
	25386.96	393.79		0.001 (1)	0.006 (6)
	25549.78	391.28	0.002	0.001 (1)	0.009 (9)
	26261.61	380.68	0.134	0.064 (8)	0.37 (5)
	27329.67	365.80	0.818	0.912 (9)	5.3 (3)
4d⁸(³F)5p z⁴F_9/2
29430.86 cm⁻¹	16707.79	598.36	0.015	0.019 (9)	0.21 (10)
9.2 (5) nsec	23739.89	421.11	0.270	0.149 (16)	1.62 (19)
	27900.89	358.31	0.332	0.237 (20)	2.6 (3)
	29430.86	339.69	0.381	0.595 (28)	6.5 (4)
4d⁸(³F)5p z⁴F_7/2
29866.34 cm⁻¹	17143.27	583.16	0.005	0.003 (3)	0.03 (3)
9.5 (5) nsec	20645.12	484.24	0.002	0.002 (1)	0.013 (11)
	22075.11	452.87	0.002	0.013 (2)	0.108 (20)
	24175.37	413.53	0.195	0.096 (11)	0.81 (10)
	27268.31	366.62	0.103	0.080 (9)	0.67 (8)
	28336.37	352.80	0.681	0.807 (21)	6.8 (4)
4d⁸(³F)5p z⁴D_3/2
30397.27 cm⁻¹	18429.04	542.47	0.004	0.005 (3)	0.020 (14)
10.2 (5) nsec	19391.22	515.55	0.011	0.010 (2)	0.039 (8)
	20083.86	497.77	0.010	0.010 (2)	0.039 (8)
	21176.05	472.10	0.003	0.003 (1)	0.0137 (59)
	26924.59	371.30	0.123	0.083 (5)	0.33 (2)
	27087.41	369.07	0.252	0.330 (14)	1.29 (9)
	27799.24	359.62	0.588	0.559 (18)	2.2 (1)
4d⁸(³F)5p z⁴G_7/2
31101.75 cm⁻¹	17581.06	568.64	0.005	0.004 (3)	0.04 (3)
8.6 (4) nsec	21880.53	456.90	0.013	0.009 (2)	0.082 (19)
	23310.52	428.87	0.081	0.053 (5)	0.49 (6)
	25410.78	393.42	0.180	0.135 (16)	1.26 (16)
	27791.89	359.71	0.486	0.510 (21)	4.7 (3)
	28503.72	350.73	0.225	0.289 (21)	2.7 (2)
4d⁸(³F)5p z⁴D_1/2
31146.68 cm⁻¹	19178.45	521.27	0.008	0.006 (3)	0.0119 (50)
10.1 (5) nsec	20140.63	496.37	0.023	0.030 (3)	0.060 (8)
	25488.71	392.22	0.073	0.063 (6)	0.125 (13)
	27674.00	361.25	0.882	0.901 (8)	1.78 (9)
4d⁸(³F)5p z⁴F_5/2
31474.50 cm	22253.28	449.25	0.005	0.004 (1)	0.027 (10)
9.0 (5) nsec	25783.53	387.74	0.042	0.033 (4)	0.22 (3)
	25816.53	387.24	0.008	0.006 (2)	0.040 (12)
	28001.82	357.02	0.123	0.164 (11)	1.09 (9)
	28164.64	354.95	0.185	0.200 (16)	1.33 (13)
	28876.47	346.20	0.595	0.560 (22)	3.7 (2)
	29944.53	333.85	0.032	0.032 (5)	0.21 (3)
4d⁸(³F)5p z²G_9/2
31613.78 cm⁻¹	18890.71	529.21	0.002	0.003 (1)	0.037 (18)
8.2 (4) nsec	25922.81	385.65	0.619	0.483 (46)	5.9 (6)
	30083.81	332.31	0.379	0.514 (46)	6.3 (6)
4d⁸(³F)5p z²F_7/2
32004.01 cm⁻¹	17216.14	580.69	0.006	0.010 (6)	0.09 (6)
8.7 (4) nsec	19280.94	518.50		0.001 (1)	0.009 (9)
	24212.78	412.89	0.172	0.150 (10)	1.38 (11)
	26313.04	379.93	0.508	0.480 (25)	4.4 (3)
	28694.15	348.40	0.009	0.008 (2)	0.074 (19)
	29405.98	339.97	0.075	0.105 (10)	0.97 (10)
	30474.04	328.05	0.205	0.205 (23)	1.89 (23)
	32004.01	312.37	0.020	0.040 (5)	0.37 (5)
4d⁸(³F)5p z²D_5/2
32046.32 cm⁻¹	20078.09	497.92	0.006	0.008 (2)	0.060 (12)
8.1 (4) nsec	22825.10	437.99	0.012	0.020 (3)	0.149 (23)
	24255.09	412.17	0.127	0.079 (7)	0.59 (6)
	26355.35	379.32	0.405	0.342 (21)	2.5 (2)
	26388.35	378.85	0.110	0.111 (7)	0.82 (7)
	28573.64	349.87	0.119	0.171 (12)	1.27 (11)
	28736.46	347.89	0.211	0.269 (20)	1.99 (18)
4d⁸(³F)5p z⁴F_3/2
32277.43 cm⁻¹	20309.20	492.25		0.003 (2)	0.013 (9)
8.7 (4) nsec	21964.02	455.16	0.008	0.036 (7)	0.160 (30)
	24486.20	408.28	0.103	0.124 (13)	0.57 (7)
	26619.46	375.56	0.083	0.007 (3)	0.02 (2)
	28804.75	347.07	0.726	0.731 (41)	3.4 (3)
	28967.57	345.12		0.007 (4)	0.02 (2)
	29679.40	336.84	0.064	0.092 (11)	0.42 (5)
4d⁸(³F)5p z²G_7/2
33043.91 cm⁻¹	19523.22	512.07	0.005	0.003 (1)	0.025 (11)
9.2 (5) nsec	20320.84	491.97		0.002 (1)	0.017 (10)
	23822.69	419.65	0.054	0.035(4)	0.31 (4)
	25252.68	395.89	0.581	0.500 (35)	4.4 (4)
	27352.94	365.49	0.050	0.055 (5)	0.48 (5)
	30445.88	328.36	0.299	0.405 (39)	3.5 (4)
4d⁸(³F)5p z²D_3/2
33867.04 cm⁻¹	19484.85	513.08	0.006	0.003 (1)	0.0174 (75)
7.0 (3) nsec	20346.35	491.35		0.002 (1)	0.012 (7)
	21898.81	456.52	0.005	0.008 (2)	0.043 (9)
	22860.99	437.30	0.013	0.012 (2)	0.070 (12)
	23553.63	424.44	0.011	0.005 (1)	0.026 (8)
	24645.82	405.63	0.006	0.007 (1)	0.038 (9)
	26075.81	383.39	0.491	0.396 (25)	2.3 (2)
	28209.07	354.40	0.263	0.325 (22)	1.86 (15)
	30394.36	328.91	0.059	0.071 (10)	0.41 (6)
	30557.18	327.16	0.107	0.142 (20)	0.81 (12)
	31269.01	319.71	0.038	0.030 (4)	0.174 (25)
4d⁸(³F)5p z²F_5/2
33946.34 cm⁻¹	21978.11	454.87	0.008	0.004 (2)	0.033 (17)
7.3 (4) nsec	26155.11	382.23	0.699	0.626 (41)	5.1 (4)
	28255.37	353.83	0.154	0.121 (10)	1.00 (10)
	30473.66	328.05		0.101 (15)	0.83 (13)
	30636.48	326.31	0.082	0.091 (13)	0.75 (12)
	31348.31	318.90	0.022	0.022 (4)	0.182 (36)
	32416.37	308.40	0.025	0.035 (7)	0.29 (6)
4d⁸(³P)5p z⁴P_5/2
35333.85 cm⁻¹	19213.13	520.33		0.002 (1)	0.010 (8)
12.0 (6) nsec	20545.98	486.58		0.005 (2)	0.025 (10)
	23365.62	427.86	0.023	0.011 (2)	0.055 (9)
	25020.44	399.56	0.086	0.055 (4)	0.28 (3)
	26112.63	382.85	0.824	0.739 (51)	3.7 (3)
	29642.88	337.25		0.006 (3)	0.030 (15)
	29675.88	336.88		0.010 (4)	0.050 (20)
	31861.17	313.77	0.027	0.040 (16)	0.20 (8)
	32023.99	312.18	0.040	0.131 (31)	0.65 (16)
4d⁸(³P)5p z⁴P_3/2
35404.24 cm⁻¹	21022.05	475.56	0.007	0.006 (1)	0.024 (5)
9.8 (5) nsec	24398.19	409.75	0.069	0.068 (5)	0.28 (2)
	25090.83	398.44	0.110	0.107 (6)	0.44 (3)
	26183.02	381.82	0.578	0.572 (16)	2.3 (1)
	27613.01	362.05	0.085	0.082 (6)	0.34 (3)
	29746.27	336.08	0.112	0.121 (15)	0.49 (7)
	32094.38	311.49	0.026	0.044 (21)	0.178 (86)
4d⁸(³P)5p z⁴P_1/2
35669.50 cm⁻¹	21694.77	460.81	0.051	0.025 (3)	0.041 (5)
12.2 (6) nsec	24663.45	405.34	0.059	0.034 (3)	0.056 (6)
	25356.09	394.27	0.820	0.875 (11)	1.43 (7)
	30011.53	333.11	0.070	0.066 (9)	0.108 (16)

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Journal of the Optical Society of America B