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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 2, Iss. 5 — May. 1, 1985
  • pp: 794–799

Infrared laser spectroscopy of H3O+ between 510 and 1150 cm−1

P. B. Davies, P. A. Hamilton, and S. A. Johnson  »View Author Affiliations


JOSA B, Vol. 2, Issue 5, pp. 794-799 (1985)
http://dx.doi.org/10.1364/JOSAB.2.000794


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Abstract

Lead-salt-diode lasers have been used to detect more than 100 absorption lines of H3O+ in an ac discharge by using the velocity-modulation technique. Many lines have been assigned to vibration-rotation transitions in the 1 ← 0+ and 1+ ← 0 components of the ν2 inversion mode of H3O+ with band centers at 954.4 and 525.8 cm−1, respectively. The results for the former band extend those of earlier work and lead to some minor changes in assignment.

© 1985 Optical Society of America

Citation
P. B. Davies, P. A. Hamilton, and S. A. Johnson, "Infrared laser spectroscopy of H3O+ between 510 and 1150 cm−1," J. Opt. Soc. Am. B 2, 794-799 (1985)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-2-5-794


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References

  1. M. Eigen, "Proton transfer, acid-base catalysis, and enzymatic hydrolysis," Angew. Chem. Int. Ed. Engl. 3, 1 (1964).
  2. M. D. Newton and S. Ehrenson, "Ab initio studies on the structures and energetics of inner- and outer-shell hydrates of the proton and hydroxide ion," J. Am. Chem. Soc. 93, 4971 (1971).
  3. A. Good, D. A. Durden, and P. Kebarle, "Mechanism and rate constants of ion-molecule reactions leading to formation of H+(H2O)n in moist oxygen and air," J. Chem. Phys. 52, 222 (1970).
  4. P. Kebarle and E. W. Godbole, "Mass-spectrometric study of ions from the α-particle irradiation of gases at near atmospheric pressure," J. Chem. Phys. 39, 1131 (1963).
  5. For a review, see D. Smith and N. G. Adams, "Molecular synthesis in interstellar clouds: recent laboratory studies of ionic reactions," Int. Rev. Phys. Chem. 1, 271 (1981).
  6. W. G. Richards, P. R. Scott, V. Sackwild, and S. A. Robin, A Bibliography of ab Initio Molecular Wave Functions (Oxford U. Press, London, 1981).
  7. N. N. Haese and T. Oka, "Observation of the ν2(1 ← 0+) inversion mode band in H3O+ by high resolution infrared spectroscopy," J. Chem. Phys. 80, 572 (1984).
  8. M. H. Begemann, C. S. Gudeman, J. Pfaff, and R. J. Saykally, "Detection of the hydroxonium ion (H3O+), by high-resolution infrared spectroscopy," Phys. Rev. Lett. 51, 554 (1983).
  9. P. Botschwina, P. Rosmus, and E. A. Reinsch, "Spectroscopic properties of the hydroxonium ion, calculated from SCEP CEPA wavefunctions," Chem. Phys. Lett. 102, 299 (1983).
  10. P. R. Bunker, W. P. Kraemer, and V. Spirko, "Ab initio rotation-vibration energies of H3O+," J. Mol. Spectrosc. 101, 180 (1983).
  11. P. R. Bunker, T. Amano, and V. Spirko, "A preliminary determination of the equilibrium geometry and inversion potential in H3O+ from experiment," J. Mol. Spectrosc. 107, 208 (1984).
  12. C. S. Gudeman, M. H. Begemann, J. Pfaff, and R. J. Saykally, "Velocity-modulated infrared laser spectroscopy of molecular ions: the ν1 band of HCO+," Phys. Rev. Lett. 50, 727 (1983).
  13. K. Jolma, J. Kauppinen, and V. M. Horneman, "Vibration-rotation bands of CO2 and OCS in the region 540 cm−1–890 cm−1," J. Mol. Spectrosc. 101, 300 (1983); C. Freed, L. C. Bradley, and R. G. O'Donnell, "Absolute frequencies of lasing transitions in seven CO2 isotopic species," IEEE J. Quantum Electron. QE-16, 1195 (1980).
  14. K. Jolma, J. Kauppinen, and V. M. Horneman, "Vibration-rotation spectrum of N2O in the region of the lowest fundamental," J. Mol. Spectrosc. 101, 278 (1983); B. G. Whitford, K. J. Siemsen, H. D. Riccius, and G. R. Hanes, "Absolute frequency measurements of N2O laser transitions," Opt. Commun. 14, 70 (1975).
  15. R. L. Poynter and J. S. Margolis, "The ν2 spectrum of NH3," Mol. Phys. 51, 393 (1984).
  16. J. Kauppinen, K. Jolma, and V. M. Horneman, "New wave-number calibration tables for H2O, CO2, and OCS lines between 500 and 900 cm−1," Appl. Op. 21, 3332 (1982).
  17. J. W. C. Johns, Herzberg Institute of Astrophysics, National Research Council of Canada, Ottawa, Canada (personal communication).
  18. B. Lemoine and J. L. Destombes, "I. R. spectroscopy of molecular ions in a magnetically confined glow discharge," Chem. Phys. Lett. 111, 284(1984).
  19. P. B. Davies, P. A. Hamilton, and S. A. Johnson, "Laboratory measurement of H3O+ line positions around 10 μm for astrophysical searches," Astron. Astrophys. 141, L9 (1984).
  20. J. M. Hollas, High Resolution Spectroscopy (Butterworths, London, 1982).
  21. N. Shida, K. Tanaka, and K. Ohno, "An ab initio calculation of symmetric bending and stretching vibrational states of the H3O+ and D3O+ ions," Chem. Phys. Lett. 104, 575 (1984).

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